Polymerization of aldehydes and oxides:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York, NY [u.a.]
Interscience Publ.
1963
|
| Series: | Polymer reviews
3 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 482 S. graph. Darst. |
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Record in the Search Index
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| adam_text | POLYMERIZATION OF
ALDEHYDES AND
OXIDES
JUNJI FURUKAWA and TAKEO SAEGUSA
Department of Synthetic Chemistry
Kyoto University, Kyoto, Japan
Am i F) ~ ? (o ?
GMELIN-INSTiUT
fur ar orqcn sc e Che e un i Gren _;e„ie!e
oer Max - Pen « e » , ;c af ur
for eruns Gc-r Wis e j haf e i
Frankfurt/Main
— Bibliothek —
INTERSCIENCE PUBLISHERS
A DIVISION OF JOHN WILEY amp; SONS
NEW YORK • LONDON • SYDNEY
CONTENJS
I General Survey of Polymerizations of Heterocyclic and Carbonyl Cora-
pounds 1
A Introduction 1
B Polymerization of Heteroatomic Unsaturated Compounds 3
1 Polymerizable Heteroatomic Unsaturated Compounds 3
2 Polymerizability of Unsaturated Compounds 8
C Polymerization of Heterocyclic Compounds 13
1 Polyinerizable Heterocyclic Compounds 13
2 Polymerizability of Cyclic Compounds 15
3 Polymerizability of Bridged Bicyclic Compounds 26
D Structural Aspects of Poly ethers 30
1 Polymers of Heteroatomic Unsaturated Compounds 30
2 Polymers of Cyclic Oxides 34
Bibliography 40
II Polymerization of Aldehydes 43
• A Introduction 43
1 History of Research and Recent Developments 43
2 The Mode of Polymerization Reactions; 44
B Polymerization to Cyclic Oligomers 45
C Polymerization of Formaldehyde 48
1 Types of Polymerization Reactions 48
2 Condensation Polymerization of Formal lehyde 50
3 ^ddition Polymerization of Anhydrous Formaldehyde 56
4 Recent Developments of Formaldehyde Polymerization 59
5 Radiation-Induced Polymerization 70
6 Aldol-Type Condensation of Formaldehyde 72
• D Polymerization of Acetaldehyde 77
1 Freezing Polymerization 77
2 Cationic Polymerization 88
3 Adsorption Polymerization 89
4 Stereoregular Polymerization 94
5 Stereoblock Polymerization 104
6 Radiation Polymerization 107
7 Polyaldolization of Acetaldehyde 109
E Polymerizations of Higher Aldehydes, Halogenated Aldehydes and
Dialdehydes 112
1 Polymerizations of Higher Aldehydes 112
2 Polymerizations of Halogenated Aldehydes 114
3 Polymerization of Dialdehyde 115
F Copolymerization of Aldehydes 116
G Polymerizations of Ketones and Other Carl •onyl Compounds 116
1 Polymerizations of Acetone and Monobroinoacctone 116
Bibliography 118
X CONTENTS
III Polymerization of Alkylene Oxides 125
A A General Discussion of the Polymerization of Alkylene Oxides 125
1 Historical 125
2 Structure of Alkylene Oxide 127
3 Mechanism of Ring Opening Reaction of Alkylene Oxide 129
4 Polymerization Mechanisms 130
B Stepwise Anionic Polymerization 133
1 Principles and Procedures 133
2 Kinetic Study 135
3 Copolymerization by Stepwise Polymerization 142
4 End Groups of Polypropylene Glycol Prepared with Alkali
Catalysts 144
5 Polymerization of Alkylene Oxide by Solid Alka li Catalysts 147
C Polymerization by Cationic Mechanisms 147
D Coordinated Anionic Polymerization 155
1 Introduction to Coordinate Anionic Polymerization 155
2 Description of Catalytic Systems 159
3 Polymerization by the Binary Systems of Acidic Oxides (Alumina
or Silica-Alumina) and Organometallic Compound 172
4 Polymerization by Organometallic Compounds in the Presence of
Water or Active Hydrogen Compounds • 181
5 Mechanism of Coordinate Polymerizati n 187
F Polymerization of Miscellaneous Epoxy Compounds 193
1 Introduction 193
2 Polymerization of ^Propylene Oxide 196
3 Polymerization of Isobutylene Oxide 197
4 Polymerization of Styrene Oxide and Butadiene Monoxide 197
5 Polymerizations of Glycidyl Ethers 198
6 Chlorinated Epoxides 200
7 Polymerization of Symmetrical Disubst ituted Epoxides 201
8 Polymerizations of Di-epoxides 202
G Radical Polymerization of Alkylene Oxides 202
Bibliography 204
IV Polymerization of Oxacyclobutane and Its Derivatives 209
A Introduction 209
B Mechanism of the Polymerization of Oxacyclobutaue 210
C Polymerization Procedure for 3,3-Bis(chloromethyl)oxacyclobutane 214
1 Polymerization Catalyst, Solvent, and 1 emperaLure 214
2 Polymerization Apparatus and Flowsheet 217
D Various Substituted Oxacyclobutanes 220
E Copolymerizatioiis of Oxacyclobutanes 223
Bibliography 224
V Polymerizations of Tetrahydrofuran and 1,4-Epoxycyclohexane 225
A Introduction 225
B Catalysts and Mechanism for Polymerization of Tetrahydrofuran 226
Bibliography 235
CONTENTS xi
VI Polymerization of Cyclic Formals 237
A Introduction 237
B Polymerizability of Cyclic Formals 237
C Polymerization of 1,3-Dioxolane 238
D Polymerizations of Seven-Membered Cyclic Formals and Higher
Homologs 241
E Polymerization of Trioxane 242
Bibliography 245
VII Copolymerizations of Aldehydes and of Cyclic Oxides 247
A Introduction 247
B Copolymerizations of Aldehydes and of Cyclic Oxides 248
1 Copolymerizations of Aldehyde with Olefmic or Vinyl Compounds 249
2 Copolymerizations of Alkylene Oxides with Olefins or Vinyl Com
pounds 251
3 Copolymerizations of Oxacyclobutane with Olefins or Vinyl Com
pounds 252
4 Copolymerizations of Tetrahydrofuran with Olefins or Vinyl Com
pounds • 252
5 Copolymerizations of Cyclic Formals or Trioxane with Olefins or
Vinyl Compounds 252
6 Copolymerization of Aldehyde with Alkylene Oxide 253
7 Copolymerization of Aldehyde with Oxacy clobuta t ie 253
8 Copolymerization of Aldehyde with Tetrahydrofuran 253
9 Copolymerization of Aldehyde with Cyclk Formal 254
10 Copolymerization of Oxacyclobutane with Alkylene Oxide 254
11 Copolymerization of Alkylene Oxide with Tetrahydrofuran 254
12 Copolymerization of Alkylene Oxide with Cyclic Formals 255
13 Copolymerization of Oxacyclobutanes with Tetrahydrofuran 255
14 Copolymerization of Oxacyclobutanes with Cyclic Formal 255
15 Copolymerization of Tetrahydrofuran wit h Cyclic Formal 256
Bibliography 256
VIII Properties and Applications of Polyethers 257
A Introduction 257
B Degradation and Stabilization of Polyforinaklohyde 260
1 Decomposition Reactions of Polyformaldrhyde 260
2 Stabilization of Polyformaldehyde 263
C Properties of Polyformaldehyde 270
1 Introduction 270
2 Properties of the Classical Polymers of Formaldehyde 270
3 Properties of Thermally Stable Polymers • f Formaldehyde 274
D Properties of Polymers of Acetaldehyde and Other Higher Aldehydes 280
1 Polyacetaldehyde 280
2 Properties of Higher Aldehydes and Halouenated Aldehydes 284
E Polyethylene Oxide 286
1 Degradation and Stabilization 286
2 Properties and Applications of Polyetln lene Oxide of Low and
Medium Molecular Weights 288
xii CONTENTS
3 Properties and Applications of Polyethylene Oxide of High Molecn-
lar Weight 290
F Pplyjners of Propylene Oxide and Other Alkylene Oxides • 297
1 Degradation and Stabilization 297
2 Crystallinity and Crystal Structure 298
3 Mechanical Properties 302
G Polymers of Oxacyclobutane and Derivatives 302
1 Stability and Stabilization 302
2 Solubility and Water Absorption 304
3 Physical and Mechanical Properties 304
H - Miscellaneous Polyethers 306
• • - 1: Poly tetrahydrofuran 306
2 Poly-l,3-dioxolane 306
3 Polymer and Copolymer of Trioxane 307
• • • • Bibliography 308
IX Tabulated Examples of Patents 311
X Appendix (Developments during 1961 and 1962) 401
Author Index - 459
Subject Index
Patent Index
|
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| indexdate | 2024-07-09T15:40:41Z |
| institution | BVB |
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| physical | XII, 482 S. graph. Darst. |
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| series | Polymer reviews |
| series2 | Polymer reviews |
| spelling | Furukawa, Junji Verfasser aut Polymerization of aldehydes and oxides Junji Furukawa and Takeo Saegusa New York, NY [u.a.] Interscience Publ. 1963 XII, 482 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymer reviews 3 Aldéhydes Oxydes Polymérisation Aldehydes Oxides Polymerization Oxide (DE-588)4126202-5 gnd rswk-swf Aldehyde (DE-588)4186368-9 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Aldehyde (DE-588)4186368-9 s Polymerisation (DE-588)4046704-1 s DE-604 Oxide (DE-588)4126202-5 s Saegusa, Takeo Verfasser aut Polymer reviews 3 (DE-604)BV001890082 3 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001391315&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Furukawa, Junji Saegusa, Takeo Polymerization of aldehydes and oxides Polymer reviews Aldéhydes Oxydes Polymérisation Aldehydes Oxides Polymerization Oxide (DE-588)4126202-5 gnd Aldehyde (DE-588)4186368-9 gnd Polymerisation (DE-588)4046704-1 gnd |
| subject_GND | (DE-588)4126202-5 (DE-588)4186368-9 (DE-588)4046704-1 |
| title | Polymerization of aldehydes and oxides |
| title_auth | Polymerization of aldehydes and oxides |
| title_exact_search | Polymerization of aldehydes and oxides |
| title_full | Polymerization of aldehydes and oxides Junji Furukawa and Takeo Saegusa |
| title_fullStr | Polymerization of aldehydes and oxides Junji Furukawa and Takeo Saegusa |
| title_full_unstemmed | Polymerization of aldehydes and oxides Junji Furukawa and Takeo Saegusa |
| title_short | Polymerization of aldehydes and oxides |
| title_sort | polymerization of aldehydes and oxides |
| topic | Aldéhydes Oxydes Polymérisation Aldehydes Oxides Polymerization Oxide (DE-588)4126202-5 gnd Aldehyde (DE-588)4186368-9 gnd Polymerisation (DE-588)4046704-1 gnd |
| topic_facet | Aldéhydes Oxydes Polymérisation Aldehydes Oxides Polymerization Oxide Aldehyde Polymerisation |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001391315&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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