Chemistry of the carbohydrates:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York, NY
Acad. Press
1948
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVII, 748 S. graph. Darst. 24 cm |
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MARC
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| 100 | 1 | |a Pigman, William Ward |d 1910-1977 |e Verfasser |0 (DE-588)1036533816 |4 aut | |
| 245 | 1 | 0 | |a Chemistry of the carbohydrates |c by William Ward Pigman and Rudolph Maximilian Goepp |
| 246 | 1 | 3 | |a Carbohydrate chemistry |
| 264 | 1 | |a New York, NY |b Acad. Press |c 1948 | |
| 300 | |a XVII, 748 S. |b graph. Darst. |c 24 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Glucides |2 ram | |
| 650 | 4 | |a Carbohydrates | |
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| 700 | 1 | |a Goepp, Rudolph Maximilian |e Verfasser |4 aut | |
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| _version_ | 1804116504064557056 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
CHAPTEB .PAGE
PREFACE V
I. INTRODUCTION 1
1. DEVELOPMENT OF CARBOHYDRATE CHEMISTRY 1
2. GENERAL CHEMISTRY 5
A. STEREOISOMERISM . 5
B. ACTIVATION BY CARBONYL GROUPS 5
C. INTERMOLECULAR REACTIONS S
D. THE GLYCOSIDIC HYDROXYL AND POLYMERIC CARBOHYDRATES ILL
3. NOMENCLATURE AND DEFINITIONS 13
A. SCOPE AND GENERAL DEFINITIONS 13
B. CONFIGURATIONAL AND TRIVIAL NAMES IS
C. D- AND L-SERIES 21
D. ALPHA-BETA DESIGNATIONS 21
II. STRUCTURE AND STEREOCHEMISTRY OF THE MONOSACCHARIDES 23
1. STRUCTURES OF GLUCOSE AND FRUCTOSE 23
2. STEREOCHEMISTRY 24
A. GENERAL PRINCIPLES 24
B. ESTABLISHMENT OF THE CONFIGURATION OF GLUCOSE AND SOME OTHER SUGARS
27
C. D,L NOMENCLATURE 35
3. RING STRUCTURES OF THE SUGARS 42
A. NECESSITY FOR RING STRUCTURES 42 *
B. PROOF OF RING STRUCTURE 44
C. CONFIGURATION OF THE ANOMERIC CARBON ATOM 48
D. THE REPRESENTATION OF THE RING STRUCTURES OF THE SUGARS 50
E. NOMENCLATURE OF ANOMERS (A-I3 NOMENCLATURE) 55
4. HOMOMORPHOUS SUGARS 56
A. HOMOMORPHOLOGY 56
B. NOMENCLATURE OF THE HIGHER SUGARS 60
5. THE SUGARS IN SOLUTION 62
A. IN THE ABSENCE OF STRONG ACIDS OR ALKALIES; MUTAROTATION 62
B . IN THE PRESENCE OF ACIDS 69
C. IN THE PRESENCE OF ALKALIES 71
A. ISOMERIZATIONS 72
B . FRAGMENTATION 77
D. BEHAVIOR OF THE SUGARS WITH SHORT CARBON CHAINS 70
6. OPTICAL SUPERPOSITION, THE ISOROTATION RULES, UIID T.HE INFLUENCE OF
STRUC TURE ON OPTICAL ROTATION SO
III. OCCURRENCE, PROPERTIES, SYNTHESIS AND ANALYSIS OF THE
MONOSACCHARIDES... SO 1. NATURALLY OCCURRING MONOSACCHARIDES SO
A. INTRODUCTION SO
B. PROPERTIES, IDENTIFICATION, ORIGIN AND PREPARATION OF NATURALLY
OCCURRING MONOSACCHARIDES 00
A. HEXOSES 01
IX
0
HTTP://D-NB.INFO/1036532569
IMAGE 2
X CONTENTS
CHAPTER PAGE
O-FRUCTOSE.. 91
I)-GALACTOSE 93
II- AND D,IJ-GALACTOSE 96
D-GLUCOSE 96
N-MANNOSE 99
L-SORBOSE 101
B . PENTOSES: 102
J.-ARABINOSE 102
U-ARABINOSE 103
D-RIBOSE 103
D-XYLOSE 104
IJ-XYLULOSE 105
C. METHYLOSES: 106
6-DESOXY-U-GLUEOSE 106
II-FUCOSE 107
D-FUCOSE 107
L-RHAMNOSE 108
D. HEPTOSES: 109
N-MANNOHEPTULOSE 109
SEDOHEPTULOSE 110
2. SYNTHETIC SUGARS ILL
A. COMPLETE SYNTHESIS OF THE SUGARS ILL
B. METHODS TOR LENGTHENING THE CARBON CHAINS OF THE SUGARS .... 116 C.
METHODS FOR SHORTENING THE CARBON CHAINS OF SUGARS 121
D. METHODS FOR THE SYNTHESIS OF SUGARS WITH TERMINAL METHYL GROUPS
(METHYLOSES) 125
E. SYNTHETIC METHODS BASED ON CHANGING THE CONFIGURATION OF OTHER SUGARS
126
F. PREPARATION OF LVETOSES BY BIOCHEMICAL OXIDATION OF ALCOHOLS .. 131
G. ALDOSE TO KETOSE CONVERSION UTILIZING THE OSONES 132
3. THE IDENTIFICATION AND THE QUANTITATIVE DETERMINATION OF CARBOHY
DRATES 133
A. QUALITATIVE IDENTIFICATION 133
*. SEPARATION OF SUGAR MIXTURES 133
*. COLOR REACTIONS 134
C. DERIVATIVES 135
X B. QUANTITATIVE DETERMINATION 137
*. OPTICAL ROTATION 137
*. REDUCING SUGAR METHODS 139
OXIDATION BY METALLIC SALTS IN ALKALINE SOLUTION 139
OXIDATION WITH POTASSIUM FERRICYANIDE 143
C. COLORIMET-RIC PROCEDURES USING ORCINOL OR CARBAZOLE 143 (I. SPECIAL
METHODS 7 144
DETERMINATION OF ALDOSES BY HYPOIODITE 144
DETERMINATION OF PENTOSES AND PENTOSANS 145
DETERMINATION OF SUGARS AS HYDRAZONES AND OSAZONES. . 145 FERMENTATION
METHODS 146
IV. ESTERS 149
IMAGE 3
CONTENTS XI
CHAPTER PAGE
1. ACETYL DERIVATIVES 150
A. CYCLIC ACETATES 150
B. ACYCLIC SUGAR ACETATES (ALDEHYDO DERIVATIVES) . 152
C. ACETATES WITH A HEPTANOSE RING 155
D. DERIVATIVES OF ORTHOACETIC ACID 156
E. ACETJ L MIGRATION 159
2. ACETYLGLYCOSYL HALIDES (HALOGENO ACETYL SUGARS) 159
A. CYCLIC FORMS 159
B. OPTICAL ROTATION AND ATOMIC DIMENSION 164
C. ACYCLIC ANALOGS OF THE ACETYLGLYCOSYL HALIDES 164
3. BENZOYL DERIVATIVES 165
4. GALLOYL DERIVATIVES AND TANNIIIS 167
5. OTHER ORGANIC ESTERS 169
6. TOSYL AND MESYL DERIVATIVES 170
1. NITRIC ACID ESTERS 176
2. SUGAR CARBONATES 177
3. PHOSPHATE ESTERS 17S
4. ESTERS OF ARSENOUS ACIDS 182
5. SULFATE ESTERS 1S2
6. BORIC ACID ESTERS 183
7. HALOGENO ESTERS 184
V. GLYCOSIDES, FULL ACETALS AND THIOACETALS 186
1. GLYCOSIDES 187
A. METHODS FOR SYNTHESIS 188
*. FISCHER METHOD 189
*. MICHAEL SYNTHESIS 193
C. KOENIGS-KNORR REACTION 193
D . HELFERICH METHOD *. 194
E. USE OF SUGAR MERCAPTALS 195
/. DIRECT ALKYLATION METHOD 196
G. FROM GLYCALS 197
H . FURANOID GLYCOSIDES AND SUGARS FROM-CARBONATES 197
I . ENZYMIC SYNTHESIS 197
J . TRANSGLYCOSIDATION 198
B. PROPERTIES OF GLUCOSIDES 199
A. STABILITY TO ALKALINE HYDROLYSIS 199
B . HYDROGENATION 201
C. EASE OF HYDROLYSIS BY ACIDS 202
C. DETERMINATION OF THE STRUCTURES OF GLYCOSIDES: 207
A. PYRANOICL STRUCTURE OF FISCHER S CRYSTALLINE METHYL GLYCOSIDES 207
B . FURANOID STRUCTURE OF Y METHYL GLUCOSIDES. 208
C. PYRANOID NATURE OF THE METHYL FRUCTOSIDES 208
D . PERIODIC ACID OXIDATION 209
2. GLYCOSANS (INNER GLYCOSIDES) 214
A. PREPARATION : 214
B. DIFRUCTOSE ANHYDRIDES 216
C. STRUCTURES 217
D. REACTIONS 218
IMAGE 4
CHAPTER PAGE
3. ACETAL AND MERCAPTAL DERIVATIVES OF ACYCLIC SUGARS 21S
A. MERCAPTALS 218
B. ACETALS 220
4. REACTIONS OF CARBOHYDRATES WITH ALDEHYDES AND KETONES 222
A. METHYLENE (FORMAL) DERIVATIVES 224
B. BENZYLIDENE DERIVATIVES 224
C. CONDENSATION WITH ACETALDEHYDE AND FURFURALDEHYDE 22G
D. ISOPROPYLIDENE (ACETONE) DERIVATIVES 22S
E. ACETOACETIC ESTER DERIVATIVES 231
VI. THE POLYOLS 232
PAST I. ACYCLIC POLYOLS (GI.YKITOLS) 1. CONFIGURATIONS, OCCURRENCE AND
PREPARATION 233
A. TETRITOLS 233
B. PENTITOLS 234
C. HEXITOLS 236
D. HEPTITOLS 242
E. OCT-ITOLS, NONITOLS AND DECITOLS 245
2. PROOFS OF STRUCTURE AND CONFIGURATION 247
3. SYNTHESIS 250
4. REACTIONS 252
A. ESTERIFICATION 252
B. OXIDATION 254
C.- REDUCTION 255
D. ETHERIFICATION 256
E. QUALITATIVE AND QUANTITATIVE DETERMINATION 256
F. BIOCHEMISTRY 257
5 ; DESOXY POLYOLS 257
A. SYNTHESIS AND PROPERTIES OF MONODESOXY POLYOLS 259
B. SYNTHESIS AND PROPERTIES OF DIDESOXY POLYOLS 26.1
C. PROOFS OF STRUCTURE AND CONFIGURATION 263
PAHT II. THE INOSITOLS AND RKI.ATEU COMPOUNDS 1. ISOMERIZATION AND
REPRESENTATION OF CONFIGURATION 264
2. OCCURRENCE AND SYNTHESIS 266
3. PROOFS OF STRUCTURE AND CONFIGURATION 271
A. NIESO-INOSITOL 271
B. D - AND Z-INOSITOL 273
C. D-QUERCITOL 273
D. CONDURITOL 275 *
E. MYTILITOL 276
F. QUINIC ACID 277
G. SHIKIMIC ACID 27S
4. REACTIONS 279
A. BEHAVIOR WITH OXIDIZING AGENTS 279
*. NITRIC ACID 279
*. ALKALINE PERMANGANATE 280
C. HYPOBROMITE AND BROMINE 280
D . TETRAVALENT LEAD 2S0
E. BACTERIAL OXIDATION 280
IMAGE 5
CONTENTS XIII
CHAPTER . PAGE
B. REACTION WITH HALOGEN ACIDS 2S1
O. HALOHYDRIN FORMATION 2S1
6. AROMATIZATION 2S3
C. ESTERIFICATION 2S3
D. ALKYLIDENE FORMATION 2S4
E. METALLIC COMPLEXES 2S4
F. MISCELLANEOUS REACTIONS 284
5. BIOCHEMISTRY 2S6
VII. ACIDS AND OXIDATION PRODUCTS OF CARBOHYDRATES . 2SS
1. PREPARATION AND REACTIONS 290
A. ALDONIC ACIDS 21)0
*. PREPARATION 291
*. EQUILIBRIUM IN SOLUTION 292
C. EPIMERIZATION 295
D . OPTICAL ROTATORY RELATIONSHIPS 296
E. REACTIONS OF THE ALDONIC ACIDS 297
B. SACCHARIC (ARIC) ACIDS 299
*. TARTRONIC AND MALIC ACIDS 299
*. TETRARIC ACIDS (TARTARIC ACIDS) 300
C. PENTARIC AND HEXARIC ACIDS 301
C. URONIC ACIDS 303
A. PREPARATION AND OCCURRENCE 303
B . ALDOBIURONIC ACIDS 306
C. REACTIONS OF URONIC ACIDS 30S
D. KETO ALDBNIC ACIDS 310
E. ASCORBIC ACIDS 313
A..GENERAL PROPERTIES AND REACTIONS 313
B . VITAMIN C (L-XYLOASCORBIC ACID) 316
F. OSONES 318
2. OXIDATION AGENTS 319
A. HALOGEN OXIDATIONS 319
A. HALOGENS AND HYPOHALITES 320
B . HALIC ACIDS (HXO A) 327
C. CHLOROUS ACID (HCLOS) 32S
B. REAGENTS CLEAVING GLYCOLS 32S
C. NITRIC ACID AND NITROGEN OXIDES 332
D. OXYGEN IN ALKALINE OR NEUTRAL SOLUTION 335
E. HYDROGEN PEROXIDE 336
F. RELATIVELY UNSPECIFIC OXIDANTS 339
A. CHROMIC ACIDS AND CERIC SULFATE (ACID CONDITIONS) 339 WET COMBUSTIONS
339
B . NEUTRAL AND ALKALINE PERMANGANATE 341
C. SILVER OXIDE 342
D . COPPER SALTS IN ALKALINE SOLUTION 342
G. MICROBIAL OXIDATIONS 343
VIII. ETHERS, ANHYDRIDES AND UNSATURATED DERIVATIVES 345
1. ETHER DERIVATIVES (EXTERNAL) 345
A. ALKYLATION METHODS 346
B. TRITYL DERIVATIVES 34S
IMAGE 6
XIV CONTENTS
CHAPTER PAGE
2. CARBOHYDRATE INNER ETHERS (ANHYDRIDES) 350
A. FIVE-MEMBERED RINGS. 1,4 AND 3,6 TYPES 351
B. ISOHEXIDES (1,4-3,6-HEXIDES) 354
C. 2,5-ANHYDRO COMPOUNDS 354
D. 1,5-ETHE R RINGS 359
E. EPOXY DERIVATIVES 361
F. BIOCHEMISTRY AND REACTIONS OF SUGAR ALCOHOL ANHYDRIDES (GLYKITANS)
362
A. BIOCHEMISTRY 362
B . REACTIONS WITH INORGANIC REAGENTS 363
C. REACTIONS WITH ORGANIC REAGENTS 366
3. UNSATURATED SUGARS (GLYCALS AND GLYCOSEENS) 369
A. GLYCALS 369
B. GLYCOSEENS 372
IX. NITROGENOUS DERIVATIVES 375
1. GLYCOSYLAMINES 376
A. OSIMINES OR PRIMARY GLYCOSYLAMINES 376
B. N-GLYCOSIDES *. 377
A. PREPARATION 379
B . REACTIONS OF N-GLYCOSIDES 385
C. AMADORI REARRANGEMENT 386
D . NUCLEOSIDES 388
2. NUCLEOTIDES 390
A. PREPARATION AND STRUCTURE. 390
B. ADENOSINE DI- AND TRI-PHOSPHORIC ACIDS 392
C. BIOLOGICALLY IMPORTANT SUBSTANCES RELATED TO THE NUCLEOTIDES. 393 3.
NUCLEIC ACIDS * 396
A. THYMUS DESOXYRIBONUCLEIC ACID 398
B. YEAST RIBONUCLEIC ACID..: 399
4. REACTIONS OF THE SUGARS WITH SUBSTITUTED HYDRAZINES AND HY-
DROXYLAMINE 401
A. HYDRAZONES AND OSAZONES 401
B. OXIMES 410
5. DERIVATIVES IN WHICH AN AMINO.GROUP REPLACES A PRIMARY OR SECONDARY
HYDROXYL GROUP 412
A. AMINO SUGARS (GLYCOSAMINES). 412
B. GLYCAMINES AND DESOXY AMINO GLYKITOLS 419
6. COMBINATIONS OF SUGARS WITH AMINO ACIDS AND PROTEINS 420
A. PREPARATION 421
B. PROTEIN-CARBOHYDRATE COMPOUNDS AS SYNTHETIC ANTIGENS 425 X.
OLIGOSACCHARIDES 427
1. INDIVIDUAL OLIGOSACCHARIDES AND THEIR CLASSIFICATION 430
2. SYNTHESIS OF OLIGOSACCHARIDES 430
A. FROM NATURALLY OCCURRING OLIGOSACCHARIDES 430
B. CONDENSATION OF TWO MONOSACCHARIDE MOLECULES 432
3. DETERMINATION OF STRUCTURE 435
4. EASE OF ACID HYDROLYSIS 437
5. PREPARATION, PROPERTIES AND STRUCTURES OF SOME NATURAL OLIGOSAC
CHARIDES 438
IMAGE 7
CONTENTS
XV
CHAPTER PAGE
A. DISACCHARIDES 438
B. TRI- AND TET-RASACCHARIDES ; * 455
XI. NATURALLY OCCURRING GLYCOSIDES AND GLYCOSIDASES 459
1. ANTHOCYANIDIN AND FLAVANOL GLYCOSIDES 460
2. INDICAN 462
3. AGLYCONS RELATED TO PHENANTHRENE 463
A. CARDIAC GLYCOSIDES 463
B. SAPONINS 465
4. SUBSTITUTED-PHENYL GLYCOSIDES 466
5. VANILLIN AND COUMARIN GLUCOSIDES 467
6. CYANOGENETIC GLYCOSIDES 468
7. HYDROXYANTHRAQUINONE GLYCOSIDES 469
8. SUGAR COMPONENTS OF NATURAL PLANT GLYCOSIDES 470
9. THIOGLYCOSIDES AND THIOSUGARS 472
10. STREPTOMYCIN 474
1. INTRODUCTION AND CLASSIFICATION 474
2. MECHANISM OF ACTION 476
A. KINETIC EQUATIONS AND EFFECT OF SUBSTRATE CONCENTRATIONS 476 B.
MECHANISM 481
C. INFLUENCE OF HYDROGEN ION CONCENTRATION 483
D. MEASUREMENT OF ACTIVITY AND INFLUENCE OF ENZYME CONCEN TRATION 484
E. TEMPERATURE INFLUENCES 485
3. CHEMICAL COMPOSITION OF GLYCOSIDASES 487
A. 0-GLUCOSIDASE 487
B. YEAST INVERT-ASE 488
4. ENZYMES OF ALMOND EMULSIN 488
A. PREPARATION AND PURIFICATION 488
B. OPTIMAL PH 489
C. ENZYMES PRESENT 489
D. SPECIFICITY OF THE 0 -GLUCOSIDASE 492
5. OCCURRENCE AND SPECIFICITY OF OTHER 0-GLUCOSIDASES 499
6. ALFALFA AND COFFQE EMULSINS 502
7. YEAST GLYCOSIDASES 503
8. ENZYMIC SYNTHESIS OF GLYCOSIDES 507
9. IN VIVO SYNTHESIS OF GLYCOSIDES 509
10. BOURQUELOT BIOCHEMICAL DETERMINATION OF GLYCOSIDES AND OLIGOSAC
CHARIDES IN PLANT MATERIALS 510
XII. CLASSIFICATION AND DETERMINATION OF STRUCTURE OF THE
POLYSACCHARIDES.... 512 1. STRUCTURAL CLASSIFICATION OF THE
POLYSACCHARIDES 513
2. CLASSIFICATION BASED ON BIOLOGICAL FUNCTION 514
3. GENERAL PROCEDURES FOR THE DETERMINATION, OF THE STRUCTURES OF THE
POLYSACCHARIDES 514
A. END GROUP ANALYSIS 515
B. STRUCTURE OF A BACTERIAL DEXTRAN (AN EXAMPLE OF STRUCTURAL ANALYSIS)
519
IMAGE 8
1
XVI CONTENTS
CHAPTER PAGE *
4. GENERAL PROCEDURES FOR THE DETERMINATION OF THE MOLECULAR WEIGHT
OF HIGH POLYMERS 521
A. OSMOTIC PRESSURE METHOD 522
B. ULTRACENTRIFUGE 523
C. VISCOSITY MEASUREMENTS 525
D. LIGHT SCATTERING METHOD 527
E. OTHER METHODS 528
XIII. CELLULOSE 529
1. OCCURRENCE AND STRUCTURE 529
A. OCCURRENCE 529
B. CHEMICAL EVIDENCE FOR STRUCTURE 530
C. MOLECULAR WEIGHTS OF CELLULOSE AND DERIVATIVES 532
D. CRYSTALLINE STRUCTURE 536
A. UNIT CELL 537
B . SPATIAL MOLECULAR MODEL 538
C. MICELLAR STRUCTURE OF NATIVE CELLULOSE FIBERS 539
D . REGENERATED CELLULOSE 542
2. REACTIONS OF CELLULOSE 542
A. REACTIONS WITH BASES, ACIDS AND SALTS 543
*. AMMONIA, AMINES, QUATERNARY BASES, ETC 543
*. ACTION OF INORGANIC ACIDS AND SALTS 545
B. CELLULOSE XANTHATE 546
C. OXYCELLULOSE 547
D. CELLULOSE ESTERS 548
A. CELLULOSE NITRATES 549
B . CELLULOSE ACETATES 552
C. OTHER ESTERS 553
E. CELLULOSE ETHERS 554
A. METHYL AND ETHYL ETHERS 555
B . OTHER ETHERS 556
K. .METHYLENE DERIVATIVES 557
(.}. HYDROLYSIS BY ENZYMES 55S
XIV. THE STARCHES AND STARCH SUBSTANCES 560
1. INTRODUCTION 560
2. COMPOSITION 561
A. GENERAL COMPOSITION OF STARCH GRANULES 561
B. AMYLOSE AND AMYLOPECTIN 564
C. SOLUBLE STARCHES 569
D. CHEMICAL EVIDENCE FOR STRUCTURE 569
E. MOLECULAR WEIGHT OF STARCHES 570
F. END GROUP ASSAY AND MOLECULAR STRUCTURE 572
G. X-RAY DIFFRACTION STUDIES OF STARCH 576
3. STARCH ESTERS 577
4. ETHER DERIVATIVES. . 579
5. OXIDATION PRODUCTS 580
6. THE ACTION OF ENZYMES ON STARCH 5S2
A. SACCHAROGENIC OR ^-AMYLASES 586
B. LIQUEFYING AMYLASES 5S9
C. SCHARDINGER DEXTRINS 592
D. SYNTHETIC STARCHES AND PHOSPHOAMYLABES 594
IMAGE 9
CONTENTS XVII
CHAPTER * PAGE
7. INDUSTRIAL PREPARATION AND UTILIZATION OF STARCH AND STARCH PRODUCTS
597
S. GLYCOGEN 599
XV. POLYURONIDES, HEMICELLULOSES, PLANT GUMS, MICROBIAL POLYSACCHARIDES
AND RELATED SUBSTANCES 602
1. HOMOPOLYSACCHARIDES 602
A. GLUCOSE POLYMERS 602
B. FRUCTOSE POLYMERS 604
C. GALACTURONIC ACID POLYMERS (PECTINS) 607
D. POLYMERS OF OTHER HEXOSES, PENTOSES AND URONIC ACIDS 614 E. POLYMERS
OF GLUCOSAMINE (CHITIN) 619
2. HETEROPOLYSACCHARIDES DERIVED FROM SEVERAL SUGAR TYPES 620
A. HEMICELLULOSES AND CELL-WALL POLYSACCHARIDES 620
B.- MUCILAGES, GUMS AND GEL-FORMING SUBSTANCES 630
G. POLYSACCHARIDES ASSOCIATED WITH PROTEINS AND/OR MICRO ORGANISMS 639
D. MUCOPOLYSACCHARIDES 640
E. BACTERIAL AND FUNGAL POLYSACCHARIDES 642
F. GLYCOPROTEINS 646
AUTHOR INDEX 649
SUBJECT INDEX 669
|
| any_adam_object | 1 |
| author | Pigman, William Ward 1910-1977 Goepp, Rudolph Maximilian |
| author_GND | (DE-588)1036533816 |
| author_facet | Pigman, William Ward 1910-1977 Goepp, Rudolph Maximilian |
| author_role | aut aut |
| author_sort | Pigman, William Ward 1910-1977 |
| author_variant | w w p ww wwp r m g rm rmg |
| building | Verbundindex |
| bvnumber | BV002053904 |
| callnumber-first | Q - Science |
| callnumber-label | QD321 |
| callnumber-raw | QD321 |
| callnumber-search | QD321 |
| callnumber-sort | QD 3321 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VK 8580 |
| classification_tum | CHE 850f |
| ctrlnum | (OCoLC)489926757 (DE-599)BVBBV002053904 |
| dewey-full | 547.3 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.3 |
| dewey-search | 547.3 |
| dewey-sort | 3547.3 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| id | DE-604.BV002053904 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:39:33Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001343136 |
| oclc_num | 489926757 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-20 DE-12 DE-210 DE-29 DE-188 DE-83 |
| owner_facet | DE-19 DE-BY-UBM DE-20 DE-12 DE-210 DE-29 DE-188 DE-83 |
| physical | XVII, 748 S. graph. Darst. 24 cm |
| psigel | BSBQK0043 |
| publishDate | 1948 |
| publishDateSearch | 1948 |
| publishDateSort | 1948 |
| publisher | Acad. Press |
| record_format | marc |
| spelling | Pigman, William Ward 1910-1977 Verfasser (DE-588)1036533816 aut Chemistry of the carbohydrates by William Ward Pigman and Rudolph Maximilian Goepp Carbohydrate chemistry New York, NY Acad. Press 1948 XVII, 748 S. graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier Glucides ram Carbohydrates Kohlenhydrate (DE-588)4164517-0 gnd rswk-swf Kohlenhydrate (DE-588)4164517-0 s DE-604 Goepp, Rudolph Maximilian Verfasser aut DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001343136&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pigman, William Ward 1910-1977 Goepp, Rudolph Maximilian Chemistry of the carbohydrates Glucides ram Carbohydrates Kohlenhydrate (DE-588)4164517-0 gnd |
| subject_GND | (DE-588)4164517-0 |
| title | Chemistry of the carbohydrates |
| title_alt | Carbohydrate chemistry |
| title_auth | Chemistry of the carbohydrates |
| title_exact_search | Chemistry of the carbohydrates |
| title_full | Chemistry of the carbohydrates by William Ward Pigman and Rudolph Maximilian Goepp |
| title_fullStr | Chemistry of the carbohydrates by William Ward Pigman and Rudolph Maximilian Goepp |
| title_full_unstemmed | Chemistry of the carbohydrates by William Ward Pigman and Rudolph Maximilian Goepp |
| title_short | Chemistry of the carbohydrates |
| title_sort | chemistry of the carbohydrates |
| topic | Glucides ram Carbohydrates Kohlenhydrate (DE-588)4164517-0 gnd |
| topic_facet | Glucides Carbohydrates Kohlenhydrate |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001343136&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT pigmanwilliamward chemistryofthecarbohydrates AT goepprudolphmaximilian chemistryofthecarbohydrates AT pigmanwilliamward carbohydratechemistry AT goepprudolphmaximilian carbohydratechemistry |