Methods of organic elemental microanalysis:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Chapman and Hall
1962
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 511 S. graph. Darst. |
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Record in the Search Index
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| adam_text | Methods of
Organic Elemental
Microanalysis
G Ingram
ARIC
Research Laboratory
Courtaulds Limited
Maidenhead
i
Chapman amp; Hall
London: 1962
Contents
Preface vii
Part 1 The Elements Carbon and Hydrogen, Oxygen,
Nitrogen, the Halogens and Sulphur l
Introduction 3
References 5
1 Determination of Carbon and Hydrogen
The Pregl Method 6
The Combustion Tube Filling 9
Combustion Procedure 13
Determination of Carbon and Hydrogen by Rapid Combustion 20
Other Methods of Determining Carbon Dioxide and Water following
a Combustion Procedure 51
Special Methods 55
Determination of Carbon and Hydrogen in Fluorine-containing
Compounds 56
Determination of Carbon and Hydrogen in Volatile and Gaseous
Compounds 68
Determination of Carbon by Wet Combustion 73
Simultaneous Determination of Carbon, Hydrogen and
Other Elements 81
Absorption Tubes for Carbon and Hydrogen Determination 82
References 84
2 Determination of Oxygen 86
Sources of Error 96
The Gravimetric Method 100
Other Methods of Completing the Determination 101
Method of Analysis: Modified Procedure 102
References 104
3 Determination of Nitrogen 105
The Dumas Combustion Method 105
Recent Advances 127
Slow Combustion Procedure 130
Rapid Combustion Procedure 134
High Temperature Method 139
Determination of Nitrogen by the Kjeldahl Method 144
Decomposition Methods 148
Pretreatment Procedure 148
Distillation of Ammonia 149 xiii
Contents
Important Considerations 151
The Digestion 151
Distillation Apparatus 155
Determination of Ammonia 156
References 159
4 Determination of the Halogens 161
Decomposition Methods for Chlorine, Bromine and Iodine 161
The Rapid Combustion Method for Halogens 165
The Acid Decomposition Method for Chlorine and Bromine 172
Bomb Fusion Method for Chlorine and Bromine 176
The Oxygen-Flask Combustion Method 179
Procedures for Determining Inorganic Halogen 181
Precipitation Method for Chlorine and Biomine 183
Direct Gravimetric Method 188
Argentometric Titration of Chloride and Bromine 195
Mercuric Oxycyanide Method for Chlorine and Bromine 203
Amplified Titration Procedures 204
The Determination of Fluorine 209
Titration Method 211
Determination of Other Halogens in Fluorine-containing Compounds 216
Colorimetric Method 221
References 222
5 Determination of Sulphur 224
Decomposition Methods 224
The Rapid Combustion Method for Sulphur 227
Potassium Fusion Method 229
The Catalytic Hydrogenation Method 234
Bomb Fusion Method 237
Procedures for Determining Sulphur after Decomposition of
Organic Material 238
The Barium Sulphate Method after the Combustion 238
The Direct Gravimetric Method 242
Alkalimetric-Acidimetric Titration Methods 255
Titrimetric Method 256
Recent Advances in the Determination of Sulphur 258
Determination of Sulphur in Fluorine-containing Compounds 259
Xiv References 261
Contents
Part 2 Metals, Non-Metals and Some of the Less
Common Elements
Introduction 265
References 268
6 General Techniques 269
Decomposition of the Sample 269
Precipitation and Filtration 276
Centrifugal Technique of Separation 287
References 289
7 Determination of Metals and Non-Metals 290
Aluminium, Antimony, Arsenic, Barium, Beryllium, Bismuth, Boron,
Cadmium, Calcium, Cesium, Chromium, Cobalt, Copper, Ger
manium, Gold, Indium, Iron, Lead, Lithium, Magnesium, Mercury,
Nickel, Phosphorus, Platinum, Potassium, Rhinium, Rubidium,
Selenium, Silicon, Silver, Sodium, Strontium, Tellurium, Thallium,
Tin, Titanium, Zinc 290
Determination of Other Less Common Elements 377
Niobium, Osmium, Tantalum, Vanadium, Uranium, Zirconium 378
References 379
Part 3 Microgram Analysis
Introduction 385
References ; 388
8 The Techniques of Microgram Analysis 390
The Microgram Balance 390
Wet Oxidation Treatment of Samples 395
Liquid Transfer 396
Measuring Pipettes 398
Titrimetric Apparatus 398
References 400
9 Methods of Analysis 401
Determination of Carbon and Hydrogen 401
The Unterzaucher Method 404
The Wet Combustion Method for Carbon 413
Dry Combustion Method for Carbon 426
Determination of Nitrogen 429
The Diffusion Method 431
The Rapid Titrimetric Method 434
The Kirsten-Dumas Method 439 XV
Contents
Determination of Halogens 443
Combustion Method for Chlorine 444
Determination of Bromine 447
Determination of Iodine 451
Determination of Fluorine 452
Determination of Sulphur 454
Hydrogen Sulphide Methods 456
The Iodometric Method 460
Titrimetric Method: EDTA Procedure 461
Titrimetric Method: Lead Nitrate Titration 464
Determination of Phosphorus 465
References 468
Appendices
1 Preparation of Samples 471
Sampling 471
Drying Techniques 472
Purification of Samples 475
Determination of Water 480
References 483
2 Preparation of Standard Solutions 484
Primary Standards 484
Standard Solutions 486
Indicators 490
References 491
3 Reference Substances and Microanalytical Reagents 492
References 493
Index of Reference Substances for Use in Organic Micro
analysis 494
Author Index 497
General Index 503
xvi
|
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| indexdate | 2024-07-09T15:39:31Z |
| institution | BVB |
| language | English |
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| spelling | Ingram, Gerald Verfasser aut Methods of organic elemental microanalysis G. Ingram London Chapman and Hall 1962 XVI, 511 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemistry, Organic Microchemistry Mikroanalyse (DE-588)4169804-6 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Mikroanalyse (DE-588)4169804-6 s Organische Verbindungen (DE-588)4043816-8 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001341848&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ingram, Gerald Methods of organic elemental microanalysis Chemistry, Organic Microchemistry Mikroanalyse (DE-588)4169804-6 gnd Organische Verbindungen (DE-588)4043816-8 gnd |
| subject_GND | (DE-588)4169804-6 (DE-588)4043816-8 |
| title | Methods of organic elemental microanalysis |
| title_auth | Methods of organic elemental microanalysis |
| title_exact_search | Methods of organic elemental microanalysis |
| title_full | Methods of organic elemental microanalysis G. Ingram |
| title_fullStr | Methods of organic elemental microanalysis G. Ingram |
| title_full_unstemmed | Methods of organic elemental microanalysis G. Ingram |
| title_short | Methods of organic elemental microanalysis |
| title_sort | methods of organic elemental microanalysis |
| topic | Chemistry, Organic Microchemistry Mikroanalyse (DE-588)4169804-6 gnd Organische Verbindungen (DE-588)4043816-8 gnd |
| topic_facet | Chemistry, Organic Microchemistry Mikroanalyse Organische Verbindungen |
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