Electrochemistry of fused salts:
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| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Washington, DC
Sigma Pr.
1961
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Aus d. Russ. übers. |
| Beschreibung: | XV, 335 S. |
Internformat
MARC
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| 100 | 1 | |a Delimars'kij, Jurij K. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Electrochemistry of fused salts |c by Iu. K. Delimarskii and B. F. Markov |
| 264 | 1 | |a Washington, DC |b Sigma Pr. |c 1961 | |
| 300 | |a XV, 335 S. | ||
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Datensatz im Suchindex
| _version_ | 1804116449670725632 |
|---|---|
| adam_text | ELECTROCHE
OF
FUSED
SALTS
by
IU K Delimarskii
Institute for General and
Inorganic Chemistry and
Electrochemistry
Academy of Sciences
Ukranian S S R
iU IV
i r r
ISTRY
and
B F Markov
Physics Institute
Academy of Sciences
USSR
Translated from Russian by
ADAM PEIPERL
National Bureau of Standards
Translation edited by
REUBEN E WOOD
Professor of Chemistry
The George Washington University
THE SIGMA PRESS, PUBLISHERS
A Division of Medical and Technical Summaries, Inc
TABLE OF CONTENTS
Page
Preface ix
Introduction xi
Chapter 1 Electric Conductance and Ionic Transfer in
Fused Salts
General Background 1
Methods of Determining Conductance 2
Conductance of Single Fused Salts 5
Conductance of Fused Salts and the Periodic System 12
Temperature Dependence of Conductance 15
Conductance and Viscosity 18
Measurement of Conductance as a Method of Physico-
chemical Analysis 22
Temperature and Concentration Dependence of the
Conductance of Binary Fused Salt Systems 25
Ionic Transfer in Fused Salts 40
Transfereftce Numbers of Single Fused Salts 52
References 56
Chapter 2 Galvanic Cells with Fused Electrolytes
General Outline of Galvanic Cells in Melts 61
Concentration Cells with Fused Salts 62
Diffusion Potential in Concentration Cells 67
Jacobi—Daniell Galvanic Cells 72
Relationship Between the emf of Chemical Cells and
the emf of Jacobi—Daniell Cells 77
Use of emf Data on Jacobi—Daniell Cells 82
Summary of the Experimental Data on Jacobi-Daniell
Galvanic Cells • 85
Chemical Cells with Fused Salts 90
Calculation of the Thermodynamic Properties of Fused
Salts from the emf s of Chemical Cells 97
Thermodynamic Properties of Salts of Lower-Valence
Metals • • 100
Chemical Cells with Fused Salt Mixtures 103
v
Page
Survey of Experimental Work on Chemical Cells with
Fused Salt Mixtures 107
Attempt at Classifying Fused Salt Systems on the
Basis of the Thermodynamic Properties of the
Components 109
References 118
Chapter 3 Decomposition Potentials of Fused Salts
General Outline of the Decomposition Potentials of
Fused Salts 123
Calculation of Decomposition Potentials from Thermo-
chemical Data - 124
General Outline of the Experimental Methods of Deter
mining Decomposition Potentials 129
Determination of Decomposition Potentials by Measur
ing the emf s of Chemical Cells 130
Determination of Decomposition Potentials by Measur
ing the Polarization emf with the Use of the Commu
tator Method 131
Determination of Decomposition Potentials by Means
of I—V Curves 133
Determination of Decomposition Potentials with Auxil
iary Electrodes 137
Most Reliable Values of the Decomposition Potentials
of Fused Halides 138
Decomposition Potentials of Complex Fused Electro
lytes 140
Decomposition Potentials of Fused Oxygen-Containing
Salts 144
Decomposition Potentials and Chemical Interaction
Between the Components of a Melt 149
References 155
Chapter 4 Electrode Potentials in Fused Salts
Problem of a Reference Electrode for Fused Salts 159
Metal Electrodes of the First Kind 160
Hydrogen Electrode 162
Halogen Electrodes 163
Oxygen Electrode 165
Electrodes of the Second Kind Analogous to the Silver
Chloride Electrode 168
vi
Page
Glass Electrodes 173
Universal Reference Electrode for Fused Salts 175
Zero Electrode in the Electrochemistry of Fused
Salts Hydrogen Electrode Potentials 176
Sodium Zero Electrode 179
Single Electrode Potentials in Fused Salts, Calculated
by the Zero Electrode Method 180
Electrochemical Series in Fused Salts 181
Effect of the Anion on the Electrode Potentials of
Metals 190
Periodic Dependence of the Electrode Potentials of
Metals in Fused Salts on the Atomic Number 192
Electrode Discharge Potentials of Anions 194
Zero Charge Potentials 196
References 198
Chapter 5 Solubility of Metals in Fused Salts The Metal-
Fused Salt Equilibrium
General Background 201
Methods of Determining the Solubility of Metals in
Fused Salts Experimental Methods of Studying the;
Metal—Fused Salt Equilibrium 202
Nature of Solutions of Metals in Fused Salts 207
Theory of Metal—Fused Salt Equilibria 214
Mass-Action Law for Condensed Systems 219
Thermodynamic Calculation of Equilibria 222
Chemical Analysis of Equilibria 223
Electrochemical Study of Equilibria 224
Study of Equilibria by Thermal Analysis 229
Effect of Various Factors on Equilibrium 232
Brief Survey of Studied Metal—Fused Salt Equilibria 237
Equilibrium Constants and the Electromotive Series
of Metals 241
Equilibrium Constant and Structure of Fused Salts and
Metals 245
References 247
Chapter 6 Electrolysis and Polarization
Brief Discussion of the Electrolysis of Fused Salts 251
Faraday s Laws for Fused Salts 254
Polarization in the Electrolysis of Melts 255
vii
Page
Current Efficiency in the Electrolysis of Melts 257
References 263
Chapter 7 Electrode Processes in Fused Salts
Processes at Single Electrodes 265
Cathodic Deposition of Metals in the Solid Form 269
Cathodic Deposition of Liquid Metals 271
Simultaneous Discharge of Several Ions at the Cathode 275
Depolarization Phenomena at the Cathode 282
Anodic Phenomena 286
References 293 *
Chapter 8 Polarography of Fused Salts
General Outline of the Polarography of Fused Salts 297
Indicator Electrode for the Polarography of Fused
Salts 298
Second Electrode for the Polarography of Fused Salts 301
Reference Electrode for the Polarography of Fused
Salts 302
Dependence of the Height of the Polarographic Wave on
Various Factors 302
Equation of a Polarographic Wave Obtained in Fused
Salts When Solid Electrodes Are Used 305
Deviations from the Heyrovsky—Ilkovic Equation 310
Diffusion Coefficients in Fused Salts 314
Anode Polarography in Fused Salts 318
Place Occupied by Polarography in the Electrochem
istry of Fused Salts 320
Polarography and the Structure of Fused Electrolytes 325
References 329
Index of Authors 331
Translations of Names of Russian Journals 337
viii
|
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T15:38:41Z |
| institution | BVB |
| language | English |
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| physical | XV, 335 S. |
| psigel | TUB-nveb |
| publishDate | 1961 |
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| publisher | Sigma Pr. |
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| spelling | Delimars'kij, Jurij K. Verfasser aut Electrochemistry of fused salts by Iu. K. Delimarskii and B. F. Markov Washington, DC Sigma Pr. 1961 XV, 335 S. txt rdacontent n rdamedia nc rdacarrier Aus d. Russ. übers. Elektrochemie (DE-588)4014241-3 gnd rswk-swf Salzschmelze (DE-588)4051454-7 gnd rswk-swf Salzschmelze (DE-588)4051454-7 s Elektrochemie (DE-588)4014241-3 s DE-604 MARKOV, BORIS F. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001305810&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Delimars'kij, Jurij K. MARKOV, BORIS F. Electrochemistry of fused salts Elektrochemie (DE-588)4014241-3 gnd Salzschmelze (DE-588)4051454-7 gnd |
| subject_GND | (DE-588)4014241-3 (DE-588)4051454-7 |
| title | Electrochemistry of fused salts |
| title_auth | Electrochemistry of fused salts |
| title_exact_search | Electrochemistry of fused salts |
| title_full | Electrochemistry of fused salts by Iu. K. Delimarskii and B. F. Markov |
| title_fullStr | Electrochemistry of fused salts by Iu. K. Delimarskii and B. F. Markov |
| title_full_unstemmed | Electrochemistry of fused salts by Iu. K. Delimarskii and B. F. Markov |
| title_short | Electrochemistry of fused salts |
| title_sort | electrochemistry of fused salts |
| topic | Elektrochemie (DE-588)4014241-3 gnd Salzschmelze (DE-588)4051454-7 gnd |
| topic_facet | Elektrochemie Salzschmelze |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001305810&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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