Semiconducting ore minerals:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam u.a.
Elsevier
1975
|
| Schriftenreihe: | Developments in economic geology
4 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 415 S. graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Semiconducting ore minerals |c R. T. Shuey |
| 264 | 1 | |a Amsterdam u.a. |b Elsevier |c 1975 | |
| 300 | |a XII, 415 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 490 | 1 | |a Developments in economic geology |v 4 | |
| 650 | 4 | |a Minerais | |
| 650 | 4 | |a Minéralogie | |
| 650 | 4 | |a Roches - Propriétés électriques | |
| 650 | 4 | |a Semiconducteurs | |
| 650 | 4 | |a Ores | |
| 650 | 4 | |a Semiconductors | |
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Datensatz im Suchindex
| _version_ | 1804116411383021568 |
|---|---|
| adam_text | CONTENTS
INTRODUCTION ....................... 1
Definition of ore mineral, p. 1 — Occurrence of ore minerals,
p. 1 — Mineral conductivity, p. 4 — Significance of conduc-
tivity, p. 6 — References, p. 7.
PART ONE: PRINCIPLES
CHAPTER 1. ELECTRONIC STRUCTURE ............. 9
Energy units, p. 9 — Wave mechanics, p. 12 — Independent-
electron approximation, p. 15 — Atomic structure, p. 15 —
Electronic energy levels in ionic crystals, p. 19 — Packing
of spheres, p. 21 — Ionic radii, p. 24 — Transition metal
ions, p. 26 — Covalence, p. 28 — Delocalized electrons, p. 32
Energy bands, p. 34 — Bond type, p. 37 — Summary, p. 39 —
References, p. 40.
CHAPTER 2. CONDUCTION MECHANISM ............. 41
Measurement of conductivity or resistivity, p. 41 — Electri-
cal anisotropy, p. 44 — Drude theory, p. 45 — Electronic
units, p. 46 — Mobility, p. 48 — Hopping, p. 52 — Elec-
tron-hole equilibrium, p. 55 — Donors and acceptors, p. 57 —
Native atomic disorder, p. 58 — Defect association, p. 59 —
Screening, p. 61 — Defect equilibrium calculations, p. 61 —
Intrinsic semiconduction, p. 63 — Trapping equilibria, p. 64
— Compensation, p. 65 — Nonstoichiometry, p. 66 — Impurities,
p. 70 — Dielectrics, p. 71 — Conductivity versus temperature,
p. 72 — Resistivity versus pressure, p. 73 — Summary, p. 75
— References, p. 76.
CHAPTER 3. OTHER ELECTRONIC PROPERTIES ......... 78
Description of alternating-field electrical response, p. 78 —
Conduction versus polarization, p. 82 — Mechanisms of alter-
nating-field electrical response, p. 84 — Free-carrier absorp-
tion , p. 84 — Interband transitions, p. 86 — Lattice polari-
zation, p. 91 — Dipole orientation, p. 92 — Magnetic suscep-
tibility, p. 93 — Diamagnetism, p. 95 — Paramagnetism, p. 96
— Magnetic order, p. 99 — Galvanomagnetic effects, p. 101 —
Thermal conductivity, p. 105 — Thermoelectricity, p. 110 —
Summary, p. 113 — References, p. 114.
vm
SEMICONDUCTING ORE MINERALS
CHAPTER 4. HETEROGENEITY AND THE SEMICONDUCTOR-ELECTROLYTE
INTERFACE.........................Hö
Mixture formulas, p. 117 — Application to ore conductivity, p.
123 — Maxwell-Wagner effect, p. 125 — Observation of the Max-
well-Wagner effect, p. 128 — P-N junctions, p. 130 — Other
electronic interfaces, p. 134 — Composition of mineral waters,
p. 138 — Conductivity of mineral waters, p. 141 — Water in al-
ternating electric fields, p. 143 — Semiconductor-electrolyte
interface, p. 145 — Interface charge distribution, p. 146 —
Interface capacitance, p. 149 — Zeta potential and adsorption,
p. 150 — Electrode potential, p. 153 — Electrode potentials
of common sulfides, p. 157 — Reaction impedance, p. 162 —
Diffusion impedance, p. 164 — Equivalent circuits, p. 166 —
Induced polarization, p. 167 — Types of interface reactions,
p. 170 — Summary, p. 172 — References, p. 173.
PART TWO: ELEMENTS
CHAPTER 5. BISMUTH - Bi.................178
Occurrence, p. 178 — Related minerals, p. 178 — Resistivity,
p. 178 — Type, p. 179 — Structure, p. 179 — Bonding, p. 180
— Band structure, p. 180 — Band gap and overlap, p. 182 —
Effective mass, p. 182 — Mobility, p. 183 — Impurities, p.
183 — Summary, p. 184 — References, p. 185.
CHAPTER 6. COPPER - Cu.................187
Occurrence, p. 187 — Related minerals, p. 187 — Resistivity
and type, p. 187 — Structure, p. 188 — Bonding, p. 188 —
Band structure, p. 189 — Effective mass, p. 189 — Mobility,
p. 190 — Impurities, p. 190 — Summary, p. 191 — References,
p. 192.
CHAPTER 7. GRAPHITE - C.................193
Occurrence, p. 193 — Related minerals, p. 193 — Resistivity,
p. 193 -- Type, p. 195 — Structure, p. 196 — Bonding, p. 197
— Band structure, p. 198 — Band overlap, p. 200 — Effective
mass, p. 200 — Mobility, p. 200 — Structural imperfections,
p. 201 — Impurity, p. 201 — Summary, p. 202 — References,
p. 202.
CONTENTS ix
PART THREE: SULFIDES
CHAPTER 8. ARSENOPYRITE - FeAsS ............. 205
Occurrence, p. 205 — Related minerals, p. 205 — Resistivity
and type, p. 205 — Marcasite structure, p. 206 — Arsenopyrite
structure, p. 207 — Magnetism, p. 208 — Bonding, p. 209 —
Band structure, p. 211 — Conductivity activation energy, p.
212 — Energy gap, p. 213 — Mobility, p. 214 — Nonstoichi-
ometry, p. 214 — Impurities, p. 216 — Löllingite, p. 216 —
Safflorite, p. 217 — Summary, p. 218 — References, p. 218.
CHAPTER 9. BORNITE - Cu5FeS4 .............. 221
Occurrence, p. 221 — Related minerals, p. 221 — Resistivity,
p. 221 — Type, p. 222 — Structure, p. 223 — High temperature
resistivity, p. 224 — Bonding, p. 224 — Magnetism, p. 225 —
Band structure, p. 226 — Defect ionization, p. 226 — Nonstoi-
chiometry, p. 227 — Impurity, p. 227 — Summary, p. 228 —
References, p. 228.
CHAPTER 10. CHALCOCITE - Cu9 S.............230
Occurrence, p. 230 — Mineralogy, p. 230 — Resistivity and
type, p. 231 — Structure, p. 232 — Ionic mobility p. 233 —
Bonding, p. 234 — Band structure, p. 234 — Hole mobility,
p. 235 — Effective mass, p. 236 — Defect ionization, p. 237
— Nonstoichiometry and carrier concentration, p. 237 — Sum-
mary, p. 238 — References, p. 239.
CHAPTER 11. CHALCOPYRITE - CuFeS2 ............ 242
Occurrence, p. 242 — Related minerals, p. 242 — Resistivity
and type, p. 243 — Structure, p. 244 — Magnetic structure,
p. 245 — Bonding, p. 245 — Band gap, p. 246 — Band struc-
ture, p. 246 — Mobility, p. 247 — Defect ionization, p. 247
— Nonstoichiometry: metal/sulfur ratio, p. 248 — Nonstoi-
chiometry: Cu/Fe ratio, p. 249 — Impurities, p. 249 — Cu-
banite, p. 250 — Summary, p. 251 — References, p. 251.
CHAPTER 12. COVELLITE - CuS...............254
Occurrence, p. 254 — Related minerals, p. 254 — Resistivity,
p. 254 — Structure, p. 255 — Bonding, p. 255 — Band struc-
ture, p. 256 — Nonstoichiometry and impurity, p. 258 — Sum-
mary, p. 258 — References, p. 259.
SEMICONDUCTING ORE MINERALS
CHAPTER 13. GALENA - PbS................260
Occurrence, p. 260 — Related minerals, p. 260 — Resistivity
and type, p. 261 — Structure, p. 262 — Bonding, p. 262 —
Band structure, p. 263 — Energy gap, p. 263 — Fourfold de-
generacy of electronic states, p. 26A — Effective mass, p.
264 — Mobility, p. 265 — Carrier concentration, p. 266 —
Nonstoichiometry, p. 268 — Impurities, p. 270 — Summary,
p. 272 — References, p. 273.
CHAPTER 14. MOLYBDENITE - MoS2............276
Occurrence, p. 276 — Related minerals, p. 276 — Resistivity,
p. 276 — Type, p. 277 — Anisotropy, p. 277 — Frequency ef-
fect, p. 278 — Structure, p. 278 — Bonding, p. 279 — Energy
gap, p. 280 — Band structure, p. 281 — Effective mass, p.
282 — Hole mobility, p. 282 — Electron mobility, p. 284 —
Defect ionization, p. 285 — Nonstoichiometry, p. 285 — Im-
purities, p. 286 — Summary, p. 286 — References, p. 287.
CHAPTER 15. PYRRHOTITE - Fe, S............ 290
Occurrence, p. 290 — Related minerals, p. 290 — Composition,
p. 290 — Resistivity, p. 292 — Anisotropy, p. 292 — Type,
p. 293 — Crystal structure, p. 294 — Magnetic structure, p.
296 — Bonding, p. 297 — Band structure, p. 298 — Impurities,
p. 300 — Summary, p. 300 — References, p. 301.
CHAPTER 16. PYRITE - FeS2...............304
Occurrence, p. 304 — Related minerals, p. 304 — Resistivity
and type, p. 305 — Structure, p. 306 — Bonding, p. 307 —
Band structure, p. 307 — Energy gap, p. 308 — Mobility, p.
308 — Carrier concentration, p. 309 — Defect ionization, p.
310 — Nonstoichiometry, p. 310 — Pyrite geothermometer, p.
312 — Impurities, p. 312 — Electrical properties of related
minerals, p. 313 — Summary, p. 315 — References, p. 316.
CHAPTER 17. SPHALERITE - ZnS..............319
Occurrence, p. 319 — Related minerals, p. 319 — Resistivity,
p. 319 — Structure, p. 320 — Bonding, p. 320 — Band struc-
ture, p. 321 — Effective mass, p. 322 - Mobility, p. 322 —
Defect chemistry, p. 323 — Impurity conduction, p. 324 —
Summary, p. 325 — References, p. 325.
CONTENTS xi
CHAPTER 18. MISCELLANEOUS SULFIDES ........... 328
Argentite - Ag S, p. 328 — Cinnabar - HgS, p. 330 — Enargite
- Cu AsS,, p. 331 — Pyrargyrite - Ag3SbS , Proustite - Ag AsS ,
p. 332 — Skutterudite - CoAs3, p. 333 — Stibnite - St 2S ,
Bismuthinite - Bi„S3, p. 334 — Tetrahedrite - Cu sy^, Ten-
nantite - Cu, As,S , p. 336 — References, p. 337.
PART FOUR: OXIDES
CHAPTER 19. CASSITERITE - SnO2.............340
Occurrence, p. 340 — Related minerals, p. 340 — Resistivity,
p. 340 — Type, p. 341 — Structure, p. 341 — Bonding, p. 342
— Band structure, p. 343 — Effective mass, p. 344 — Mobility,
p. 344 — Nonstoichiometry, p. 345 — Impurities, p. 345 —
Summary, p. 346 — References, p. 346.
CHAPTER 20. CUPRITE - Cu2O...............349
Occurrence, p. 349 — Type and resistivity, p. 349 — Structure,
p. 349 — Bonding, p. 350 — Band structure, p. 350 — Mobility,
p. 351 — Nonstoichiometry, p. 353 — Impurities, p. 354 —
Summary, p. 354 — References, p. 354.
CHAPTER 21. HEMATITE - a-Fe2O3 ............. 357
Occurrence, p. 357 — Related minerals, p. 357 — Resisitivity,
p. 357 —• Type and anisotropy, p. 358 — Structure, p. 358 —
Magnetic structure, p. 359 — Bonding, p. 360 — Band structure,
p. 360 — Resistivity activation energy, p. 361 — Mobility, p.
363 — Nonstoichiometry, p. 364 — Impurities, p. 365 — Ilmen-
ite, p. 367 — Summary, p. 368 — References, p. 368.
CHAPTER 22. MAGNETITE - Fe^.............371
Occurrence, p. 371 — Related minerals, p. 371 — Resistivity, p.
371 — Type, p. 373 — Structure, p. 373 — Magnetic structure,
p. 375 — Bonding, p. 375 — Band structure, p. 376 — Mobility,
p. 377 — Nonstoichiometry and maghemite, p. 378 — Titanomag-
netite, p. 379 — Exsolution, p. 380 — Other impurities, p.
382 — Verwey s rule, p. 383 — Jacobsite and hausmannite, p.
383 — Chromite, p. 384 — Summary, p. 384 — References, p.
385.
xii SEMICONDUCTING ORE MINERALS
CHAPTER 23. PYROLUSITE - MnO2..............389
Occurrence, p. 389 — Related minerals, p. 389 — Resistivity
and type, p. 389 — Structure, p. 390 — Magnetic structure,
p. 391 — Electric order (?), p. 391 — Bonding, p. 392 —
Band structure, p. 392 — Mobility, p. 393 — Nonstoichiometry,
p. 393 — Impurities, p. 394 — Summary, p. 395 — References,
p. 395.
CHAPTER 24. RUTILE - TiO2................397
Occurrence, p. 397 — Related minerals, p. 397 — Resistivity,
type and anisotropy, p. 397 — Structure, p. 398 — Bonding,
p. 399 — Band structure, p. 399 — Mobility, p. 400 — Non-
stoichiometry, p. 401 — Impurity, p. 403 — Summary, p. 405
— References, p. 405.
SUBJECT INOEX ...................... 408
MINERAL IUDEX ...................... 412
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| illustrated | Illustrated |
| indexdate | 2024-07-09T15:38:05Z |
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| language | English |
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| physical | XII, 415 S. graph. Darst. |
| publishDate | 1975 |
| publishDateSearch | 1975 |
| publishDateSort | 1975 |
| publisher | Elsevier |
| record_format | marc |
| series | Developments in economic geology |
| series2 | Developments in economic geology |
| spelling | Shuey, R. T. Verfasser aut Semiconducting ore minerals R. T. Shuey Amsterdam u.a. Elsevier 1975 XII, 415 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Developments in economic geology 4 Minerais Minéralogie Roches - Propriétés électriques Semiconducteurs Ores Semiconductors Amorpher Halbleiter (DE-588)4001756-4 gnd rswk-swf Erzmineralien (DE-588)4153014-7 gnd rswk-swf Erzmineralien (DE-588)4153014-7 s Amorpher Halbleiter (DE-588)4001756-4 s DE-604 Developments in economic geology 4 (DE-604)BV000022940 4 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001283323&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Shuey, R. T. Semiconducting ore minerals Developments in economic geology Minerais Minéralogie Roches - Propriétés électriques Semiconducteurs Ores Semiconductors Amorpher Halbleiter (DE-588)4001756-4 gnd Erzmineralien (DE-588)4153014-7 gnd |
| subject_GND | (DE-588)4001756-4 (DE-588)4153014-7 |
| title | Semiconducting ore minerals |
| title_auth | Semiconducting ore minerals |
| title_exact_search | Semiconducting ore minerals |
| title_full | Semiconducting ore minerals R. T. Shuey |
| title_fullStr | Semiconducting ore minerals R. T. Shuey |
| title_full_unstemmed | Semiconducting ore minerals R. T. Shuey |
| title_short | Semiconducting ore minerals |
| title_sort | semiconducting ore minerals |
| topic | Minerais Minéralogie Roches - Propriétés électriques Semiconducteurs Ores Semiconductors Amorpher Halbleiter (DE-588)4001756-4 gnd Erzmineralien (DE-588)4153014-7 gnd |
| topic_facet | Minerais Minéralogie Roches - Propriétés électriques Semiconducteurs Ores Semiconductors Amorpher Halbleiter Erzmineralien |
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