Complex compounds of transuranium elements:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
New York
Consultants Bureau
1962
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 195 S. Ill., graph. Darst. |
Internformat
MARC
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| 245 | 1 | 0 | |a Complex compounds of transuranium elements |c by Anna D. Gel'man... Authorized transl. from the Russian by C. Nigel Turton and Tatiana I. Turton |
| 264 | 1 | |a New York |b Consultants Bureau |c 1962 | |
| 300 | |a 195 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 650 | 7 | |a Quimica inorganica |2 larpcal | |
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Datensatz im Suchindex
| _version_ | 1804116387636969472 |
|---|---|
| adam_text | COMPLEX COMPOUNDS
OF TRANSURANIUM ELEMENTS
by
A D Gel man, A I Moskvin,
L M Zaitsev, M P Mefod eva
Authorized translation from the Russian
by
C Nigel Turton, B Sc , Ph D
and Tatiana I Turton, B A
CONSULTANTS BUREAU
NEWYORK
CONTENTS
•o Chapter I
COMPLEX FORMATION BY NEPTUNIUM IN AQUEOUS SOLUTIONS
Complex Formation by Np (III) 1
Complex Formation by Np(IV) 2
Complex Formation by Np(IV) with Anions of Monobasic Acids 2
Complex Formation by Np(IV) with Anions of Dibasic Acids 2
Complex Formation by Np(IV) with Anions of Polybasic Organic
Acids 5
Complex Formation by Np(V) 8
Complex Formation by Np(V) with Anions of Monobasic Acids 8
Complex Formation by Np(V) with Anions of Dibasic Acids 9
Complex Formation by Np(V) with Anions of Polybasic Organic
Acids 11
Complex Formation by Np(VI) 14
Complex Formation by Np(VI) with Anions of Monobasic Acids 14
Complex Formation by Np(VI) with Anions of Dibasic Acids 17
Complex Compounds of Neptunium Isolated in a Solid State 19
Oxalates 19
Carbonates 20
Acetates 20
Fluorides 20
Literature Cited 20
Chapter II
COMPLEX FORMATION BY PLUTONIUM IN AQUEOUS SOLUTIONS
Types of Complex Compound in Aqueous Solutions 23
Hydrolysis of Hydrated Plutonium Ions in Various Oxidation States 25
Hydrolysis of Pu(III) Ions 25
Hydrolysis of Pu(IV) Ions 25
Hydrolysis of Pu(V) Ions 27
Hydrolysis of Pu(VI) Ions 27
Acido Complex Formation by Plutonium in Various Oxidation States 29
Acido Complex Formation by Pu(III) 30
Complexes of Pu(HI) with Anions of Monobasic Acids 31
Relative Tendency of Anions of Monobasic Acids to
Form Complexes with Pu(III) 32
Complexes of Pu(III) with Anions of Dibasic Acids 32
Relative Tendency of Anions of Dibasic Acids to Form
Complexes with Pu (III) 46
Complexes of Pu(III) with Anions of Polybasic Acids 46
Acido Complex Formation^by Pu(IV) 51
Complexes of Pu(IV) with Anions of Monobasic Acids 52
Relative Tendency of Anions of Monobasic Acids to
Form Complexes with Pu(IV) 54
Complexes of Pu(IV) with Anions of Dibasic Acids 55
Complexes of Pu(IV) with Anions of Polybasic Acids 61
Relative Tendency of Anions of Polybasic Acids to
Form Complexes with Pu(IV) 64
Acido Complex Formation by Pu(V), 65
Relative Tendency of Anions of Acids to Form
Complexes with Pu02+ 67
Acido Complex Formation by Pu(VI) 67
Complexes of Pu(VI) with Anions of Monobasic Acids 67
Complexes of Pu(VI) with Anions of Dibasic Acids 73
Relative Tendency of Anions of Various Acids to Form
Complexes with Pu(VI) 80
Relative Tendency of Pu(III, IV, V, and VI) to Form Complexes
with Anions of Some Acids 83
Some Physicochemical Properties of Plutonium Compounds in Aqueous
Solutions 86
Plutonium Oxalates 87
Acid Properties of Pu(IV) Oxalate 87
Solubility Products of Tri-, Tetra-, and Hexavalent
Plutonium Oxalates 89
Pu(IV) Phosphates 92
Pu(VI) Acetates 95
Pu(VI) Phosphates 95
Solubility and Solubility Products of Some Plutonium Compounds 95
Oxidation-Reduction Properties and Complex Formation of
Plutonium Ions 97
Oxidation-Reduction Potentials 97
Equilibria between Valence States 99
Literature Cited 104
Chapter III
SYNTHESIS AND PROPERTIES OF SOME COMPLEX COMPOUNDS
OF TRI-, TETRA-, AND HEXAVALENT PLUTONIUM
Acido Complexes of Trivalent Plutonium 116
Acido Complexes of Tetravalent Plutonium 116
Complexes of Tetravalent Plutonium with Anions of Monobasic
Acids 117
Complexes of Tetravalent Plutonium with Anions of Dibasic
Acids 121
Acido Complexes of Hexavalent Plutonium 142
Some Sparingly Soluble Plutonium Compounds 146
Pu (III) Oxalate 146
Pu(IV) Oxalate 147
Plutonyl Oxalate 147
Pu (III) Hydroxide 148
Pu(IV) Hydroxide 148
Ammonium Diplutonate (NH4)2Pu207 148
Plutonium Dioxide 149
Pu(IV) Peroxide 149
Literature Cited 150
Chapter IV
COMPLEX FORMATION BY TRANSPLUTONIUM ELEMENTS IN SOLUTION
t
Complex Formation by Americium 153
Complex Formation by Am (III)
Complex Formation by Am (III) in Solutions of
Inorganic Acids HC104, HNOs, HC1, and H2S04 154
Fluoride Complexes of Am (III) 156
Thiocyanate Complexes of Am (III) 156
Carbonate and Acetate Complexes of Am (III) 156
Oxalate Complexes of Am (III) 156
Complexes of Am (III) with Anions of Ethylenediami-
netetraacetic Acid 160
Complexes of Am (III) with Anions of Citric, Tartaric,
Lactic, and oi-Hydroxyisobutyric Acids 162
Complex Formation by Am(V) 165
Complex Formation by Am (VI) 166
Complex Formation by Curium 167
Complex Formation by Berkelium 168
Complex Formation by Californium
Complex Formation by Einsteinium, Fermium, and Mendelevium,
Literature Cited
Chapter V
APPLICATION OF COMPLEX COMPOUNDS IN THE ISOLATION
AND SEPARATION OF TRANSURANIUM ELEMENTS
Isolation of Plutonium and Neptunium from Irradiated Uranium 175
Methods Based on Coprecipitation 175
Extraction Methods 176
Ion-Exchange Methods 181
Fractional Distillation 183
Isolation and Identification of Transplutonium Elements 183
Ion-Exchange Chromatography 184
Methods Based on Coprecipitation 187
Extraction Methods 188
Literature Cited 190
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| id | DE-604.BV001946629 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:37:42Z |
| institution | BVB |
| language | English |
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| oclc_num | 761180 |
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| owner_facet | DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-210 DE-91G DE-BY-TUM |
| physical | 195 S. Ill., graph. Darst. |
| publishDate | 1962 |
| publishDateSearch | 1962 |
| publishDateSort | 1962 |
| publisher | Consultants Bureau |
| record_format | marc |
| spelling | Kompleksnye soedinenija transuranovych ėlementov Complex compounds of transuranium elements by Anna D. Gel'man... Authorized transl. from the Russian by C. Nigel Turton and Tatiana I. Turton New York Consultants Bureau 1962 195 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Quimica inorganica larpcal Transuranium elements Komplexe (DE-588)4133953-8 gnd rswk-swf Transurane (DE-588)4185938-8 gnd rswk-swf Transurane (DE-588)4185938-8 s Komplexe (DE-588)4133953-8 s DE-604 Gel'man, Anna D. Sonstige oth Turton, C. Nigel Sonstige oth HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001268917&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Complex compounds of transuranium elements Quimica inorganica larpcal Transuranium elements Komplexe (DE-588)4133953-8 gnd Transurane (DE-588)4185938-8 gnd |
| subject_GND | (DE-588)4133953-8 (DE-588)4185938-8 |
| title | Complex compounds of transuranium elements |
| title_alt | Kompleksnye soedinenija transuranovych ėlementov |
| title_auth | Complex compounds of transuranium elements |
| title_exact_search | Complex compounds of transuranium elements |
| title_full | Complex compounds of transuranium elements by Anna D. Gel'man... Authorized transl. from the Russian by C. Nigel Turton and Tatiana I. Turton |
| title_fullStr | Complex compounds of transuranium elements by Anna D. Gel'man... Authorized transl. from the Russian by C. Nigel Turton and Tatiana I. Turton |
| title_full_unstemmed | Complex compounds of transuranium elements by Anna D. Gel'man... Authorized transl. from the Russian by C. Nigel Turton and Tatiana I. Turton |
| title_short | Complex compounds of transuranium elements |
| title_sort | complex compounds of transuranium elements |
| topic | Quimica inorganica larpcal Transuranium elements Komplexe (DE-588)4133953-8 gnd Transurane (DE-588)4185938-8 gnd |
| topic_facet | Quimica inorganica Transuranium elements Komplexe Transurane |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001268917&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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