Biochemical and clinical applications of thermometric and thermal analysis:
Saved in:
| Other Authors: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier
1982
|
| Series: | Wilson and Wilson's comprehensive analytical chemistry
12,B : Thermal analysis |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | XVII, 254 S. Ill., graph. Darst. |
| ISBN: | 0444420622 |
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| 245 | 1 | 0 | |a Biochemical and clinical applications of thermometric and thermal analysis |c ed. by Neil D. Jespersen |
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 1982 | |
| 300 | |a XVII, 254 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Wilson and Wilson's comprehensive analytical chemistry |v 12,B : Thermal analysis | |
| 500 | |a Literaturangaben | ||
| 650 | 7 | |a Biochimie - technique |2 ram | |
| 650 | 7 | |a Calorimètre et calorimétrie |2 ram | |
| 650 | 7 | |a Chimie analytique |2 ram | |
| 650 | 7 | |a Chimie clinique |2 ram | |
| 650 | 4 | |a Biochemistry |x Technique | |
| 650 | 4 | |a Calorimetry | |
| 650 | 4 | |a Chemistry, Analytical | |
| 650 | 4 | |a Clinical chemistry |x Technique | |
| 650 | 4 | |a Thermal analysis | |
| 650 | 4 | |a Thermometric titration | |
| 700 | 1 | |a Jespersen, Neil D. |0 (DE-588)142895806 |4 edt | |
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Record in the Search Index
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| adam_text | Wilson and Wilson s
COMPREHENSIVE ANALYTICAL CHEMISTRY
Edited by
G SVEHLA, PH D,D SC ,FRSC
Reader in Analytical Chemistry
The Queen s University of Belfast
VOLUME XII
THERMAL ANALYSIS
FWRTB
BIOCHEMICAL AND CLINICAL
APPLICATIONS OF
THERMOMETRIC AND THERMAL
ANALYSIS
EDITED BY
NEIL D JESPERSEN
St John s University, Jamaica, NY, U S A
ELSEVIER SCIENTIFIC PUBLISHING COMPANY
AMSTERDAM OXFORD NEW YORK
XI
Contents
Chapter1
INTRODUCTION1
Chapter2
TITRATIONANDFLOWCALORIMETRY:INSTRUMENTATIONANnOATACALCULATION3
(DelbertJEatough,ReedMIzattandJames-1Christensen)
1Introduction3
2DescriptionofTechniques3
3InstrumentationandDataReduction5
31IsoperibolTitrationCalorimetry5
311EquipmentDescription5
312CalibrationandDataAnalysis10
3121CalibrationofTitrantDeliverySystem10
3122CalibrationoftheTemperatureSensingDevice10
3123DeterminationoftheEnergyEauivalentofthe
ReactionVessel10
3124AnalysisoftheThermogram13
3125CorrectionTermsforNon-ChemicalEffectsin
theReactionVessel14
3126CorrectionTermsfortheTemperatureDifference
betweenTitrantandTitrate16
32IsothermalTitrationCalorimetry17
3?1EquipmentDescription17
322CalibrationandDataAnalysis20
3221CalibrationoftheTitrantpelivervSystem20
3222DeterminationoftheEnergyEquivalentofthe
ControlHeater20
3223Non-ChemicalEnergyTerm;21
33FlowCalorimetry21
331IsothermalFlowCalorimeter22
332HeatConductionFlowCalorimeter23
34ComparisonofInstruments24
4CalculationofAHandKValues26
41CalculationofCorrectedQcValues26
411DilutionofTitrantandTitrate26
412HeatContributionsfromOtherReactions27
413CalculationoftheEnergyReleasedbyReaction(s)forwhich
AHandKValuesaretobeDeternined28
i
XII
42CalculationofAHValues28
43CalculationofKValues29
431DescriptionoftheTechnique29
432ApproximateCalculationof Values31
433EvaluationofKValuesbynLeastSquaresTechnique33~
434EvaluationofKValuesUsingCalorimetricandFree
LigandConcentrationData34
5Sumrary35
6Symbols36
References37
Chapter3
FUNDAMENTALSOFDIFFERENTIALSCANNINGCALORIMETRY:INSTRUMENTSANDj
THEORY39i
(HenryTGaud)
1Introduction39
2Instrumentation40
3Thermodynamics44
References52
Chapter4
FLOWREACTORS53
(RichardSSchifreen)
1Introduction53
lJLHistory53
12SuitabilityforClinicalAnalysis54
2ConstructionoftheFlowEnthalpimeter55
21ReactorConfiguration56
22InstrumentComponents56
221TheBathHousing56
222BufferDeliverySystems58
223Valves,TubingandConnections58
224ThermalEquilibrationCoils58
225TheThermalReactor59
226DetectorElectronics60
23ComponentEvaluation61
3TheoreticalAspects61
31ReactorModels62
311PurePlugFlowReactor62
312PerfectlyWell-MixedReactor63
313TheAxiallyDispersedReactor64
XIII
4ExperimentalOperation65
41SampleVolume65
42FlowRates67
43SampleConcentration68
44Pre-ColumnMixingVolume68
5Applications69
51DevelopingaMethod70
511PredictingSensitivity70
512ReducingBaselineNoise70
513PreventingDoublePeaks71
52ClinicalMethods71
References74
Chapter5
THERMISTORPROBES75
(RobertMlannielloandNeilDJespersen)
1Introduction75
2EnzymeProbes75
21PotentiometricEnzymeProbes75
22AmperometricEnzymeProbes77
3ThermistorProbes78
31ThermalMethodsinEnzymaticAnalysis78
32ThermalEnzymeProbe79
33EnzymeBoundThermistor83
34Th^mistorEnzymeProbe86
35ThermalEnzymeProbe-FlowThroughCell90
4TheoreticalDescriptionofThermistorProbeResponse92
41EnzymeKinetics92
42ThermistorConstructionandOperation94
43MathematicalModelsforThermistorProbeResponse95
431ThermalEnzymeProbe95
432Enzyme-BoundThermistor97
433ThermistorEnzymeProbe98
5Conclusion100
References101
Chapter6
INORGANICIONSANDSMALLORGANICSPECIES103
(NeilDJespersen)
1Introduction103
XIV
2GeneralConsiderations103
3MajorIonicSpecies:Na+,K+,CI,Ma+,Ca++104
31SodiumIonAnalysis104
32PotassiumIonAnalysis104
33ChlorideIonAnalysis105
34CalciumandMagnesiumIonAnalysis106
4IonsRelatedtothepHofBiologicalFluids107
41SpeciesRelatedtoCO2107
42PhosphateSpecies107
5SmallOrganicMoleculesandIons108
51Lactate,SalicylateandUricAcid108
52Glucose,UreaandTriglycerides108
53KetoneBodies109
6NitrogenCompounds109
7SolidMaterials109
8Conclusions109
References110
Chapter7
TITRATIONANDFLOWCALORIMETRY:APPLICATIONTOPROTEINSANDLIPIDS112
(DelbertJEatough,SelwynJRehfeld,ReedMIzattand
JamesJChristensen)
1Introduction112
2LeastSquaresAnalysisofData112
2*1General112
22BindingofAdenosineDiphosphatetoBovineLiverGlutamate
Dehydrogenase112
2+
23BindingofZnand1,10-Phenanthrolineto-Thermolysin114
24BindingofTritontoBovineSerumAlbumin116
3EstimationofKandAHforEnzyme-InilibitorBindina 118
31General118
32BindingofAdenosineDiphosphatetoBovineLiverGlutamate
Dehydrogenase119
33BindingofN-AcetylglucosaminetoLysosyme121
4CombinationofCalorimetricandOtherDatatoCalculate
AHandKValues123
41General 123
42ProtonIonizationfromProteins123
421Instrumentation123
422DataAnalysis126
43MetalIonBindingtoPhosphatidyIserineVesicles(PSV)132
XV
5Summary134
Referencesi134
Chapter8
-ENZYMATICENTHALPIMETRY136
(JKeithGrime)
1Introduction136
2Nomenclature136
3TheDevelopmentofEnzymaticEnthalpimetry138
4TheDeterminationofEnzymeActivity139
41EnzymeKineticConsiderations139
42EnzymeActivity-TemperatureChangeRelitionshins141
43EnthalpimetricMethodology143
431FlowEnthalpimetry143
432KineticInjectionEnthalpimetry/BalchMixingCalorimetry144
433Fixed-TimeKineticEnthalpimetry148
434ChemicalandBiochemicalAmplificationofReaction
Enthalpies152
44Applications154
441Hydrolases154
442Oxidoreductases155
443Transferases156
444Dehydrogenases156
445Lyases156
5DeterminationofSubstrateConcentration156
51EnzymeKineticsandMethodologicalPrinciples156
511KineticApproach156
512EquilibriumApproach157
52Applications158
521SerumCholesterolandCholesterolTsters158
522SerumUricAcid159
523SerumGlucose159
524Penicillins160
525IodideinthePresenceofOtherHalides160
6TheDeterminationofInhibitorConcentration 161
61TypesofEnzymaticInhibition161
611IrreversibleorReversibleInhibition161
62InhibitionKineticsandExperimentalDesign162
621Non-CompetitiveInhibition162
XVI
622CompetitiveInhibition163
623IrreversibleInhibition163
63Applications164
631Non-CompetitiveInhibitors164
632CompetitiveInhibitors165
633IrreversibleInhibitors166
7DeterminationofBiochemicalConstants168
71SignificanceofK,V,andK1683mmax^
72GraphicalMethodfortheDeterminationofK,V,andK168 IU lllo A I
73EnthalpimetricMethodology169
731InitialRateMeasurements169
732TangentialExtrapolation169
733IntegratedMichaelis-MentenEquation169
734MicrocalorimetricMeasurementoftheEnthalpyof
InhibitorBinding170
735FlowEnthalpimetry171
74Applications171
8EnzymaticEnthalpimetry-ARealisticAlternativeforClinical
andBiochemicalAnalysis?172
81EnzymeAssay172
82SubstrateDetermination173
83InhibitorDetermination173
84DeterminationofBiochemicalConstants173
References174
Chapter9
MICROCALORIMETRYINANTIBIOTICBIOASSAY176
(BrianFPerry)
1Introduction176
2ExperimentalConsiderations179
21Instrumentation179
211CommerciallyAvailableInstruments179
212CalorimetricTechniques180
22Inoculum185
221TestOrganism185
23AntibioticStandards190
24Medium190
25Aerobic-Anaerobic1,92
3AntibioticBioassaybyMicrocalorimetry193
31MicrocalorimetricMechanisticStudiesofMicroorganism-
AntibioticInteractions193
XVII
311Mycoplasma193
312Bacteria194
313Yeasts204
32QuantitativeAntibioticBioassay204
321Bacteria205
322Yeasts205
4ConcludingRemarks209
References212
Chapter10
DIFFERENTIALSCANNINGCALORIMETRYOFMACROMOLECULESANDMEMBRANES217
(SusanMabrey-Gaud)
1Introduction217
2PrinciplesofDifferentialScanningCalorimetry217
3ApplicationofDSCtoLipids219
31PureLipids221
32Vesicles224
33LipidMixtures225
34Summary228
4ApplicationofDSCtoMembranes228
41BiologicalMembranes228
42BacterialMembranes229
43ManmalianMembranes231
5ApplicationofDSCtoProteins233
6Conclusions?239
References 239
INDEX 249
|
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| discipline | Chemie / Pharmazie |
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| id | DE-604.BV001062298 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:23:16Z |
| institution | BVB |
| isbn | 0444420622 |
| language | English |
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| physical | XVII, 254 S. Ill., graph. Darst. |
| publishDate | 1982 |
| publishDateSearch | 1982 |
| publishDateSort | 1982 |
| publisher | Elsevier |
| record_format | marc |
| series | Wilson and Wilson's comprehensive analytical chemistry |
| series2 | Wilson and Wilson's comprehensive analytical chemistry |
| spelling | Biochemical and clinical applications of thermometric and thermal analysis ed. by Neil D. Jespersen Amsterdam [u.a.] Elsevier 1982 XVII, 254 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wilson and Wilson's comprehensive analytical chemistry 12,B : Thermal analysis Literaturangaben Biochimie - technique ram Calorimètre et calorimétrie ram Chimie analytique ram Chimie clinique ram Biochemistry Technique Calorimetry Chemistry, Analytical Clinical chemistry Technique Thermal analysis Thermometric titration Jespersen, Neil D. (DE-588)142895806 edt Wilson and Wilson's comprehensive analytical chemistry 12,B : Thermal analysis (DE-604)BV000900805 12,2 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000642818&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Biochemical and clinical applications of thermometric and thermal analysis Wilson and Wilson's comprehensive analytical chemistry Biochimie - technique ram Calorimètre et calorimétrie ram Chimie analytique ram Chimie clinique ram Biochemistry Technique Calorimetry Chemistry, Analytical Clinical chemistry Technique Thermal analysis Thermometric titration |
| title | Biochemical and clinical applications of thermometric and thermal analysis |
| title_auth | Biochemical and clinical applications of thermometric and thermal analysis |
| title_exact_search | Biochemical and clinical applications of thermometric and thermal analysis |
| title_full | Biochemical and clinical applications of thermometric and thermal analysis ed. by Neil D. Jespersen |
| title_fullStr | Biochemical and clinical applications of thermometric and thermal analysis ed. by Neil D. Jespersen |
| title_full_unstemmed | Biochemical and clinical applications of thermometric and thermal analysis ed. by Neil D. Jespersen |
| title_short | Biochemical and clinical applications of thermometric and thermal analysis |
| title_sort | biochemical and clinical applications of thermometric and thermal analysis |
| topic | Biochimie - technique ram Calorimètre et calorimétrie ram Chimie analytique ram Chimie clinique ram Biochemistry Technique Calorimetry Chemistry, Analytical Clinical chemistry Technique Thermal analysis Thermometric titration |
| topic_facet | Biochimie - technique Calorimètre et calorimétrie Chimie analytique Chimie clinique Biochemistry Technique Calorimetry Chemistry, Analytical Clinical chemistry Technique Thermal analysis Thermometric titration |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000642818&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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