Isotope dilution analysis:
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| Main Authors: | , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Oxford [u.a.]
Pergamon Press
1972
|
| Edition: | 1. ed. |
| Series: | International series of monographs on analytical chemistry
49 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Aus dem Ungar. übers. |
| Physical Description: | 194 S. Ill., graph. Darst. |
| ISBN: | 0080158560 |
Staff View
MARC
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| 100 | 1 | |a Tölgyessy, Juraj |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Isotope dilution analysis |c J. Tölgyessy ; T. Braun ; M. Kyrš |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Oxford [u.a.] |b Pergamon Press |c 1972 | |
| 300 | |a 194 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 490 | 1 | |a International series of monographs on analytical chemistry |v 49 | |
| 500 | |a Aus dem Ungar. übers. | ||
| 650 | 4 | |a Analyse par dilution isotopique | |
| 650 | 4 | |a Isotope dilution analysis | |
| 650 | 4 | |a Radioisotope Dilution Technique | |
| 650 | 0 | 7 | |a Isotopenverdünnungsanalyse |0 (DE-588)4162583-3 |2 gnd |9 rswk-swf |
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Record in the Search Index
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| adam_text | CONTENTS
Preface.......................... 9
1. Principles, Types and Theory of Isotope Dilution Analysis 11
1.1. General principles ................. 11
1.2. Classification of the methods of IDA......... 14
1.3. Types of IDA.................... 17
1.3.1. Direct IDA ................. 17
1.3.2. Reverse IDA................. 23
1.3.3. Derivative IDA................ 26
1.3.4. The substoichiometric principle in IDA..... 30
1.3.4.1. General................ 30
1.3.4.2. Reactions used for substoichiometric IDA 34
1.3.4.3. Substoichiometric principle in IDA and radio-
reagent methods............ 36
1.3.5. Double IDA................. 38
1.3.5.1. Double dilution with inactive isotopes ... 38
1.3.5.2. Zimakov and Rozhavskii s method .... 41
1.3.5.3. DeVoe s method............ 42
1.3.5.4. Double direct classic IDA ....... 42
1.3.5.5. Grashchenko and Sobotovich s method . . 43
1.3.6. Other types of IDA.............. 43
1.3.6.1. Dilution of radioactive substance with a
second isotopic radionuclide....... 43
1.3.6.2. Substoichiometric IDA after activation . . 46
1.3.6.3. Pseudoisotopic dilution analysis..... 47
1.3.6.4. Miscellaneous............. 48
1.4. Precision, accuracy and sensitivity of IDA....... 48
1.4.1. Precision................... 48
1.4.2. Accuracy................... 53
1.4.3. Sensitivity .................. 54
1.5. Advantages, drawbacks, trends............ 57
1.6. References..................... 61
5
6 CONTENTS
2. Experimental Techniques, Separation and Mass Determination 69
2.1. Reagents and tracers ................ 69
2.2. Separation of components.............. 76
2.2.1. Separation by precipitation .......... 76
2.2.2. Separation by ion exchange .......... 78
2.2.3. Separation by paper chromatography and by the
ring-oven technique.............. 78
2.2.4. Separation by solvent extraction ........ 82
2.2.5. Electrochemical separation........... 83
2.2.6. Separation by distillation............ 87
2.2.7. Separation by adsorption ........... 88
2.3. Determination of the amount of substance separated ... 90
2.3.1. Gravimetry.................. 91
2.3.2. Titrimetry .................. 91
2.3.3. Colorimetry ................. 92
2.3.4. Flame photometry .............. 93
2.3.5. Fluorometry ................. 94
2.3.6. Radiometry ................. 95
2.4. References..................... 95
3. Inorganic Applications 99
3.1. Determination of various elements.......... 99
3.2. Selected procedures................. 116
3.2.1. Determination of 137Cs in mixtures of fission products 116
3.2.2. Determination of sulphate........... 118
3.2.3. Determination of carbonate .......... 118
3.2.4. Determination of cobalt in steels and non-ferrous
alloys .................... 119
3.2.5. Determination of strontium and calcium in mixtures 120
3.3. References..................... 121
4. Applications in Organic Chemistry and Biochemistry 127
4.1. Alcohols and ethers ................ 127
4.2. Carboxylic acids, acid chlorides and anhydrides . . . .128
4.3. Sulpho derivatives.................. 129
4.4. Proteins and amino acids .............. 130
4.5. Steroids ...................... 137
4.6. Vitamin B12 .................... 138
CONTENTS 7
4.7. Penicillin .....................143
4.8. Insecticides.....................144
4.9. Other applications in organic chemistry and biochemistry 147
4.10. References.....................148
5. Isotope Dilution Analysis with Stable Isotopes 155
5.1. Introduction .................... 155
5.2. Methods for the determination of isotopic composition.
Analysis by mass spectrometry............ 156
5.3. Fundamentals and technique............. 158
5.4. Practical applications ................ 160
5.4.1. Applications in organic chemistry........ 160
5.4.2. Applications in inorganic chemistry ....... 162
5.4.3. Determination of geological age ........ 165
5.5. References..................... 167
6. Special Applications of Isotope Dilution 171
6.1. Volume determination................171
6.1.1. Determination of water in the human body . . . .172
6.1.2. Determination of the volume of the extracellular fluid 173
6.1.3. Determination of the volume of erythrocytes, plasma
and blood ..................173
6.2. Determination of solubility .............175
6.3. Determination of radioactive contaminants ......177
6.4. Determination of the content of isotopic carriers in radio-
active preparations .................179
6.5. Determination of dissociation constants........180
6.6. Studies on reaction rates and equilibria........183
6.7. Determination of the capacity of ion exchangers .... 184
6.8. Determination of the coefficient of self-absorption and of
specific activity...................186
6.9. Measurement of flow rates..............187
6.10. References.....................188
Index.......................191
|
| any_adam_object | 1 |
| author | Tölgyessy, Juraj Braun, Tibor 1932-2022 Kyrš, Miroslav |
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| discipline | Chemie / Pharmazie |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T15:21:30Z |
| institution | BVB |
| isbn | 0080158560 |
| language | English |
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| owner_facet | DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-83 |
| physical | 194 S. Ill., graph. Darst. |
| psigel | TUB-nvmb |
| publishDate | 1972 |
| publishDateSearch | 1972 |
| publishDateSort | 1972 |
| publisher | Pergamon Press |
| record_format | marc |
| series | International series of monographs on analytical chemistry |
| series2 | International series of monographs on analytical chemistry |
| spelling | Tölgyessy, Juraj Verfasser aut Isotope dilution analysis J. Tölgyessy ; T. Braun ; M. Kyrš 1. ed. Oxford [u.a.] Pergamon Press 1972 194 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier International series of monographs on analytical chemistry 49 Aus dem Ungar. übers. Analyse par dilution isotopique Isotope dilution analysis Radioisotope Dilution Technique Isotopenverdünnungsanalyse (DE-588)4162583-3 gnd rswk-swf Isotopenverdünnungsanalyse (DE-588)4162583-3 s DE-604 Braun, Tibor 1932-2022 Verfasser (DE-588)1018604952 aut Kyrš, Miroslav Verfasser aut International series of monographs on analytical chemistry 49 (DE-604)BV001889010 49 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000572722&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Tölgyessy, Juraj Braun, Tibor 1932-2022 Kyrš, Miroslav Isotope dilution analysis International series of monographs on analytical chemistry Analyse par dilution isotopique Isotope dilution analysis Radioisotope Dilution Technique Isotopenverdünnungsanalyse (DE-588)4162583-3 gnd |
| subject_GND | (DE-588)4162583-3 |
| title | Isotope dilution analysis |
| title_auth | Isotope dilution analysis |
| title_exact_search | Isotope dilution analysis |
| title_full | Isotope dilution analysis J. Tölgyessy ; T. Braun ; M. Kyrš |
| title_fullStr | Isotope dilution analysis J. Tölgyessy ; T. Braun ; M. Kyrš |
| title_full_unstemmed | Isotope dilution analysis J. Tölgyessy ; T. Braun ; M. Kyrš |
| title_short | Isotope dilution analysis |
| title_sort | isotope dilution analysis |
| topic | Analyse par dilution isotopique Isotope dilution analysis Radioisotope Dilution Technique Isotopenverdünnungsanalyse (DE-588)4162583-3 gnd |
| topic_facet | Analyse par dilution isotopique Isotope dilution analysis Radioisotope Dilution Technique Isotopenverdünnungsanalyse |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000572722&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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