Kinetic methods in chemical analysis:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English Czech |
| Published: |
Amsterdam [u.a.]
Elsevier
1983
|
| Series: | Wilson and Wilson's Comprehensive analytical chemistry
18 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 444 S. graph. Darst. |
| ISBN: | 0444996850 |
Staff View
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| 490 | 1 | |a Wilson and Wilson's Comprehensive analytical chemistry |v 18 | |
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| 249 | |a Application of computers in analytical chemistry |v [by Karel Eckschlager] | ||
Record in the Search Index
| _version_ | 1804115346665242624 |
|---|---|
| adam_text | Wilson and Wilson s
COMPREHENSIVE
ANALYTICAL
CHEMISTRY
EDITED BY
G SVEHLA, PH D,D Sc ,FRSC
Reader in Analytical Chemistry
The Queen s University of Belfast
i SI-
VOLUME XVIII
Kinetic Methods in Chemical Analysis
Application of Computers in Analytical Chemistry
?
LLSEVIER SCIENTIFIC PUBLISHING COMPANY
AMSTERDAM OXFORD JEW YORK
Contents
List of symbols 17
Introduction 19
1 KINETIC ASPECTS OF THE ANALYTICAL USE
OF CHEMICAL REACTIONS 21
2 KINETICS OF CHEMICAL REACTIONS 25
i! 1i21 Principal concepts; |, 25
2 2 Kinetic equations : 27
2 3 Factors affecting the rate of chemical reactions in solution 27
J
3 CATALYTIC REACTIONS 33
I : i i :
3 1 Kinetic equations for catalytic reactions 33
3 2 The catalysis mechanism 36
321 Mechanisms of analytically important catalytic reactions 36
322 Activation of catalytic reactions 41
3 3 Catalytic reactions with an induction period 42
3 4 6scillating chemical reactions 43
3 5 Reactions catalyzed by organic catalysts 44
3 6 Selectivity of catalytic reactions 45
361 Modification of the selectivity of catalytic reactions 48
362 Improvement of the selectivity by masking and separations 49
4 ENZYME REACTIONS 53
4 1 The kinetic equation for enzyme-catalyzed reactions 53
4 2 Factors affecting the rate of enzyme reactions 57
421 Activators 57
422 Inhibitors 58
423 Hydrogen ion concentration 60
424 Temperature 61
4 3 Principles of the analytical use of enzyme reactions 61
431 Determination of substrates 62
432 Determination of enzymes 62
433 Determination of the activate rs and coenzymes 63
434 Determination of inhibitors 64
435 General remarks on the methods of enzyme analysis 65
4 4 Immobilized enzymes 66
441 Quantitative treatment of reactions involving enzymes
immobilized in artificial membranes 69
5 UNCATALYZED REACTIONS 75
5 1 The effect of the structure of the reactants on the reaction
rate 76
5 2 Oxidation-reduction reactions 81
5 3 Fast reactions 83
6 REACTIONS OF COMPLEXES 87
6 1 Kinetics of complex formation in aqueous solutions 87
6 2 Catalytic effects in reactions of com plexes 88
6 3 Substitution reactions of complexes 89
631 Substitution reactions of pol dentate complexes 90
632 Coordination chain reactions 92
633 Substitution reactions of bini clear complexes 96
64j Analytical use of the modifying effect of complexing agents
on the rate of catalytic reactions 97
6 5 Differential kinetic methods based on reactions of com
plexes 99
7 REACTIONS AFFECTING ELECTRODE
PROCESSES 107
7 1 Polarographic kinetic currents 107
7 2 Catalytic electrode processes 109
7 3 Hydrogen catalytic currents Ill
8 KINETIC METHODS 113
8 1 Classification of kinetic methods 113
8 2 Methods for determination of a singl j component: 113
821 Methods using catalytic reactions 115
8211 Differential methods 115
8212 Integration methods 119
8213 Method of tangents 120
8214 The method based on the measurement of the induction
period 122
8215 Catalytic end-point titrations 123
8216 Catalytic methods employing open systems 123
822 Methods based on uncatalyzed reactions 126
8 3 Methods of analysis of mixtures of substances 128
831 Methods of determination of two su! stances that react at
different rates with a single reagent 128
832 Differential kinetic methods 129
8321 Methods based on first or pseudofirst order reactions with
respect to the reactants 130
8322 Methods based on second order reactions 138
8323 Methods using first and pseudofirst order reactions with
respect to the reagent 147 li
8324 Methods based on1 pseudozero order reactions 151
8 4 The accuracy, precision and sensitivit y of kinetic methods 152
841 Methods employing catalytic reactions 153
842 Methods employing uncatalyzed reactions 155
843 Differential kinetic methods 157
9 INSTRUMENTATION FOR KIN I TIC METHODS 163
9 1 Monitoring of the reaction course 164
911 Instrumental methods 164
9111 Optical methods 164
9112 Electrochemical methods 166
91121 Enzyme electrodes 167
91122 Bipotentiometry and differential potentiometry 169
9113 Other methods 171
9 2 Instrumentation for differential methods 172
9 3 Stat methods 174
9 4 Flow-through methods 176
941 Flow-through measurements on paper 176
942 Flow-through cell 177
943 Closed flow-through systems with sample injection 179
944 Continuous flow and st opped-flow methods 182
9 5 Automation of kinetic methods 184
951 Automation of methods for determination of a single
substance 185
952 Automatic analysis of mixtures of substances 188
9 6 The use of minicomputers in kinetic analysis 188
10 KINETIC ANALYSIS 191
10 1 Catalytic methods 191
10 1 1 Determination of inorganic substances 191
10 1 2 Catalytic end-point titrations 211
10 1 3 Indirect catalytic determination of organic substances 211
10 1 4 Determinations based on measurement of catalytic polaro-
graphic waves 214
10 2 Kinetic methods 217
10 2 1 Methods for determination of a single substance 217
10 2 2 Analysis of mixtures 218
10 3 Enzyme analysis methods 218
10 3 1 Determination of enzymes 218
10 311 Determination of hydrolases 221
10 312 Determination of oxida ses 222
10 313 Determination of dehydrogenases 223
1Q?3 1 4 Determination of other enzymes 224
10 3 2 Determination of substrates 224
10 321 Determination of sugars 224
10 322 Determination of organic acids 225
10 323 Determination of amino acids 225
10 324 Determination of hydroxycompounds 225
10 325 Determination of inorganic substances as substrates 225
10 3 3 Determination of activators 226
10 3 4 Determination of inhibitors 227
References 227
|
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| author_facet | Kopanica, Miloslav Stara, Vera |
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 543 - Analytical chemistry |
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| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV000908916 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:21:09Z |
| institution | BVB |
| isbn | 0444996850 |
| language | English Czech |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000560456 |
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| owner_facet | DE-19 DE-BY-UBM DE-188 |
| physical | 444 S. graph. Darst. |
| publishDate | 1983 |
| publishDateSearch | 1983 |
| publishDateSort | 1983 |
| publisher | Elsevier |
| record_format | marc |
| series | Wilson and Wilson's Comprehensive analytical chemistry |
| series2 | Wilson and Wilson's Comprehensive analytical chemistry |
| spelling | Kopanica, Miloslav Verfasser aut Kinetic methods in chemical analysis [by Miloslav Kopanica ; Věra Stará] Amsterdam [u.a.] Elsevier 1983 444 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wilson and Wilson's Comprehensive analytical chemistry 18 Chimie analytique Chimie analytique ram Cinétique chimique Réactions chimiques - vitesse ram Chemical kinetics Chemistry, Analytic Stara, Vera Verfasser aut Wilson and Wilson's Comprehensive analytical chemistry 18 (DE-604)BV000900805 18 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000560456&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Application of computers in analytical chemistry [by Karel Eckschlager] |
| spellingShingle | Kopanica, Miloslav Stara, Vera Kinetic methods in chemical analysis Wilson and Wilson's Comprehensive analytical chemistry Chimie analytique Chimie analytique ram Cinétique chimique Réactions chimiques - vitesse ram Chemical kinetics Chemistry, Analytic |
| title | Kinetic methods in chemical analysis |
| title_auth | Kinetic methods in chemical analysis |
| title_exact_search | Kinetic methods in chemical analysis |
| title_full | Kinetic methods in chemical analysis [by Miloslav Kopanica ; Věra Stará] |
| title_fullStr | Kinetic methods in chemical analysis [by Miloslav Kopanica ; Věra Stará] |
| title_full_unstemmed | Kinetic methods in chemical analysis [by Miloslav Kopanica ; Věra Stará] |
| title_short | Kinetic methods in chemical analysis |
| title_sort | kinetic methods in chemical analysis |
| topic | Chimie analytique Chimie analytique ram Cinétique chimique Réactions chimiques - vitesse ram Chemical kinetics Chemistry, Analytic |
| topic_facet | Chimie analytique Cinétique chimique Réactions chimiques - vitesse Chemical kinetics Chemistry, Analytic |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000560456&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000900805 |
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