Dynamic characteristics of ion-selective electrodes:
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| Main Authors: | , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton, Fla.
CRC Press
1988
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 136 S. |
| ISBN: | 0849364930 |
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| adam_text | DYNAMIC CHARACTERISTICS OF ION-SELECTIVE ELECTRODES AUTHORS ERNOE
LINDNER, PH.D. RESEARCH SCIENTIST INSTITUTE FOR GENERAL AND ANALYTICAL
CHEMISTRY TECHNICAL UNIVERSITY BUDAPEST, HUNGARY KLARA TOETH, PH.D.
ASSOCIATE PROFESSOR INSTITUTE FOR GENERAL AND ANALYTICAL CHEMISTRY
TECHNICAL UNIVERSITY BUDAPEST, HUNGARY ERNOE PUNGOR, PH.D. HEAD OF
INSTITUTE INSTITUTE FOR GENERAL AND ANALYTICAL CHEMISTRY TECHNICAL
UNIVERSITY BUDAPEST, HUNGARY CRC PRESS, INC. BOCA RATON, FLORIDA TABLE
OF CONTENTS CHAPTER 1 HISTORY AND DEVELOPMENT 1 CHAPTER 2 TRANSIENT
TECHNIQUES APPLIED TO STUDY LON-SELECTIVE ELECTRODES 3 I. INTRODUCTION 3
II. THE IMPEDANCE METHOD 4 A. THE IMPEDANCE PLANE PLOTS: DEFINITIONS 4
B. APPLICATION OF THE METHOD FOR LON-SELECTIVE ELECTRODE STUDIES 8 C.
INFORMATION OBTAINED FROM IMPEDANCE PLANE PLOTS 8 III. POLARIZATION
STUDIES OF LON-SELECTIVE ELECTRODES 11 A. METHODS FOR DETERMINING
EXCHANGE CURRENT DENSITIES 11 B. A MIXED POTENTIAL LON-SELECTIVE
ELECTRODE THEORY 16 IV. STUDIES INDIRECTLY RELATED TO THE DYNAMIC
CHARACTERISTICS OF LON-SELECTIVE ELECTRODES 19 V. THE ACTIVITY STEP
METHOD 21 A. THE PRINCIPLE OF THE METHOD 21 B. EXPERIMENTAL TECHNIQUES
22 1. THE DIPPING (IMMERSION) METHOD 22 2. THE INJECTION METHOD 22 3.
SPECIAL TECHNIQUES 23 C. PARAMETERS AFFECTING THE TRANSIENT FUNCTION OF
LON-SELECTIVE ELECTRODES 26 1. THE PRIMARY ION CONCENTRATION 27 2.
INTERFERENCES 28 3. HYDRODYNAMIC CONDITIONS 28 4. MEMBRANE BULK AND
SURFACE PARAMETERS 30 VI. COMPARISON OF THE DIFFERENT TECHNIQUES 31
CHAPTER 3 THEORIES OF TRANSIENT POTENTIALS (FOLLOWING AN ACTIVITY STEP
IN THE ABSENCE OF INTERFERING IONS) 33 I. INTRODUCTION 33 II. DIFFUSION
THROUGH A STAGNANT LAYER 35 A. LIMITS OF THE DIFFUSION MODEL 44 1. THE
EFFECT OF THE ACTIVITY LEVEL 49 2. THE EFFECT OF THE ACTIVITY RATIOS 51
3. CONCLUSIONS 54 B. THE MULTIELECTRODE MODEL 54 III. KINETICS OF
INTERFACIAL REACTIONS 60 A. ENERGY BARRIER CONCEPT 60 B. FIRST-ORDER
CHEMICAL KINETICS AND THE CONSECUTIVE REACTION MODEL 62 C. SECOND-ORDER
CHEMICAL KINETICS 64 IV. DIFFUSION WITHIN THE ION-SENSING MEMBRANE 68 V.
UNIFIED MODELS FOR TRANSIENT FUNCTIONS 77 CHAPTER 4 TRANSIENT POTENTIALS
IN THE PRESENCE OF INTERFERING IONS 81 I. INTRODUCTION 81 II. THE
SEGMENTED MEMBRANE MODEL 84 III. DIFFERENCES IN THE SURFACE ACTIVITY DUE
TO ADSORPTION/DESORPTION PROCESSES 90 A. QUALITATIVE INTERPRETATION 90
1. EFFECT OF FLOW RATE 94 2. EFFECT OF INTERFERING ION ACTIVITY 94 3.
EFFECT OF THE DIRECTION OF ACTIVITY CHANGE 95 4. EFFECT OF ELECTRODE
SURFACE CONDITIONS 95 5. EFFECT OF TEMPERATURE ON THE TRANSIENT SIGNAL
96 B. QUANTITATIVE INTERPRETATION 97 IV. COMPARISON OF THE DIFFERENT
MODELS 104 CHAPTER 5 DETERMINATION AND DEFINITION OF RESPONSE TIME 107
I. INTRODUCTION 107 II. DYNAMIC RESPONSE OF AN LON-SELECTIVE ELECTRODE
AND AN ELECTROCHEMICAL CELL 107 III. DEFINITION OF RESPONSE TIME 108 IV.
ESTIMATION OF THE EQUILIBRIUM POTENTIAL 112 V. SELECTED EXAMPLES 114 A.
INTERPRETATION OF THE DATA OF MERTENS ET AL 116 B. INTERPRETATION OF THE
DATA OF DENKS AND NEEB 116 CHAPTER 6 THE IMPORTANCE OF DYNAMIC
PROPERTIES OF LON-SELECTIVE ELECTRODES IN PRACTICAL ANALYSIS 121
REFERENCES 125 INDEX 131
|
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| author | Lindner, Ernö Tóth, Klára Pungor, Ernö |
| author_facet | Lindner, Ernö Tóth, Klára Pungor, Ernö |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T15:20:25Z |
| institution | BVB |
| isbn | 0849364930 |
| language | English |
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| physical | 136 S. |
| publishDate | 1988 |
| publishDateSearch | 1988 |
| publishDateSort | 1988 |
| publisher | CRC Press |
| record_format | marc |
| spelling | Lindner, Ernö Verfasser aut Dynamic characteristics of ion-selective electrodes authors Ernö Lindner ; Klára Róth ; Ernö Pungor Boca Raton, Fla. CRC Press 1988 136 S. txt rdacontent n rdamedia nc rdacarrier Electrodes, Ion selective Ionenselektive Elektrode (DE-588)4072918-7 gnd rswk-swf Ionenselektive Elektrode (DE-588)4072918-7 s DE-604 Tóth, Klára Verfasser aut Pungor, Ernö Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000531092&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Lindner, Ernö Tóth, Klára Pungor, Ernö Dynamic characteristics of ion-selective electrodes Electrodes, Ion selective Ionenselektive Elektrode (DE-588)4072918-7 gnd |
| subject_GND | (DE-588)4072918-7 |
| title | Dynamic characteristics of ion-selective electrodes |
| title_auth | Dynamic characteristics of ion-selective electrodes |
| title_exact_search | Dynamic characteristics of ion-selective electrodes |
| title_full | Dynamic characteristics of ion-selective electrodes authors Ernö Lindner ; Klára Róth ; Ernö Pungor |
| title_fullStr | Dynamic characteristics of ion-selective electrodes authors Ernö Lindner ; Klára Róth ; Ernö Pungor |
| title_full_unstemmed | Dynamic characteristics of ion-selective electrodes authors Ernö Lindner ; Klára Róth ; Ernö Pungor |
| title_short | Dynamic characteristics of ion-selective electrodes |
| title_sort | dynamic characteristics of ion selective electrodes |
| topic | Electrodes, Ion selective Ionenselektive Elektrode (DE-588)4072918-7 gnd |
| topic_facet | Electrodes, Ion selective Ionenselektive Elektrode |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000531092&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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