Phospholipid bilayers: physical principles and models
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Wiley
1987
|
| Schriftenreihe: | Cell biology
5 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 442 S. Ill. |
| ISBN: | 047109255X |
Internformat
MARC
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Datensatz im Suchindex
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|---|---|
| adam_text | IMAGE 1
CONTENTS
1 BILAYER PROPERTIES 1
INTRODUCTION 2
CHEMICAL STRUCTURE OF PHOSPHOLIPIDS 3
CRYSTAL STRUCTURES OF PHOSPHOLIPIDS 6
PHASE BEHAVIOR OF PHOSPHOLIPIDS 12
CALORIMETRIC PROPERTIES 15
DILATOMETRIC PROPERTIES 18
BILAYER DIMENSIONS 19
LIPID CHAIN DYNAMICS 24
REFERENCES 28
2 SELF-ASSEMBLY 29
INTRODUCTION 30
HYDROPHOBIE EFFECT 30
PARTITIONING INTO BILAYERS 34
THERMODYNAMICS OF AGGREGATION 36
CRITICAL MICELLE CONCENTRATION 37
MICELLE SIZE 40
BILAYER POLAR-APOLAR INTERFACE 42
XI
IMAGE 2
XUE CONTENTS
PACKING CONSTRAINTS 46
PHOSPHOLIPID MICELLES 48
LIPID TRANSFER 51
REFERENCES 55
3 LIPID HYDRATION 57
INTRODUCTION 58
MOLECULAR DESCRIPTION OF LIPID-WATER ASSOCIATION 59 MEAN-FIELD
MOLECULAR-FORCE MODEL OF LIPID HYDRATION 63 SURFACE-INDUCED WATER
POLARIZATION 68 BILAYER HYDRATION AND POLARIZATION POTENTIALS 73
THERMODYNAMICS OF LIPID-WATER ASSOCIATION 76 SORPTION OF WATER ONTO
BILAYERS 82
EFFECT OF HYDRATION ON BILAYER STRUCTURE 86
EFFECT OF HYDRATION ON LIPID DYNAMICS 91
DYNAMIC WATER PROPERTIES AND PERMEABILITY 93
REFERENCES 96
4 SURFACE ELECTROSTATICS 99
INTRODUCTION 100
DIFFUSE DOUBLE LAYER OF PLANAR CHARGED SURFACES 102 ELECTROSTATIC
BILAYER POTENTIAL 107 ZETA POTENTIAL 112 BILAYER ELECTRIC FIELD 113
THERMODYNAMICS OF DIFFUSE-DOUBLE-LAYER
FORMATION 114 DIFFUSE DOUBLE LAYER OF CHARGED CURVED SURFACES 117
DISCRETENESS OF SURFACE CHARGE EFFECT 119
MODIFICATIONS OF THE CLASSICAL DOUBLE-LAYER MODEL 124 APPLICABILITY OF
CLASSICAL DOUBLE-LAYER THEORY TO LIPID BILAYERS 127
REFERENCES 128
5 HYDRATED SURFACES IN IONIC SOLUTIONS 131
INTRODUCTION 132
IMAGE 3
CONTENTS XU1
PLANAR BILAYERS IN ELECTROLYTE SOLUTION 132
INTERLAMELLAR ELECTRIC FIELD AND SOLVENT POLARIZATION 133 ELECTROSTATIC
POTENTIAL OF HYDRATED CHARGED BILAYERS 143 POLARIZATION POTENTIAL OF THE
INTERLAMELLAR ELECTROLYTE SOLUTION 149 FREE ENERGY OF HYDRATED CHARGED
BILAYERS 149 SPHERICAL HYDRATED BILAYERS IN ELECTROLYTE SOLUTION 153
REFERENCES 155
6 SOLUTE-BILAYER INTERACTIONS, BINDING, AND TRANSPORT 157
INTRODUCTION 158
SOLUTE CONCENTRATION PROFILE NEAR A MEMBRANE 158
SURFACE-SOLUTE INTERACTIONS SOLUTE CONCENTRATION PROFILE DUE TO
NONCOULOMBIC FORCES 165 ION DISTRIBUTION FOR CHARGED BILAYERS 169 SOLUTE
BINDING 172
SOLUTE BINDING CONSTANTS AND BINDING ENERGIES 178 PH TITRATION 182
SOLUTE TRANSPORT ACROSS MEMBRANES 184
MEMBRANE PERMEABILITY 186 PARTITIONING OF SOLUTES INTO LIPID BILAYERS
187 ION TRANSPORT 190
TEMPERATURE DEPENDENCE OF MEMBRANE PERMEABILITY 193 REFERENCES 196
7 INTERBILAYER FORCES, AGGREGATION, AND FUSION 201
INTRODUCTION 202
ATTRACTIVE FORCES BETWEEN LIPID MEMBRANES 202
STANDARD MODEL OF VAN DER WAALS FORCES 203 VAN DER WAALS FORCE FROM
INTERBILAYER CHARGE CORRELATIONS 209
IMAGE 4
XIV CONTENTS
VAN DER WAALS ATTRACTION BETWEEN CURVED SURFACES 211 SHORT-RANGE
REPULSION FROM HYDRATION FORCES 212
ELECTROSTATIC INTERBILAYER REPULSION 214
LONG-RANGE REPULSION FROM FLUCTUATION FORCES 218 EQUILIBRIUM
INTERBILAYER SEPARATION 220
AGGREGATION OF LIPID VESICLES 223
FUSION OF LIPID MEMBRANES AND VESICLES 225
REFERENCES 229
8 BILAYER PHASE TRANSITIONS 231
INTRODUCTION 232
CHAIN-MELTING PHASE TRANSITION 237
KINETICS OF CHAIN MELTING 237 TRANSITION TEMPERATURE AND THERMODYNAMICS
OF CHAIN MELTING 240 EFFECT OF THE POLAR INTERFACE ON THE CHAIN-MELTING
TRANSITION TEMPERATURE 246 PH TITRATION OF BILAYER PHASE TRANSITION 253
EFFECT OF SALT AND NONELECTROLYTES ON THE CHAIN- MELTING PHASE
TRANSITION 253 PRE- AND SUBTRANSITIONS 258
PHASE METASTABILITY 263
REFERENCES 266
9 CHAIN ROTATIONAL ISOMERISM 269
INTRODUCTION 270
BOND ROTATIONAL POTENTIAL AND THE ROTATIONAL ISOMERIC MODEL 270
INTERDEPENDENT BOND ROTATIONAL POTENTIALS 272
CONFIGURATIONAL PARTITION FUNCTION 274
CONFORMATIONAL PROBABILITIES 276
CONFIGURATIONAL ENTROPY AND ENTHALPY 279
TRANSFORMATION MATRICES 281
CHAIN DIMENSIONS 284
IMAGE 5
CONTENTS XV
CHAIN ORDERING 286
SIMPLE MODEL FOR INTERMOLECULAR STERIC RESTRICTIONS 287 REFERENCES 292
10 BILAYER MODELS 293
INTRODUCTION 294
EXACTLY SOLUBLE LATTICE MODELS 295
MOLECULAR DYNAMICS SIMULATIONS 297
MONTE CARLO METHODS 300
A REVIEW OF VARIOUS MODELS 301
MOLECULAR FIELD THEORY 310
EXTENSIONS OF THE MOLECULAR FIELD THEORY 314
HARD-CORE REPULSION THEORY 318
REFERENCES 322
11 FLUID PHASE 325
INTRODUCTION 326
ORDER PARAMETER PROFILE 326
THERMODYNAMIC PROPERTIES 332
SPATIAL CONFIGURATION AND BILAYER DIMENSIONS 333
CONFORMATIONAL PROBABILITIES 341
CONCLUSION 345
REFERENCES 345
12 BILAYER ELASTICITY 347
INTRODUCTION 348
MONOLAYER SURFACE PRESSURE 350
BILAYER SURFACE PRESSURE 355
AREA AND THICKNESS COMPRESSIBILITY 357
BILAYER THERMOMECHANICS AND THERMAL EXPANSION 361 BENDING MOMENTS AND
CURVATURE ELASTICITY 365
SPONTANEOUS CURVATURE 366
REFERENCES 368
IMAGE 6
XVI CONTENTS
13 LATERAL PHASE SEPARATION 369
INTRODUCTION 370
PHASE RULE 370
PHASE DIAGRAMS 373
CLASSIFICATION OF PHASE DIAGRAMS 377
IDEAL SOLUTION THEORY 384
FREE ENERGY-COMPOSITION RELATIONS 389
FREE ENERGY OF MIXING-MISCIBILITY 393
REGULAR SOLUTION THEORY 396
ORIGIN OF NONIDEAL MIXING: REGULAR AND ATHERMAL SOLUTIONS 400
STATISTICAL-MECHANICAL CALCULATION OF LIPID PHASE SEPARATION REFERENCES
14 NONBILAYER PHASES
INTRODUCTION NONLAMELLAR PHASE STABILITY LAMELLAR-INVERTED HEXAGONAL
PHASE TRANSITION
TEMPERATURE SHIFTS KINETICS OF LAMELLAR-NONLAMELLAR TRANSITIONS
REFERENCES
402 406
407
408 409
415 420 424
INDEX 427
|
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| isbn | 047109255X |
| language | English |
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| physical | XVI, 442 S. Ill. |
| publishDate | 1987 |
| publishDateSearch | 1987 |
| publishDateSort | 1987 |
| publisher | Wiley |
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| series | Cell biology |
| series2 | Cell biology |
| spelling | Cevc, Gregor Verfasser aut Phospholipid bilayers physical principles and models Gregor Cevc ; Derek Marsh New York [u.a.] Wiley 1987 XVI, 442 S. Ill. txt rdacontent n rdamedia nc rdacarrier Cell biology 5 Doppelschicht (DE-588)4150451-3 gnd rswk-swf Phospholipidmembran (DE-588)4174401-9 gnd rswk-swf Phospholipidmembran (DE-588)4174401-9 s Doppelschicht (DE-588)4150451-3 s DE-604 Marsh, Derek Verfasser (DE-588)1031679154 aut Cell biology 5 (DE-604)BV000013895 5 SWB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000414362&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cevc, Gregor Marsh, Derek Phospholipid bilayers physical principles and models Cell biology Doppelschicht (DE-588)4150451-3 gnd Phospholipidmembran (DE-588)4174401-9 gnd |
| subject_GND | (DE-588)4150451-3 (DE-588)4174401-9 |
| title | Phospholipid bilayers physical principles and models |
| title_auth | Phospholipid bilayers physical principles and models |
| title_exact_search | Phospholipid bilayers physical principles and models |
| title_full | Phospholipid bilayers physical principles and models Gregor Cevc ; Derek Marsh |
| title_fullStr | Phospholipid bilayers physical principles and models Gregor Cevc ; Derek Marsh |
| title_full_unstemmed | Phospholipid bilayers physical principles and models Gregor Cevc ; Derek Marsh |
| title_short | Phospholipid bilayers |
| title_sort | phospholipid bilayers physical principles and models |
| title_sub | physical principles and models |
| topic | Doppelschicht (DE-588)4150451-3 gnd Phospholipidmembran (DE-588)4174401-9 gnd |
| topic_facet | Doppelschicht Phospholipidmembran |
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