Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Elektronisch Software E-Book |
| Sprache: | English |
| Veröffentlicht: |
Leipzig
2018
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | 1 CD-ROM (113, LXV Blätter) Illustrationen 30 cm |
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| 245 | 1 | 0 | |a Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources |c vorgelegt von Dipl.-Ing. Carolin Urban, geb Stang |
| 264 | 1 | |a Leipzig |c 2018 | |
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Datensatz im Suchindex
| _version_ | 1804180468967407616 |
|---|---|
| adam_text | TABLE OF CONTENT
ZUSAMMENFASSUNG..............................................................................................................................3
SUMMARY.............................................................................................................................................6
ABBREVIATIONS 9
PREFACE...............................................................................................................................................
12
1
INTRODUCTION...............................................................................................................................
14
1.1 MOTIVATION AND STRUCTURE OF THE
THESIS......................................................................................14
1.2
BIOREFINERIES..........................................................................................................................
16
1.2.1 ANAEROBIC DIGESTION - AN AUSPICIOUSLY TOOLBOX FOR BIOREFMERIES
............................
17
1.2.2 ANAEROBIC FERMENTATION OF CARBOXYLIC ACIDS
............................................................
18
1.2.3 TRANSPORTATION BIOFUELS FROM BIOREFINERIES AND FUEL
PROPERTIES...............................20
1.3 ELECTROCHEMICAL
REACTIONS....................................................................................................22
1.3.1 FUNDAMENTALS IN ELECTROCHEMICAL
REACTIONS.............................................................
22
1.3.1.1 CHARGE TRANSPORT IN AQUEOUS ELECTROLYTE
SOLUTIONS......................................24
1.3.1.2 THE ELECTROCHEMICAL DOUBLE LAYER
...............................................................
26
1.3.1.3 KINETICS OF ELECTROCHEMICAL
REACTIONS.........................................................27
1.3.2 ELECTROORGANIC REACTIONS - AN INEXHAUSTIBLE TOOLBOX FOR SELECTIVE
CONVERSIONS..............................................................................................................
30
1.3.2.1 CARBOXYLIC ACIDS - ONE MOLECULE CLASS, VARIOUS ELECTROCHEMICAL
REACTION
PATHWAYS......................................................................................
.31
1.3.2.2 PHYSICAL AND CHEMICAL CHARACTERISTICS OF CARBOXYLIC ACIDS IN
AQUEOUS
PHASES............................................................................................36
1.4 COMBINED APPROACHES FOR BIOTECHNOLOGY AND ELECTROCHEMISTRY
.........................................
38
1.4.1 MICROBIAL ELECTROCHEMICAL
TECHNOLOGIES...................................................................39
1.4.2 DIVERGENT OPTIMA FOR REACTION CONDITIONS IN BIOTECHNOLOGY AND
ELECTROCHEMISTRY CALL FOR A SPATIAL
SEPARATION............................................................
41
1.5 AIMS OF THIS
THESIS...............................................................................................................
42
2
PUBLICATIONS..............................................................................................................................
43
2.1 OVERVIEW OF
PUBLICATIONS.......................................................................................................43
2.2 PRODUCTION OF DROP-IN FUEL FROM BIOMASS AT HIGH SELECTIVITY BY A
BIOELECTROREFINERY..................................................................................................................45
2.3 THE DILEMMA OF SUPPORTING ELECTROLYTES FOR ELECTROORGANIC SYNTHESIS:
A CASE
STUDY ON KOLBE
ELECTROLYSIS................................................................................................68
2.4 DETERIORATION OF AQUEOUS N-OCTANOATE ELECTROLYSIS DUE TO
ELECTROLYTIC
CONDUCTIVITY COLLAPSE CAUSED BY FORMATION OF W-OCTANOIC ACID/
N-OCTANOATE
AGGLOMERATES........................................................................................................................
79
3 DISCUSSION AND FUTURE
PROSPECTS............................................................................................
91
3.1 THE CONCEPT OF A *BIOELECTROREFMERY*: COMBINING TWO FIELDS WITH
DISSIMILAR
OPERATING NEEDS IN ADVANCING
TECHNOLOGIES.........................................................................91
3.2 QUICK ESTIMATION OF THE ECONOMIC VIABILITY OF THE PROPOSED
BIOELECTROREFMERY
YIELDING DIESEL-LIKE
FUEL.......................................................................................................
93
3.3 OPTIMIZATION OF THE ELECTROCHEMICAL CARBOXYLIC ACIDS CONVERSION
.....................................
98
3.4 CONCLUSION & FUTURE
PROSPECTS............................................................................................
104
4
REFERENCES..................................................................................................................................108
|
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| spelling | Urban, Carolin 1989- Verfasser (DE-588)1160101302 aut Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources vorgelegt von Dipl.-Ing. Carolin Urban, geb Stang Leipzig 2018 1 CD-ROM (113, LXV Blätter) Illustrationen 30 cm txt rdacontent c rdamedia cd rdacarrier Dissertation Universität Leipzig 2018 (DE-588)4113937-9 Hochschulschrift gnd-content (DE-588)4139307-7 CD-ROM gnd-carrier B:DE-101 application/pdf http://d-nb.info/1159538425/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031518763&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Textdatei PDF |
| spellingShingle | Urban, Carolin 1989- Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources |
| subject_GND | (DE-588)4113937-9 (DE-588)4139307-7 |
| title | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources |
| title_auth | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources |
| title_exact_search | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources |
| title_full | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources vorgelegt von Dipl.-Ing. Carolin Urban, geb Stang |
| title_fullStr | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources vorgelegt von Dipl.-Ing. Carolin Urban, geb Stang |
| title_full_unstemmed | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources vorgelegt von Dipl.-Ing. Carolin Urban, geb Stang |
| title_short | Fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n-carboxylic acids derived from renewable resources |
| title_sort | fundamental study and process description of a bioelectrorefinery based on the electrochemical upgrading of n carboxylic acids derived from renewable resources |
| topic_facet | Hochschulschrift CD-ROM |
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