Emanation thermal analysis and other radiometric emanation methods:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
1984
|
| Schriftenreihe: | Wilson and Wilson's comprehensive analytical chemistry
12,C : Thermal analysis |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XV, 303 S. Ill., graph. Darst. |
| ISBN: | 0444996591 |
Internformat
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| 100 | 1 | |a Balek, Vladimír |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Emanation thermal analysis and other radiometric emanation methods |c by V. Balek and J. Tölgyessy |
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 1984 | |
| 300 | |a XV, 303 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Wilson and Wilson's comprehensive analytical chemistry |v 12,C : Thermal analysis | |
| 500 | |a Literaturangaben | ||
| 650 | 7 | |a Analyse radiochimique |2 ram | |
| 650 | 7 | |a Analyse thermique |2 ram | |
| 650 | 7 | |a Chimie analytique |2 ram | |
| 650 | 4 | |a Radiochemical analysis | |
| 700 | 1 | |a Tölgyessy, Juraj |d 1931-2014 |e Verfasser |0 (DE-588)1158007108 |4 aut | |
| 830 | 0 | |a Wilson and Wilson's comprehensive analytical chemistry |v 12,C : Thermal analysis |w (DE-604)BV000900805 |9 12,3 | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-000642819 | ||
Datensatz im Suchindex
| _version_ | 1804115479273406464 |
|---|---|
| adam_text | Wilson and-Wilson s
COMPREHENSIVE ANALYTICAL CHEMISTRY
Edited by
G SVEHLA, PH D„ D SC ,FRSC
Reader in Analytical Chenrstry
the Queen s University of Belfast
VOLUMEXII
THERMAL ANALYSIS
PARTC
EMANATION THERMAL ANALYSIS
AND OTHER RADIOMETRIC
EMANATION METHODS
BY V BALEK AND J TOLGYESSY
ELSEVIER
AMSTERDAM OXFORD NHW YORK
CONTENTS
FOREWORD IX
INTRODUCTION 1
References 2
Chapter I BASIC PRINCIPLES AND HISTORICAL DEVELOPMENT 3
1 1 Radioactive inert gases as universal trace indicators 3
1 2 Terminology 4
1 3 Historical development 4
References 7
Chapter 2 LABELLING OF SAMPLES 9
2 1 Inert gas sources 9
211 Nuclear reactions producing inert gases 13
212 Labelling sources 15
2 2 Techniques introducing the parent nuclide of inert ga 15
221 Incorporation technique 15
222 Impregnation technique 16
223 Recoil technique • 17
224 Use of inert gas radiogenic formation in mineral^ 18
225 Production of inert gas atoms from corresponding parent nuclides 18
2 3 Techniques introducing the inert gas without parent 21
231 Techniques utilizing the recoil energy of nuclear reactions 2 1
2311 Alpha-decay 21
2312 Neutron-activated reactions 22
232 Ion bombardment 23
2 3 21 Apparatus 23
2322 Trapping efficiency 26
2323 Penetration of inert gas ions 28
2324 Saturation value 33
233 Diffusion technique 34
234 Direct gas introduction during sample preparation or phase transition 38
2 4 The choice of labelling technique 40
References 41
XI
I
Chapter 3 INERT GAS RELEASE FROM SOLIDS CONTAINING CORRESPONDING
PARETN NUCLIDES 43
3 1 Processes of inert gas release 43
3 2 Recoil emanating power, £„ 45
321 The spherical grain 45
322 The cubic grain, slab and the cylindrical sample 47
323 Recoil emanating power and surface area 48
324 Estimation of recoil range, R 48
3 3 Diffusion emanation power, ED 49
331 The spherical grain 49
332 The cylindrical sample 52
3 4 Total emanating power 53
3 5 Apparent emanating power and its time dependence 53
3 6 Emanation power of a finely dispersed solid 54
3 7 Temperature dependence of emanating power 56
371 Direct recoil emanating power, ERd 56
372 Indirect recoil emanating power, 56
373 Diffusion emanation power, E„ 57
3 8 Factors influencing the emanating power of solids 58
381 Porosity 58
382 Adsorption of inert gas 59
383 Adsorption of liquids 60
384 Grain size (surface area) 60
385 Texture and structure 60
386 Structural and chemical changes 62
387 Mechanical treatment 64
388 Radiation damage , 64
389 Non-equilibrium defects 65
3 8 10 Impurities 67
3 8 11 Non-stoichiometry 68
3 9 Information from emanating power measurement 69
References 71
Chapter 4 RELEASE OF INERT GAS INCORPORATED WITHOUT PARENT IN
SOLIDS - 72
4 1 Kinetics of inert gas release 73
411 Homogeneous gas distribution 73
412 Non-homogeneous gas distribution 77
4 2 Inert gas release during non-isothermal heating 81
421 Approaches to evaluate release curves of the I —T type 85
422 Approaches to evaluate release curves of the (i F/dT) - T type 86
423 Temperature dependence of diffusion 89
4 3 Inert gas release during surface destructions of labelled solid 92
4 4 Factors influencing the mobility of inert gas in solids 95
441 Natural crystal defects 95
442 Impurities 96
443 Radiation damage and its annealing 98
444 Crystal lattice parameters and orientation 102
445 Type of inert gas and its concentration 105
446 Evaporation of the sample 108
XII
4 5 Classification and models of inert gas mobility 109
451 System of stages for inert gas mobility 109
4511 Gas-release from high mobility sites (stage I A) 110
4512 Annealing of structural radiation damage (stage IB) 112
4513 Normal volume diffusion (unperturbed ;as mobility) (stage IIA) 113
4514 Retarded gas release due to a weak trapping (stage I IB) 114
4515 Gas filled bubbles (stage III) 114
452 Possible diffusion mechanism 116
4521 Vacancy diffusion 116
4522 Interstitial diffusion 117
4523 Interstitial diffusion plus trapping 117
4524 Mobile cluster diffusion 118
References 120
Chapter-5 MEASUREMENT OF INERT GAS RELI SE
AND INSTRUMENTATION
5 1 Methods of inert gas release determination
511 Released fraction F of inert gas
512 Release rate dF/dt of inert gas
5 2 The equipment for inert gas release measurement
521 Inert gas detection
5211 Measuring chambers
5212 Monitoring and recording of inert gas release
522 Systems of carrier gas flow and stabilization
523 Sample heating, temperature control and measurement
524 Complementary measuring systems
525 Radiation safety of ETA measurements
5 3 The apparatus response of the inert gas release
531 Mathematical analysis of practical cases
5 4 Some recommendations for practice
References j
Chapter 6 APPLICATIONS OF ETA 145
6 1 Scope and limitations of the method 145
611 Potentialities of ETA investigations 145
612 Limitations of the method 146
6 2 Surface area investigations 147
621 Direct surface area measurements 147
622 Development and changes in the surface of gelous materials 148
623 Sintering and related phenomena 150
6 3 Investigations of single phase systems 153
631 Inert gas release as a probe of the state of solids 153
6311 Mobility of inert gas atoms in relation to other properties of solids 153
6312 Emanation characteristics of rocks and minerals 159
632 Characterization of material properties 161
6321 Texture and morphology of materials and annealing of lattice defects 161
6322 Sinterability of materials 164
6323 Characterization of heat-treated producis 165
633 Defect equilibrium changes at elevated temperatures in non-stotichiometric solids 167
XIII
6 4 Physical changes in multi-phase systems 169
641 Phase transitions in solids 169
642 Crystallization and recrystallization of solids 170
643 Melting 172
644 Phase diagrams of multicomponent systems 174
6 5 Chemical reactions in solids 174
651 Dehydration and thermal decomposition 174
6511 Revealing structure and texture changes and the active state of solids 176
6512 Relation of ETA, DTA and TG curves 177
652 Solid-gas reactions 179
6521 Kinetic study of reduction and oxidation 179
6522 Application to heterogeneous catalysis 182
653 Solid-liquid reactions 183
6531 Hydration 183
654 Solid-solid reactions 183
6541 Information on reaction mechanisms 183
6542 Estimating reactivity of components in reaction mixtures 186
References 188
Chapter 7 ANALYTICAL CHEMISTRY APPLICATIONS 191
7 1 Determination of natural radioelements 191
711 Methodical procedures 191
712 Determination of individual elements 192
7121 Radon and radium 192
7122 Actinium 196
7123 Thorium 196
7124 Radon (222Rn) and thoron (220Rn) in the presence of each other 198
7 2 Applications of solids labelled by inert radioactive gases 199
721 Analysis of non-radioactive gases 200
7211 Oxygen 200
7 2 Ij2 Hydrogen 203
7213 Determination of air pollutants 207
72131 Ozone 209
72132 Sulphur dioxide 212
72133 Fluorine, hydrogen fluoride 213
72134 Mercury 217
72135 Carbon monoxide 221
72136 Water vapour 222
72137 Benzene and carbon tetrachloiide 226
7214 Analyzers 227
722 Analysis of solutions 229
7221 Non-aqueous solutions 230
7222 Determination of water pollutants 230
72221 Oxygen 231
72222 Measurement of pH 233
72223 Dichromate 235
72224 Vanadium 236
72225 Hydrochloric acid 237
72226 Sulphur dioxide 237
72227 Apparatus 237
XIV
723 Radiometric titrations
7231 Essence of the method
7232 Apparatus and procedures of titrations
72321 Discontinuous titrations
72322 Continuous titrations
7233 Types of titrations and applications
72331 Radiocomplexometric titrations
72332 Precipitation titrations
72333 Neutralization titrations
72334 Redox titrations
7234 Thermoradiometric titrations
References
Chapter 8 TECHNICAL APPLICATIONS
8 1 Measurement of surface temperatures
8 2 Investigation of friction
8 3 Investigation of the wearing process
8 4 Testing of corrosion endurance of materials
8 5 Determination of the rate constant of corrosion
8 6 Testing of building materials
861 Characterization of cement hydration processes
862 Thermal stability of mortar and concrete
863 Chemical endurance of hardened cement paste
8 7 Characterization of materials in conditions required by technology
871 Calcination and firing of oxide mixtures for feriite production
872 Preparation of nuclear ceramic fuel materials
873 Fixation of radioactive waste
References
PRESENT STATE AND FUTURE OF RADIOMETRIC EMANATION METHODS
SUBJECT IN if EX
XV
|
| any_adam_object | 1 |
| author | Balek, Vladimír Tölgyessy, Juraj 1931-2014 |
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| dewey-ones | 543 - Analytical chemistry |
| dewey-raw | 543 543/.088 |
| dewey-search | 543 543/.088 |
| dewey-sort | 3543 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV001062301 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T15:23:16Z |
| institution | BVB |
| isbn | 0444996591 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000642819 |
| oclc_num | 9218137 |
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| owner_facet | DE-19 DE-BY-UBM DE-83 DE-188 DE-355 DE-BY-UBR |
| physical | XV, 303 S. Ill., graph. Darst. |
| publishDate | 1984 |
| publishDateSearch | 1984 |
| publishDateSort | 1984 |
| publisher | Elsevier |
| record_format | marc |
| series | Wilson and Wilson's comprehensive analytical chemistry |
| series2 | Wilson and Wilson's comprehensive analytical chemistry |
| spelling | Balek, Vladimír Verfasser aut Emanation thermal analysis and other radiometric emanation methods by V. Balek and J. Tölgyessy Amsterdam [u.a.] Elsevier 1984 XV, 303 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wilson and Wilson's comprehensive analytical chemistry 12,C : Thermal analysis Literaturangaben Analyse radiochimique ram Analyse thermique ram Chimie analytique ram Radiochemical analysis Tölgyessy, Juraj 1931-2014 Verfasser (DE-588)1158007108 aut Wilson and Wilson's comprehensive analytical chemistry 12,C : Thermal analysis (DE-604)BV000900805 12,3 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000642819&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Balek, Vladimír Tölgyessy, Juraj 1931-2014 Emanation thermal analysis and other radiometric emanation methods Wilson and Wilson's comprehensive analytical chemistry Analyse radiochimique ram Analyse thermique ram Chimie analytique ram Radiochemical analysis |
| title | Emanation thermal analysis and other radiometric emanation methods |
| title_auth | Emanation thermal analysis and other radiometric emanation methods |
| title_exact_search | Emanation thermal analysis and other radiometric emanation methods |
| title_full | Emanation thermal analysis and other radiometric emanation methods by V. Balek and J. Tölgyessy |
| title_fullStr | Emanation thermal analysis and other radiometric emanation methods by V. Balek and J. Tölgyessy |
| title_full_unstemmed | Emanation thermal analysis and other radiometric emanation methods by V. Balek and J. Tölgyessy |
| title_short | Emanation thermal analysis and other radiometric emanation methods |
| title_sort | emanation thermal analysis and other radiometric emanation methods |
| topic | Analyse radiochimique ram Analyse thermique ram Chimie analytique ram Radiochemical analysis |
| topic_facet | Analyse radiochimique Analyse thermique Chimie analytique Radiochemical analysis |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000642819&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000900805 |
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