Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming: from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VII, 203 S. Ill., graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming |b from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries |c von Christoph Stock |
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| 502 | |a Münster, Univ., Diss. 2012 | ||
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Datensatz im Suchindex
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| adam_text | TABLE OF CONTENTS
I INTRODUCTION AND MOTIVATION 1
II QUARTZ CRYSTAL MICROBALANCE AND THERMODYNAMICAL PHENOMENA 5
1 QUARTZ CRYSTAL MICROBALANCE 6
1.1 HOW DOES OSCILLATION OCCUR? 6
1.2 MODELING THE RESONANCE BEHAVIOR OF QUARTZ CRYSTAL 8
1.2.1 STANDING WAVE AND SAUERBREY BEHAVIOR 8
1.2.2 BUTTERWORTH VAN DYKE IMPEDANCE MODEL 9
1.2.3 ENERGY TRANSFER MODEL (ETM) 12
1.2.4 KANAZAWA UND SAUERBREY BEHAVIOR AS BORDERING CASE OF THE ENERGY
TRANSFER MODEL 15
1.3 MEASUREMENT METHODS FOR QCM 16
1.4 SETUP OF THE FIS QCM 21
1.4.1 SCHEDULER 21
1.4.2 HARDWARE SETUP 21
1.4.3 OPTIMIZATION OF HARDWARE ELEMENTS 22
1.4.4 OPTIMIZATION OF SCHEDULER 24
2 EXPERIMENTAL METHODS BASED ON QCM MEASUREMENTS 27
2.1 MATERIALS AND MEASUREMENT DEVICES 27
2.1.1 MEASUREMENT DEVICES 27
2.1.2 CHEMICALS 28
2.2 COMPRESSIBILITY AND SPEED OF SOUND IN LIQUIDS 29
2.2.1 COMPRESSION WAVE IN FLUID MEDIA 29
2.2.2 EXPERIMENTAL SETUP AND PROCEDURE 30
2.3 SOLUBILITY OF SOLIDS IN LIQUIDS 31
2.3.1 THEORY: SOLUBILITY OF SOLIDS 31
2.3.2 EXPERIMENTAL SETUP AND PROCEDURE 35
2.4 SOLUBILITY OF GASES IN HIGH-BOILING ADSORBENTS 36
2.4.1 THEORY OF GAS SOLUBILITY 36
2.4.2 THIN LIQUID FILMS AND LIQUIDS PROPERTIES 42
2.4.3 EXPERIMENTAL SETUP AND PROCEDURE 43
3 RESULTS AND DISCUSSION 46
3.1 COMPRESSIBILITY OF LIQUIDS 46
V
HTTP://D-NB.INFO/1046128515
3.1.1 DATA EVALUATION FROM MOVING BORDER EXPERIMENT ON QCM 46
3.1.2 COMPRESSIBILITY OF WATER 48
3.1.3 COMPRESSIBILITY OF L-ETHYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE
49
3.1.4 RESULTS AND DISCUSSION 50
3.2 SOLUBILITY OF SOLIDS IN LIQUIDS 51
3.2.1 DATA EVALUATION FOR OBTAINING SOLUBILITY OF SOLIDS 51
3.2.2 SOLUBILITY OF POTASSIUM CHLORIDE IN WATER 52
3.2.3 NON-AQUEOUS SYSTEMS FOR SOLUBILITY MEASUREMENTS 53
3.2.4 EVALUATION AND COMPARISON TO ESTABLISHED PROCEDURES 54
3.3 GAS SOLUBILITY 54
3.3.1 CALIBRATION OF THE MASS SENSITIVITY 54
3.3.2 CALIBRATION OF DAMPING DUE TO PRESSURE 56
3.3.3 DATA EVALUATION FOR GAS SOLUBILITY MEASUREMENT 58
3.3.4 EVALUATION AND COMPARISON OF THIS METHOD WITH OTHER ESTABLISHED
METHODS 61
III SILICON AS HIGH CAPACITY ANODE MATERIAL IN LITHIUM ION BATTERIES 63
1 LITHIUM ION BATTERIES IN GENERAL 64
1.1 ELECTRODE MATERIALS 67
1.1.1 CATHODE MATERIALS 68
1.1.2 ANODE MATERIALS 69
1.1.3 CONDUCTIVE AGENTS 72
1.1.4 BINDER 73
1.2 SEPARATOR 76
1.3 ELECTROLYTE 76
1.3.1 LIQUID ELECTROLYTES 77
1.3.2 SOLID POLYMER ELECTROLYTES 78
1.3.3 IONIC LIQUIDS 80
1.3.4 LITHIUM SALTS 80
1.3.5 ADDITIVES 81
1.4 SILICON AS ANODE MATERIAL 84
1.4.1 LOSS OF CAPACITY 87
1.4.2 STRATEGIES TO ENHANCE CYCLE LIFE OF ALLOYING ANODE MATERIALS 89
2 EXPERIMENTAL METHODS 91
VI
2.1 MEASUREMENT EQUIPMENT AND CHEMICALS 91
2.1.1 MEASUREMENT EQUIPMENT 91
2.1.2 CHEMICALS 95
2.2 ANALYTICAL METHODS 96
2.2.1 ELECTROCHEMICAL MEASUREMENT METHODS 96
2.2.2 ADDITIONAL MEASUREMENT METHODS 103
2.3 ELECTRODE PREPARATION 109
2.4 SYNTHESIS ILL
2.4.1 SYNTHESIS OF POLYACRYLAMIDE BASED BINDERS ILL
2.4.2 SYNTHESIS OF POLY(IMIDE) BINDER 112
2.4.3 MODIFICATION OF SILICON PARTICLES 113
RESULTS AND DISCUSSION 115
3.1 ELECTROCHEMICAL BEHAVIOR OF SILICON GRAPHITE COMPOSITE ELECTRODES
115
3.1.1 INFLUENCE OF ELECTRODE THICKNESS ON ELECTROCHEMICAL PERFORMANCE
115
3.1.2 INFLUENCE OF COMPRESSION ON ELECTROCHEMICAL PERFORMANCE 121
3.1.3 REMARKS AND CONCLUSION ON ELECTRODES PROCESSING 133
3.2 NEW BINDER SYSTEMS 135
3.2.1 POLY(ACRYLAMIDE) BASED BINDERS 135
3.2.2 POLY(IMIDE) BINDER 143
3.2.3 CONCLUSION ON THE TEST OF BINDER SYSTEMS 149
3.3 SEI FORMING ADDITIVES 149
3.3.1 FLUOROETHYLENE CARBONATE AS SEI FORMING ADDITIVE 150
3.3.2 ACRYLAMIDE AS POLYMERIZABLE ADDITIVE 156
3.3.3 ISOCYANATE BASED ELECTROLYTE ADDITIVES 162
3.3.4 REMARKS AND CONCLUSION ON ADDITIVES 169
3.4 ARTIFICIAL SEI 170
3.4.1 THERMAL STABILITY OF THE FUNCTIONAL COATING 171
3.4.2 SPECTROSCOPIC ANALYSIS OF THE FUNCTIONAL COATING 172
3.4.3 ELECTROCHEMICAL CHARACTERIZATION OF FUNCTIONAL COATING 174
3.4.4 REMARKS AND CONCLUSION ON THE ARTIFICIAL SEI 182
/ RECAPITULATION AND OUTLOOK 185
REFERENCES 192
|
| any_adam_object | 1 |
| author | Stock, Christoph 1983- |
| author_GND | (DE-588)104603264X |
| author_facet | Stock, Christoph 1983- |
| author_role | aut |
| author_sort | Stock, Christoph 1983- |
| author_variant | c s cs |
| building | Verbundindex |
| bvnumber | BV041699731 |
| ctrlnum | (OCoLC)870909493 (DE-599)BVBBV041699731 |
| dewey-full | 541.342 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.342 |
| dewey-search | 541.342 |
| dewey-sort | 3541.342 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| language | English |
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| physical | VII, 203 S. Ill., graph. Darst. |
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| spelling | Stock, Christoph 1983- Verfasser (DE-588)104603264X aut Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries von Christoph Stock 2012 VII, 203 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Münster, Univ., Diss. 2012 Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Lithium-Ionen-Akkumulator (DE-588)7681721-0 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027140083&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Stock, Christoph 1983- Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd |
| subject_GND | (DE-588)7681721-0 (DE-588)4113937-9 |
| title | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries |
| title_auth | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries |
| title_exact_search | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries |
| title_full | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries von Christoph Stock |
| title_fullStr | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries von Christoph Stock |
| title_full_unstemmed | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries von Christoph Stock |
| title_short | Development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming |
| title_sort | development of new methods for fast impedance scanning quartz microbalance measurements including optimization of electronics and programming from evaluation of solubility of solids and gases in liquids to studies of lithium alloy anodes for lithium ion batteries |
| title_sub | from evaluation of solubility of solids and gases in liquids to studies of lithium-alloy anodes for lithium ion batteries |
| topic | Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd |
| topic_facet | Lithium-Ionen-Akkumulator Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027140083&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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