Topics in polymer physics:
Gespeichert in:
| Hauptverfasser: | , |
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| Format: | Buch |
| Sprache: | English |
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London
Imperial College Press
2006
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 414 S. graph. Darst. |
| ISBN: | 1860944116 1860944124 9781860944123 |
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Datensatz im Suchindex
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| adam_text | *N TOPICS IN POLYMER PHYSICS * V RICHARD S STEIN GOESSMANN PROFESSOR OF
CHEMISTRY, EMERITUS UNIVERSITY OF MASSACHUSETTS, AMHERST JOSEPH POWERS
UNITED TECHNOLOGIES CORPORATION, RETIRED (^ IMPERIAL COLLEGE PRESS
CONTENTS DEDICATION V PREFACE VII CHAPTER 1 1 INTRODUCTION 1 1.1.
BACKGROUND 1 1.2. LINEAR CHAIN MOLECULES 4 1.2.1. STRUCTURE 4 1.2.2.
SYNTHESIS 8 1.2.3. MOLECULAR WEIGHT 10 1.3. NETWORK MOLECULES 15 1.3.1.
STRUCTURE 15 1.3.2. SYNTHESIS 16 1.3.3. MOLECULAR WEIGHT 16 1.4. RUBBER
17 1.4.1. STRUCTURE 17 1.4.2. SYNTHESIS 21 1.4.3. MOLECULAR WEIGHT 21
1.5. MULTICOMPONENT SYSTEMS 21 1.5.1. COPOLYMERS 21 1.5.2. POLYBLENDS 25
1.5.3. COMPOSITES 25 1.5.4. CERAMERS 26 REFERENCES 27 APPENDIX 1A -
DERIVATION OF THE MOST PROBABLE DISTRIBUTION 28 REFERENCE 30 CHAPTER 2
31 STATISTICS OF CHAIN CONFORMATIONS 31 2.1. INTRODUCTION 31 2.2. SMALL
MOLECULES 31 2.3. LARGER MOLECULES, STATISTICAL VARIATION OF MOLECULAR
CONFORMATIONS 40 2.4. STATISTICAL SEGMENT MODEL 41 2.5. GENERALIZATION
TO HIGH POLYMERS 44 2.6. POLYMER CHAINS CONTAINING TWO KINDS OF ATOMS 45
IX TOPICS IN POLYMER PHYSICS 2.7. MODEL CHAINS WITH RESTRICTED ROTATION
AND NO INTERACTION AMONG THE $ S 47 2.8. ROTATIONAL ISOMERIC STATE (RIS)
APPROXIMATION 49 2.9. CHAINS WITH INTERACTIONS BETWEEN * VALUES OF
NEIGHBORING MONOMERS 51 2.10. ASYMMETRIC BARRIERS 53 2.11. COMPARISON
WITH EXPERIMENT 56 2.12. CHAIN END-TO-END DISTRIBUTION FUNCTIONS 58
2.12.1 ONE DIMENSIONAL CASE 58 2.12.2. EXTENSION TO A THREE DIMENSIONAL
CHAIN 61 2.12.3. EXTENSION TO NON-GAUSSIAN CASE 64 REFERENCES 71
APPENDIX 2A - STATISTICAL MECHANICS 73 REFERENCES 80 STATISTICAL
THERMODYNAMICS OF AN IDEAL MONATOMIC GAS 81 APPENDIX 2B - VECTOR
ANALYSIS 83 2B.1. VECTOR ADDITION 83 2.B.2 SCALAR PRODUCT 84 REFERENCE
85 APPENDIX 2C - RADIUS OF GYRATION 86 APPENDIX 2D. EVALUATION OF ( A
M+N * ^M ) 92 APPENDIX 2E. RESTRICTED ROTATION WITH SYMMETRICAL *
AIRIER. 99 APPENDIX 2F. ROTATIONAL ISOMERIC STATE (RIS) APPROXIMATION
103 2F.1. INTRODUCTION 103 2F.2. THE CONFORMATIONAL PARTITION FUNCTION
104 2E.3. MEAN SQUARE DISTANCE 106 REFERENCES 107 APPENDIX 2G. RANDOM
WALK OF GAUSSIAN CHAINS 109 REFERENCES 113 APPENDIX 2H. RADIUS OF
GYRATION, SIZE AND SHAPE 114 DEFINITION OF (R* 114 /R Q2 FOR A RIGID
ROD 115 /I-Q FOR A SPHERE OF RADIUS R 116 X CONTENTS DETERMINATION OF
/** FROM SCATTERING 117 CHAPTER 3 121 THERMODYNAMICS 121 3.1.
INTRODUCTION 121 3.2 THERMODYNAMICS OF ELASTICITY 121 3.3. FORCE ON A
CHAIN IN THE PRESENCE OF ENERGY CONTRIBUTIONS TO ELASTICITY 129 3.4.
SOLUTION THERMODYNAMICS 134 3.4.1. FLORY-HUGGINS THEORY 134 3.4.2.
CALCULATION OF P 2 138 3.3.3. ENTROPY OF MIXING 140 3.5. POLYMER
MISCIBILITY 145 3.6. SPINODAL DECOMPOSITION 147 3.7. HEAT CAPACITY 153
3.8. THERMODYNAMICS OF CRYSTALLIZATION 154 3.8.1 POLYMER STRUCTURE -
MELTING POINT 155 3.8.2. EFFECT OF DILUENT AND IMPURITIES 157 3.8.3.
CRYSTALLIZATION INDUCED BY STRETCHING 164 REFERENCES 167 APPENDIX **
CLASSICAL THERMODYNAMICS 169 REFERENCES 175 APPENDIX 3B. HEAT OF MIXING
176 APPENDIX 3C OSMOTIC PRESSURE 181 CHAPTER 4 185 OPTICS 185 4.1.
INTRODUCTION 185 4.2. NATURE OF ELECTROMAGNETIC WAVES 186 4.3.
REFRACTION 187 4.4. SCATTERING 191 4.4.1. INTENSITY OF LIGHT SCATTERING
FOR AN ISOLATED ATOM OR MOLECULE 194 4.4.2. EFFECT OF THE POLARIZATION
OF LIGHT 195 4.4.3. THE SCATTERING INTENSITY FOR A COLLECTION OF
SCATTERING OBJECTS 196 4.5. DIFFRACTION 205 XI TOPICS IN POLYMER PHYSICS
4.5.1.THE RECIPROCAL LATTICE 205 4.5.2. INTERPRETATION OF THE VECTOR
BRAGG EQUATION 208 4.5.3. THE DISTANCE BETWEEN CRYSTAL PLANES 209 4.5.4.
THE DIFFRACTION PHENOMENON IN ONE DIMENSION..211 4.6. ABSORPTION 215
4.7. FLUORESCENCE 216 4.8. BIREFRINGENCE 218 4.9. SCATTERING FROM
INHOMOGENEOUS MEDIA 222 4.10. QUASI-ELASTIC LIGHT SCATTERING 228 4.11.
VARIATION OF SCATTERING WITH ELECTRIC FIELDS 229 4.12. NON-LINEAR OPTICS
230 4.13. PIEZO-ELECTRIC MATERIALS 232 4.14. KERR EFFECT 233 REFERENCES
234 APPENDIX 4A DEPOLARIZATION OF SCATTERING 236 APPENDIX 4B SCATTERING
FROM A COLLECTION OF MOLECULES 239 APPENDIX 4D THE MAGNITUDE OF THE
RECIPROCAL VECTOR H ...244 APPENDIX 4E ORIENTATION FLUCTUATIONS 246
APPENDIX 4F SCATTERING FROM CONCENTRATION FLUCTUATIONS ...249 EVALUATION
OF (**/**) 252 EVALUATION OF *-(*,/ MOLECULAR WEIGHT FROM LIGHT
SCATTERING 253 DEALING WITH LARGE MOLECULES 255 EXTENSIONS TO OTHER
KINDS OF RADIATION 256 EXTENSIONS TO CONCENTRATED SOLUTION AND BULK
POLYMERS 257 EFFECT OF ANISOTROPY AND ORIENTATION 257 APPENDIX 4G WHY
CONCENTRATION FLUCTUATIONS RELATE TO MOLECULAR WEIGHT 257 HOW TO MEASURE
THE SIZE OF AN ELEPHANT 258 ANOTHER WAY OF LOOKING AT IT - 260 CHAPTER 5
263 ELECTRICAL PROPERTIES 263 5.1 INTRODUCTION 263 5.2. DIELECTRICS 264
XII CONTENTS 5.2.1. DIELECTRIC CONSTANT 264 5.2.2. ORIENTATION OF
PERMANENT DIPOLES 269 5.2.3. DIELECTRIC LOSS 269 5.3. PIEZO- AND
PYROELECTRIC EFFECTS 272 5.4. PIEZO-ELECTRIC COEFFICIENT 274 REFERENCES
276 APPENDIX 5A. LINES OF FLUX 278 5A.1. ELECTRICAL FIELD STRENGTH 278
5A.2. ELECTRIC DISPLACEMENT AND FLUX DENSITY 278 5A.4. THE ELECTROSTATIC
POTENTIAL (VOLTAGE) 280 5A.5. THE FIELD BETWEEN PARALLEL PLATES 280
APPENDIX 5B. LORENTZ CALCULATION, INTERNAL FIELD CORRECTION 282 CHAPTER
6 285 SPECTROSCOPY 285 6.1. INTRODUCTION 285 6.2. GENERAL BACKGROUND 286
6.3. INFRARED 288 6.4. RAMAN 295 6.5. ULTRAVIOLET AND VISIBLE 299 6.6.
NUCLEAR MAGNETIC RESONANCE 300 6.7. NEUTRON INELASTIC SCATTERING (NIS)
301 REFERENCES 303 APPENDIX 6A FOURIER TRANSFORM INFRARED (FTIR) 305
REFERENCES 307 APPENDIX 6B. NORMAL COORDINATE ANALYSIS 308 REFERENCES
312 APPENDIX 6C. SPECTROGRAPHIC NOTATION 313 CHAPTER 7 314 THE RUBBERY
STATE 314 7.1. INTRODUCTION 314 7.2. FORCE - EXTENSION RELATION FOR
RUBBERS 316 7.2.1. SIMPLE CASE 316 7.2.2. CONSIDERATION OF NETWORK
CROSSLINKS 318 7.3. AFFINE TRANSFORMATION 322 7.4. UNIAXIAL STRETCHING
AT CONSTANT VOLUME 329 XIII TOPICS IN POLYMER PHYSICS 7.5. BIAXIAL
STRETCHING AT CONSTANT VOLUME 331 7.6. APPLICATION TO THE INFLATION OF A
BALLOON 333 7.7. NETWORK DEFECTS -THE RELATIONSHIP BETWEEN N C AND V
.334 7.8. EFFECT OF SWELLING ON AN ISOTROPIC NETWORK 336 7.9. ELASTIC
PROPERTIES OF SWOLLEN RUBBER 339 7.10. ELASTICITY OF A SAMPLE THAT IS
SWOLLEN WHEN CROSSLINKED. 341 7.11. ELASTICITY OF RUBBERS AT SMALL
EXTENSIONS 343 7.12. GUTH-SMALLWOOD EQUATIONS 347 REFERENCES 348
APPENDIX 7A - EVALUATION OF EQUATION 7.30 350 CHAPTER 8 352 THE
CRYSTALLINE STATE 352 8.1. INTRODUCTION 352 8.2. EVIDENCE FOR
CRYSTALLINITY 354 8.2.1. X-RAY DIFFRACTION 354 8.2.2. ELECTRON
MICROSCOPICAL OBSERVATIONS 358 8.2.3. OPTICAL MICROSCOPY 359 8.2.4.
THERMODYNAMIC TRANSITIONS 360 8.3. DETERMINATION OF DEGREE OF
CRYSTALLINE 361 8.3.1. DENSITY MEASUREMENTS 361 8.3.2. X-RAY DIFFRACTION
364 8.3.3. INFRARED (IR) AND RAMAN 365 8.3.4. WIDE LINE NUCLEAR MAGNETIC
RESONANCE 366 8.3.5. THERMAL MEASUREMENTS 368 8.4. MORPHOLOGY 369 8.4.1.
ELECTRON MICROSCOPE 369 I) THE OBSERVED PYRAMIDAL STRUCTURE 369 II)
MOIRE PATTERNS 370 I.) DENSITY 370 II) NMR 371 III) X-RAY DIFFRACTION
371 IV) KINETICS 371 8.4.2. OPTICAL MICROSCOPY 372 8.4.3. LIQUID
CRYSTALS 373 8.5 MECHANISMS OF CRYSTALLIZATION 375 XIV CONTENTS 8.5.1.
NUCLEATION AND GROWTH 375 8.6. KINETICS OF CRYSTALLIZATION 376 8.6.1.
TEMPERATURE DEPENDENCE OF THE NUCLEATION RATE. 376 8.6.2. NUCLEATION AND
GROWTH 379 8.6.3. EXPERIMENTAL DETERMINATION OF N AND * 384 I.
SLOPE-INTERCEPT METHOD 384 II. HALF-LIFE METHOD 385 8.6.4. TEMPERATURE
DEPENDENCE OF THE RATE OF HOMOGENEOUS CRYSTALLIZATION 386 REFERENCES 387
GLOSSARY OF SYMBOLS ARRANGED BY CHAPTERS 389 CHAPTER 1 389 CHAPTER 2 389
CHAPTER 3 392 CHAPTER 4 396 CHAPTER 5 398 CHAPTER 7 402 CHAPTER 8 403
INDEX 407 XV
|
| adam_txt |
*N TOPICS IN POLYMER PHYSICS * V RICHARD S STEIN GOESSMANN PROFESSOR OF
CHEMISTRY, EMERITUS UNIVERSITY OF MASSACHUSETTS, AMHERST JOSEPH POWERS
UNITED TECHNOLOGIES CORPORATION, RETIRED (^ IMPERIAL COLLEGE PRESS
CONTENTS DEDICATION V PREFACE VII CHAPTER 1 1 INTRODUCTION 1 1.1.
BACKGROUND 1 1.2. LINEAR CHAIN MOLECULES 4 1.2.1. STRUCTURE 4 1.2.2.
SYNTHESIS 8 1.2.3. MOLECULAR WEIGHT 10 1.3. NETWORK MOLECULES 15 1.3.1.
STRUCTURE 15 1.3.2. SYNTHESIS 16 1.3.3. MOLECULAR WEIGHT 16 1.4. RUBBER
17 1.4.1. STRUCTURE 17 1.4.2. SYNTHESIS 21 1.4.3. MOLECULAR WEIGHT 21
1.5. MULTICOMPONENT SYSTEMS 21 1.5.1. COPOLYMERS 21 1.5.2. POLYBLENDS 25
1.5.3. COMPOSITES 25 1.5.4. CERAMERS 26 REFERENCES 27 APPENDIX 1A -
DERIVATION OF THE MOST PROBABLE DISTRIBUTION 28 REFERENCE 30 CHAPTER 2
31 STATISTICS OF CHAIN CONFORMATIONS 31 2.1. INTRODUCTION 31 2.2. SMALL
MOLECULES 31 2.3. LARGER MOLECULES, STATISTICAL VARIATION OF MOLECULAR
CONFORMATIONS 40 2.4. STATISTICAL SEGMENT MODEL 41 2.5. GENERALIZATION
TO HIGH POLYMERS 44 2.6. POLYMER CHAINS CONTAINING TWO KINDS OF ATOMS 45
IX TOPICS IN POLYMER PHYSICS 2.7. MODEL CHAINS WITH RESTRICTED ROTATION
AND NO INTERACTION AMONG THE $'S 47 2.8. ROTATIONAL ISOMERIC STATE (RIS)
APPROXIMATION 49 2.9. CHAINS WITH INTERACTIONS BETWEEN * VALUES OF
NEIGHBORING MONOMERS 51 2.10. ASYMMETRIC BARRIERS 53 2.11. COMPARISON
WITH EXPERIMENT 56 2.12. CHAIN END-TO-END DISTRIBUTION FUNCTIONS 58
2.12.1 ONE DIMENSIONAL CASE 58 2.12.2. EXTENSION TO A THREE DIMENSIONAL
CHAIN 61 2.12.3. EXTENSION TO NON-GAUSSIAN CASE 64 REFERENCES 71
APPENDIX 2A - STATISTICAL MECHANICS 73 REFERENCES 80 STATISTICAL
THERMODYNAMICS OF AN IDEAL MONATOMIC GAS 81 APPENDIX 2B - VECTOR
ANALYSIS 83 2B.1. VECTOR ADDITION 83 2.B.2 SCALAR PRODUCT 84 REFERENCE
85 APPENDIX 2C - RADIUS OF GYRATION 86 APPENDIX 2D. EVALUATION OF ( A
M+N * ^M ) 92 APPENDIX 2E. RESTRICTED ROTATION WITH SYMMETRICAL *
AIRIER. 99 APPENDIX 2F. ROTATIONAL ISOMERIC STATE (RIS) APPROXIMATION
103 2F.1. INTRODUCTION 103 2F.2. THE CONFORMATIONAL PARTITION FUNCTION
104 2E.3. MEAN SQUARE DISTANCE 106 REFERENCES 107 APPENDIX 2G. RANDOM
WALK OF GAUSSIAN CHAINS 109 REFERENCES 113 APPENDIX 2H. RADIUS OF
GYRATION, SIZE AND SHAPE 114 DEFINITION OF (R*\ 114 /R Q2 \ FOR A RIGID
ROD 115 /I-Q\ FOR A SPHERE OF RADIUS R 116 X CONTENTS DETERMINATION OF
/**\ FROM SCATTERING 117 CHAPTER 3 121 THERMODYNAMICS 121 3.1.
INTRODUCTION 121 3.2 THERMODYNAMICS OF ELASTICITY 121 3.3. FORCE ON A
CHAIN IN THE PRESENCE OF ENERGY CONTRIBUTIONS TO ELASTICITY 129 3.4.
SOLUTION THERMODYNAMICS 134 3.4.1. FLORY-HUGGINS THEORY 134 3.4.2.
CALCULATION OF P 2 138 3.3.3. ENTROPY OF MIXING 140 3.5. POLYMER
MISCIBILITY 145 3.6. SPINODAL DECOMPOSITION 147 3.7. HEAT CAPACITY 153
3.8. THERMODYNAMICS OF CRYSTALLIZATION 154 3.8.1 POLYMER STRUCTURE -
MELTING POINT 155 3.8.2. EFFECT OF DILUENT AND IMPURITIES 157 3.8.3.
CRYSTALLIZATION INDUCED BY STRETCHING 164 REFERENCES 167 APPENDIX **
CLASSICAL THERMODYNAMICS 169 REFERENCES 175 APPENDIX 3B. HEAT OF MIXING
176 APPENDIX 3C OSMOTIC PRESSURE 181 CHAPTER 4 185 OPTICS 185 4.1.
INTRODUCTION 185 4.2. NATURE OF ELECTROMAGNETIC WAVES 186 4.3.
REFRACTION 187 4.4. SCATTERING 191 4.4.1. INTENSITY OF LIGHT SCATTERING
FOR AN ISOLATED ATOM OR MOLECULE 194 4.4.2. EFFECT OF THE POLARIZATION
OF LIGHT 195 4.4.3. THE SCATTERING INTENSITY FOR A COLLECTION OF
SCATTERING OBJECTS 196 4.5. DIFFRACTION 205 XI TOPICS IN POLYMER PHYSICS
4.5.1.THE RECIPROCAL LATTICE 205 4.5.2. INTERPRETATION OF THE VECTOR
BRAGG EQUATION 208 4.5.3. THE DISTANCE BETWEEN CRYSTAL PLANES 209 4.5.4.
THE DIFFRACTION PHENOMENON IN ONE DIMENSION.211 4.6. ABSORPTION 215
4.7. FLUORESCENCE 216 4.8. BIREFRINGENCE 218 4.9. SCATTERING FROM
INHOMOGENEOUS MEDIA 222 4.10. QUASI-ELASTIC LIGHT SCATTERING 228 4.11.
VARIATION OF SCATTERING WITH ELECTRIC FIELDS 229 4.12. NON-LINEAR OPTICS
230 4.13. PIEZO-ELECTRIC MATERIALS 232 4.14. KERR EFFECT 233 REFERENCES
234 APPENDIX 4A DEPOLARIZATION OF SCATTERING 236 APPENDIX 4B SCATTERING
FROM A COLLECTION OF MOLECULES 239 APPENDIX 4D THE MAGNITUDE OF THE
RECIPROCAL VECTOR H .244 APPENDIX 4E ORIENTATION FLUCTUATIONS 246
APPENDIX 4F SCATTERING FROM CONCENTRATION FLUCTUATIONS .249 EVALUATION
OF (**/**) 252 EVALUATION OF *-(*,/ MOLECULAR WEIGHT FROM LIGHT
SCATTERING 253 DEALING WITH LARGE MOLECULES 255 EXTENSIONS TO OTHER
KINDS OF RADIATION 256 EXTENSIONS TO CONCENTRATED SOLUTION AND BULK
POLYMERS 257 EFFECT OF ANISOTROPY AND ORIENTATION 257 APPENDIX 4G WHY
CONCENTRATION FLUCTUATIONS RELATE TO MOLECULAR WEIGHT 257 HOW TO MEASURE
THE SIZE OF AN ELEPHANT 258 ANOTHER WAY OF LOOKING AT IT - 260 CHAPTER 5
263 ELECTRICAL PROPERTIES 263 5.1 INTRODUCTION 263 5.2. DIELECTRICS 264
XII CONTENTS 5.2.1. DIELECTRIC CONSTANT 264 5.2.2. ORIENTATION OF
PERMANENT DIPOLES 269 5.2.3. DIELECTRIC LOSS 269 5.3. PIEZO- AND
PYROELECTRIC EFFECTS 272 5.4. PIEZO-ELECTRIC COEFFICIENT 274 REFERENCES
276 APPENDIX 5A. LINES OF FLUX 278 5A.1. ELECTRICAL FIELD STRENGTH 278
5A.2. ELECTRIC DISPLACEMENT AND FLUX DENSITY 278 5A.4. THE ELECTROSTATIC
POTENTIAL (VOLTAGE) 280 5A.5. THE FIELD BETWEEN PARALLEL PLATES 280
APPENDIX 5B. LORENTZ CALCULATION, INTERNAL FIELD CORRECTION 282 CHAPTER
6 285 SPECTROSCOPY 285 6.1. INTRODUCTION 285 6.2. GENERAL BACKGROUND 286
6.3. INFRARED 288 6.4. RAMAN 295 6.5. ULTRAVIOLET AND VISIBLE 299 6.6.
NUCLEAR MAGNETIC RESONANCE 300 6.7. NEUTRON INELASTIC SCATTERING (NIS)
301 REFERENCES 303 APPENDIX 6A FOURIER TRANSFORM INFRARED (FTIR) 305
REFERENCES 307 APPENDIX 6B. NORMAL COORDINATE ANALYSIS 308 REFERENCES
312 APPENDIX 6C. SPECTROGRAPHIC NOTATION 313 CHAPTER 7 314 THE RUBBERY
STATE 314 7.1. INTRODUCTION 314 7.2. FORCE - EXTENSION RELATION FOR
RUBBERS 316 7.2.1. SIMPLE CASE 316 7.2.2. CONSIDERATION OF NETWORK
CROSSLINKS 318 7.3. AFFINE TRANSFORMATION 322 7.4. UNIAXIAL STRETCHING
AT CONSTANT VOLUME 329 XIII TOPICS IN POLYMER PHYSICS 7.5. BIAXIAL
STRETCHING AT CONSTANT VOLUME 331 7.6. APPLICATION TO THE INFLATION OF A
BALLOON 333 7.7. NETWORK DEFECTS -THE RELATIONSHIP BETWEEN N C AND V
.334 7.8. EFFECT OF SWELLING ON AN ISOTROPIC NETWORK 336 7.9. ELASTIC
PROPERTIES OF SWOLLEN RUBBER 339 7.10. ELASTICITY OF A SAMPLE THAT IS
SWOLLEN WHEN CROSSLINKED. 341 7.11. ELASTICITY OF RUBBERS AT SMALL
EXTENSIONS 343 7.12. GUTH-SMALLWOOD EQUATIONS 347 REFERENCES 348
APPENDIX 7A - EVALUATION OF EQUATION 7.30 350 CHAPTER 8 352 THE
CRYSTALLINE STATE 352 8.1. INTRODUCTION 352 8.2. EVIDENCE FOR
CRYSTALLINITY 354 8.2.1. X-RAY DIFFRACTION 354 8.2.2. ELECTRON
MICROSCOPICAL OBSERVATIONS 358 8.2.3. OPTICAL MICROSCOPY 359 8.2.4.
THERMODYNAMIC TRANSITIONS 360 8.3. DETERMINATION OF DEGREE OF
CRYSTALLINE 361 8.3.1. DENSITY MEASUREMENTS 361 8.3.2. X-RAY DIFFRACTION
364 8.3.3. INFRARED (IR) AND RAMAN 365 8.3.4. WIDE LINE NUCLEAR MAGNETIC
RESONANCE 366 8.3.5. THERMAL MEASUREMENTS 368 8.4. MORPHOLOGY 369 8.4.1.
ELECTRON MICROSCOPE 369 I) THE OBSERVED PYRAMIDAL STRUCTURE 369 II)
MOIRE PATTERNS 370 I.) DENSITY 370 II) NMR 371 III) X-RAY DIFFRACTION
371 IV) KINETICS 371 8.4.2. OPTICAL MICROSCOPY 372 8.4.3. LIQUID
CRYSTALS 373 8.5 MECHANISMS OF CRYSTALLIZATION 375 XIV CONTENTS 8.5.1.
NUCLEATION AND GROWTH 375 8.6. KINETICS OF CRYSTALLIZATION 376 8.6.1.
TEMPERATURE DEPENDENCE OF THE NUCLEATION RATE. 376 8.6.2. NUCLEATION AND
GROWTH 379 8.6.3. EXPERIMENTAL DETERMINATION OF N AND * 384 I.
SLOPE-INTERCEPT METHOD 384 II. HALF-LIFE METHOD 385 8.6.4. TEMPERATURE
DEPENDENCE OF THE RATE OF HOMOGENEOUS CRYSTALLIZATION 386 REFERENCES 387
GLOSSARY OF SYMBOLS ARRANGED BY CHAPTERS 389 CHAPTER 1 389 CHAPTER 2 389
CHAPTER 3 392 CHAPTER 4 396 CHAPTER 5 398 CHAPTER 7 402 CHAPTER 8 403
INDEX 407 XV |
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| genre | (DE-588)4006432-3 Bibliografie gnd-content |
| genre_facet | Bibliografie |
| id | DE-604.BV021683173 |
| illustrated | Illustrated |
| index_date | 2024-07-02T15:12:01Z |
| indexdate | 2024-07-09T20:41:34Z |
| institution | BVB |
| isbn | 1860944116 1860944124 9781860944123 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-014897362 |
| oclc_num | 69392440 |
| open_access_boolean | |
| owner | DE-703 DE-91G DE-BY-TUM DE-29T DE-11 DE-83 |
| owner_facet | DE-703 DE-91G DE-BY-TUM DE-29T DE-11 DE-83 |
| physical | XV, 414 S. graph. Darst. |
| publishDate | 2006 |
| publishDateSearch | 2006 |
| publishDateSort | 2006 |
| publisher | Imperial College Press |
| record_format | marc |
| spelling | Stein, Richard S. Verfasser aut Topics in polymer physics Richard S. Stein ; Joseph Powers London Imperial College Press 2006 XV, 414 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Conformatieanalyse gtt Fysische eigenschappen gtt Kristallijn gtt Optische eigenschappen gtt Polymeren gtt Polymères Polymères - Modèles mathématiques Polymérisation Rubber gtt Spectrometrie gtt Statistiek gtt Thermodynamica gtt Mathematisches Modell Statistik Polymerization Polymers Polymers Mathematical models Polymere (DE-588)4046699-1 gnd rswk-swf Physik (DE-588)4045956-1 gnd rswk-swf (DE-588)4006432-3 Bibliografie gnd-content Polymere (DE-588)4046699-1 s Physik (DE-588)4045956-1 s DE-604 Powers, Joseph Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014897362&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Stein, Richard S. Powers, Joseph Topics in polymer physics Conformatieanalyse gtt Fysische eigenschappen gtt Kristallijn gtt Optische eigenschappen gtt Polymeren gtt Polymères Polymères - Modèles mathématiques Polymérisation Rubber gtt Spectrometrie gtt Statistiek gtt Thermodynamica gtt Mathematisches Modell Statistik Polymerization Polymers Polymers Mathematical models Polymere (DE-588)4046699-1 gnd Physik (DE-588)4045956-1 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4045956-1 (DE-588)4006432-3 |
| title | Topics in polymer physics |
| title_auth | Topics in polymer physics |
| title_exact_search | Topics in polymer physics |
| title_exact_search_txtP | Topics in polymer physics |
| title_full | Topics in polymer physics Richard S. Stein ; Joseph Powers |
| title_fullStr | Topics in polymer physics Richard S. Stein ; Joseph Powers |
| title_full_unstemmed | Topics in polymer physics Richard S. Stein ; Joseph Powers |
| title_short | Topics in polymer physics |
| title_sort | topics in polymer physics |
| topic | Conformatieanalyse gtt Fysische eigenschappen gtt Kristallijn gtt Optische eigenschappen gtt Polymeren gtt Polymères Polymères - Modèles mathématiques Polymérisation Rubber gtt Spectrometrie gtt Statistiek gtt Thermodynamica gtt Mathematisches Modell Statistik Polymerization Polymers Polymers Mathematical models Polymere (DE-588)4046699-1 gnd Physik (DE-588)4045956-1 gnd |
| topic_facet | Conformatieanalyse Fysische eigenschappen Kristallijn Optische eigenschappen Polymeren Polymères Polymères - Modèles mathématiques Polymérisation Rubber Spectrometrie Statistiek Thermodynamica Mathematisches Modell Statistik Polymerization Polymers Polymers Mathematical models Polymere Physik Bibliografie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014897362&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT steinrichards topicsinpolymerphysics AT powersjoseph topicsinpolymerphysics |