Xylylene bridged perylene bisimide cyclophanes and macrocycles: = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen
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| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Würzburg
2016
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis kostenfrei Inhaltsverzeichnis |
| Beschreibung: | veröffentlicht 2017 |
| Beschreibung: | xiv, 203 Seiten Illustrationen, Diagramme 30 cm |
Internformat
MARC
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| 100 | 1 | |a Spenst, Peter |d ca. 21. Jh. |e Verfasser |0 (DE-588)1151454168 |4 aut | |
| 245 | 1 | 0 | |a Xylylene bridged perylene bisimide cyclophanes and macrocycles |b = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |c vorgelegt von Peter Spenst aus Saran (Kasachstan) |
| 246 | 1 | 1 | |a Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |
| 264 | 1 | |a Würzburg |c 2016 | |
| 300 | |a xiv, 203 Seiten |b Illustrationen, Diagramme |c 30 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a veröffentlicht 2017 | ||
| 502 | |b Dissertation |c Julius Maximilians-Universität Würzburg |d 2016 | ||
| 546 | |a Zusammenfassung in deutscher und englischer Sprache | ||
| 650 | 0 | 7 | |a Supramolekulare Chemie |0 (DE-588)4306141-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Elektronentransfer |0 (DE-588)4151907-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Perylenderivate |0 (DE-588)4173938-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Wirt-Gast-Beziehung |0 (DE-588)4313441-5 |2 gnd |9 rswk-swf |
| 653 | |a Perylenbisimid | ||
| 653 | |a Energietransfer | ||
| 653 | |a Elektronentransfer | ||
| 653 | |a Perylene Bisimide | ||
| 653 | |a Energy Transfer | ||
| 653 | |a Electron Transfer | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
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| 689 | 0 | 2 | |a Elektronentransfer |0 (DE-588)4151907-3 |D s |
| 689 | 0 | 3 | |a Perylenderivate |0 (DE-588)4173938-3 |D s |
| 689 | 0 | |5 DE-604 | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |o urn:nbn:de:bvb:20-opus-139015 |a Spenst, Peter |t Xylylene Bridged Perylene Bisimide Cyclophanes and Macrocycles |d Würzburg : Universität Würzburg, 2016 |h Online-Ressource |
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Datensatz im Suchindex
| _version_ | 1804178232712364032 |
|---|---|
| adam_text | TABLE OF CONTENTS
CHAPTER 1 - INTRODUCTION AND AIM OF THE THESIS
................................................................
1
CHAPTER 2 - LITERATURE
SURVEY..............................................................................................5
2.1 THE ROLE OF CHROMOPHORES IN THE LIGHT-HARVESTING SYSTEMS
....................................
5
2.2 DEACTIVATION PROCESSES OF PHOTOEXCITED PERYLENE BISIMIDE DYES
............................
12
2.3 PYROMELLITIC BISIMIDE CONTAINING MACROCYCLES
......................................................
14
2.4 COVALENTLY BONDED NAPHTHALENE BISIMIDE MACROCYCLES
.........................................
17
2.5 PERYLENE BISIMIDE CONTAINING
MACROCYCLES............................................................25
2.6 BISIMIDE CONTAINING CATENANES
...............................................................................
33
2.7 BISIMIDE
METALLOMACROCYCLES..................................................................................37
CHAPTER 3 - RESULTS AND
DISCUSSION...................................................................................49
3.1 SYNTHESIS AND
CHARACTERIZATION................................................................................49
3.2 A PBI CYCLOPHANE AS TUM-ON AND TURN-OFF FLUORESCENCE PROBE
...................
54
3.2.1 OPTICAL SPECTROSCOPY AND MOLECULAR MODELLING
...............................................
54
3.2.2 HOST-GUEST
STUDIES............................................................................................56
3.3 GUEST AND SOLVENT MODULATED PHOTO-DRIVEN CHARGE SEPARATION AND
TRIPLET
GENERATION IN A PBI
CYCLOPHANE....................................................................................63
3.3.1 STEADY STATE SPECTROSCOPY AND ELECTROCHEMISTRY
.............................................
64
3.3.2 TRANSIENT ABSORPTION SPECTROSCOPY OF THE FREE HOST 2PBI(4.,
B
U)4
....................
65
3.3.3 TRIPLET FORMATION
MECHANISM................................................ 67
3.3.4 TRANSIENT ABSORPTION SPECTROSCOPY OF THE HOST-GUEST COMPLEXES
.................
68
3.4 SELF-ENCAPSULATION OF SIDE ARMS IN PERYLENE BISIMIDE CYCLOPHANES
..................
72
3.4.1 NMR AND OPTICAL
SPECTROSCOPY........................................................................72
3.4.2 HOST-GUEST
STUDIES............................................................................................77
3.5 GUEST-MEDIATED CHIRALITY
TRANSFER...........................................................................84
3.5.1 UV-VIS ABSORPTION, FLUORESCENCE AND NMR SPECTROSCOPY OF PBI
CYCLOPHANES
.
85
3.5.2 NMR SPECTROSCOPIC STUDIES ON GUEST ENCAPSULATION
.......................................
90
3.5.3 CIRCULAR DICHROISM STUDIES
...............................................................................
92
3.6 COMPLEXATION OF FULLERENE INTO THE CYCLIC
TRIMER..................................................97
3.6.1 OPTICAL SPECTROSCOPY
.........................................................................................
97
3.6.2 TRANSIENT ABSORPTION SPECTROSCOPY
...................................................................
99
3.7 FOLDING OF PERYLENE BISIMIDE
MACROCYCLES............................................................104
3.7.1 STEADY-STATE UV-VIS ABSORPTION AND FLUORESCENCE PROPERTIES
.......................
105
3.7.2 SOLVENT-DEPENDENT FOLDING
PROPERTIES..............................................................110
3.7.3 EXCITED STATE
PROPERTIES....................................................................................115
3.7.4 FEMTOSECOND STIMULATED RAMAN SPECTROSCOPY
...............................................
119
3.8 SELF-ASSEMBLY OF PERYLENE BISIMIDE MACROCYCLES ON HOPG SURFACES
................
122
CHAPTER 4 -
SUMMARY.......................................................................................................127
CHAPTER 5 -
ZUSAMMENFASSUNG.........................................................................................133
CHAPTER 6 - EXPERIMENTAL
SECTION....................................................................................141
6.1 MATERIALS AND
METHODS............................................................................................141
6.2
SYNTHESIS..................................................................................................................144
APPENDIX...........................................................................................................................155
LIST OF
PUBLICATIONS...........................................................................................................183
REFERENCES.........................................................................................................................185
|
| any_adam_object | 1 |
| author | Spenst, Peter ca. 21. Jh |
| author_GND | (DE-588)1151454168 |
| author_facet | Spenst, Peter ca. 21. Jh |
| author_role | aut |
| author_sort | Spenst, Peter ca. 21. Jh |
| author_variant | p s ps |
| building | Verbundindex |
| bvnumber | BV044734320 |
| classification_rvk | VK 5070 |
| collection | ebook |
| ctrlnum | (OCoLC)1017028629 (DE-599)DNB1141942836 |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| id | DE-604.BV044734320 |
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| indexdate | 2024-07-10T08:00:42Z |
| institution | BVB |
| language | English |
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| physical | xiv, 203 Seiten Illustrationen, Diagramme 30 cm |
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| publishDate | 2016 |
| publishDateSearch | 2016 |
| publishDateSort | 2016 |
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| spelling | Spenst, Peter ca. 21. Jh. Verfasser (DE-588)1151454168 aut Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen vorgelegt von Peter Spenst aus Saran (Kasachstan) Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen Würzburg 2016 xiv, 203 Seiten Illustrationen, Diagramme 30 cm txt rdacontent n rdamedia nc rdacarrier veröffentlicht 2017 Dissertation Julius Maximilians-Universität Würzburg 2016 Zusammenfassung in deutscher und englischer Sprache Supramolekulare Chemie (DE-588)4306141-2 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 gnd rswk-swf Perylenderivate (DE-588)4173938-3 gnd rswk-swf Wirt-Gast-Beziehung (DE-588)4313441-5 gnd rswk-swf Perylenbisimid Energietransfer Elektronentransfer Perylene Bisimide Energy Transfer Electron Transfer (DE-588)4113937-9 Hochschulschrift gnd-content Supramolekulare Chemie (DE-588)4306141-2 s Wirt-Gast-Beziehung (DE-588)4313441-5 s Elektronentransfer (DE-588)4151907-3 s Perylenderivate (DE-588)4173938-3 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:20-opus-139015 Spenst, Peter Xylylene Bridged Perylene Bisimide Cyclophanes and Macrocycles Würzburg : Universität Würzburg, 2016 Online-Ressource B:DE-101 application/pdf http://d-nb.info/1141942836/04 Inhaltsverzeichnis https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-139015 Resolving-System kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030130324&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Spenst, Peter ca. 21. Jh Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen Supramolekulare Chemie (DE-588)4306141-2 gnd Elektronentransfer (DE-588)4151907-3 gnd Perylenderivate (DE-588)4173938-3 gnd Wirt-Gast-Beziehung (DE-588)4313441-5 gnd |
| subject_GND | (DE-588)4306141-2 (DE-588)4151907-3 (DE-588)4173938-3 (DE-588)4313441-5 (DE-588)4113937-9 |
| title | Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |
| title_alt | Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |
| title_auth | Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |
| title_exact_search | Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |
| title_full | Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen vorgelegt von Peter Spenst aus Saran (Kasachstan) |
| title_fullStr | Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen vorgelegt von Peter Spenst aus Saran (Kasachstan) |
| title_full_unstemmed | Xylylene bridged perylene bisimide cyclophanes and macrocycles = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen vorgelegt von Peter Spenst aus Saran (Kasachstan) |
| title_short | Xylylene bridged perylene bisimide cyclophanes and macrocycles |
| title_sort | xylylene bridged perylene bisimide cyclophanes and macrocycles xylol verbruckte perylenbisimid cyclophane und makrozyklen |
| title_sub | = Xylol verbrückte Perylenbisimid Cyclophane und Makrozyklen |
| topic | Supramolekulare Chemie (DE-588)4306141-2 gnd Elektronentransfer (DE-588)4151907-3 gnd Perylenderivate (DE-588)4173938-3 gnd Wirt-Gast-Beziehung (DE-588)4313441-5 gnd |
| topic_facet | Supramolekulare Chemie Elektronentransfer Perylenderivate Wirt-Gast-Beziehung Hochschulschrift |
| url | http://d-nb.info/1141942836/04 https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-139015 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=030130324&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT spenstpeter xylylenebridgedperylenebisimidecyclophanesandmacrocyclesxylolverbruckteperylenbisimidcyclophaneundmakrozyklen AT spenstpeter xylolverbruckteperylenbisimidcyclophaneundmakrozyklen |
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