Molecular energetics: condensed-phase thermochemical techniques
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford [u.a.]
Oxford University Press
2008
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | VIII, 296 S. Ill., graph. Darst. |
| ISBN: | 9780195133196 |
Internformat
MARC
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| 100 | 1 | |a Simões, José Arthur Martinho |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Molecular energetics |b condensed-phase thermochemical techniques |c José A. Martinho Simões, Manuel E. Minas da Piedade |
| 264 | 1 | |a Oxford [u.a.] |b Oxford University Press |c 2008 | |
| 300 | |a VIII, 296 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 7 | |a Festkörper - Thermoanalyse |2 idsbb | |
| 650 | 7 | |a Festkörper - Wärmemessung |2 idsbb | |
| 650 | 7 | |a Thermoanalyse - Festkörper |2 idsbb | |
| 650 | 7 | |a Wärmemessung - Festkörper |2 idsbb | |
| 650 | 4 | |a Thermochemistry | |
| 650 | 4 | |a Thermodynamics | |
| 650 | 4 | |a Condensed matter | |
| 650 | 4 | |a Molecular dynamics | |
| 700 | 1 | |a Piedade, Manuel E. Minas da |e Verfasser |4 aut | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016737715&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-016737715 | ||
Datensatz im Suchindex
| _version_ | 1804138016830128129 |
|---|---|
| adam_text | Contents
Part I Introduction
1
Thermochemistry and Molecular Energetics
3
2
The Thermodynamic Background
7
2.1
Units
7
2.2
Nomenclature
7
2.3
Standard States
8
2.4
Enthalpies of Reaction and Standard Enthalpies
of Formation
9
2.5
The Selection of Thermochemical Data and
More on Standard States
1
б
2.6
The Uncertainties in Thermochemical Data
19
2.7
Standard Enthalpies of Phase Transition
22
2.8
Lattice Energy and Ion Solvation Enthalpy
26
2.9
The Gibbs Energy: First and Second Law Methods
31
2.10
The Gibbs Energy: Third Law Method
36
3
The Kinetic Background
38
3.1
Reactions in the Gas Phase
38
3.2
Reactions in Solution
43
4
Gas-Phase Ion Energetics
47
4.1
Ionization Energy and Electron Affinity
47
4.2
Appearance Energy
50
4.3
Proton Affinity, Basicity, and Acidity
55
5
Bond Energies
58
5.1
Bond Dissociation Enthalpies and Energies
58
5.2
Stepwise and Mean Bond Dissociation Enthalpies
64
5.3
Bond Enthalpy Contributions and
Bond Strengths
68
5.4
The Laidler Terms
74
References to Part I
76
VII
viii Contents
Partii
Condensed Phase
Methods
6
Overview of Condensed Phase Methods
83
7
Combustion Calorimetry
87
7.1
Static-Bomb Combustion Calorimetry in Oxygen
87
7.2
Moving-Bomb Combustion Calorimetry
in Oxygen
108
7.3
Flame Combustion Calorimetry in Oxygen
114
7.4
Fluorine Combustion Calorimetry
120
8
Isoperibol Reaction-Solution Calorimetry
125
9
Heat Flow Calorimetry
137
10
Photocalorimetry
147
11 Titration
Calorimetry
156
11.1
Isoperibol Continuous
Titration
Calorimetry
158
11.2
Heat Flow
Titration
Calorimetry
167
12
Differential Scanning Calorimetry (DSC)
171
12.1
Thermodynamic Data from DSC Experiments
175
13
Photoacoustic Calorimetry
190
14
Equilibrium in Solution
207
15
Kinetics in Solution
219
16
Electrochemical Measurements
227
16.1
Electrochemistry and Thermodynamics
229
16.2
Cyclic Voltammetry
231
16.3
Photomodulation
Voltammetry
243
References to Part II
247
Appendix A: Units, Conversion Factors, and
Fundamental Constants
267
Appendix B: Thermochemical Databases
270
Index
283
|
| adam_txt |
Contents
Part I Introduction
1
Thermochemistry and Molecular Energetics
3
2
The Thermodynamic Background
7
2.1
Units
7
2.2
Nomenclature
7
2.3
Standard States
8
2.4
Enthalpies of Reaction and Standard Enthalpies
of Formation
9
2.5
The Selection of Thermochemical Data and
More on Standard States
1
б
2.6
The Uncertainties in Thermochemical Data
19
2.7
Standard Enthalpies of Phase Transition
22
2.8
Lattice Energy and Ion Solvation Enthalpy
26
2.9
The Gibbs Energy: First and Second Law Methods
31
2.10
The Gibbs Energy: Third Law Method
36
3
The Kinetic Background
38
3.1
Reactions in the Gas Phase
38
3.2
Reactions in Solution
43
4
Gas-Phase Ion Energetics
47
4.1
Ionization Energy and Electron Affinity
47
4.2
Appearance Energy
50
4.3
Proton Affinity, Basicity, and Acidity
55
5
Bond Energies
58
5.1
Bond Dissociation Enthalpies and Energies
58
5.2
Stepwise and Mean Bond Dissociation Enthalpies
64
5.3
Bond Enthalpy Contributions and
Bond Strengths
68
5.4
The Laidler Terms
74
References to Part I
76
VII
viii Contents
Partii
Condensed Phase
Methods
6
Overview of Condensed Phase Methods
83
7
Combustion Calorimetry
87
7.1
Static-Bomb Combustion Calorimetry in Oxygen
87
7.2
Moving-Bomb Combustion Calorimetry
in Oxygen
108
7.3
Flame Combustion Calorimetry in Oxygen
114
7.4
Fluorine Combustion Calorimetry
120
8
Isoperibol Reaction-Solution Calorimetry
125
9
Heat Flow Calorimetry
137
10
Photocalorimetry
147
11 Titration
Calorimetry
156
11.1
Isoperibol Continuous
Titration
Calorimetry
158
11.2
Heat Flow
Titration
Calorimetry
167
12
Differential Scanning Calorimetry (DSC)
171
12.1
Thermodynamic Data from DSC Experiments
175
13
Photoacoustic Calorimetry
190
14
Equilibrium in Solution
207
15
Kinetics in Solution
219
16
Electrochemical Measurements
227
16.1
Electrochemistry and Thermodynamics
229
16.2
Cyclic Voltammetry
231
16.3
Photomodulation
Voltammetry
243
References to Part II
247
Appendix A: Units, Conversion Factors, and
Fundamental Constants
267
Appendix B: Thermochemical Databases
270
Index
283 |
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| isbn | 9780195133196 |
| language | English |
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| spelling | Simões, José Arthur Martinho Verfasser aut Molecular energetics condensed-phase thermochemical techniques José A. Martinho Simões, Manuel E. Minas da Piedade Oxford [u.a.] Oxford University Press 2008 VIII, 296 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Festkörper - Thermoanalyse idsbb Festkörper - Wärmemessung idsbb Thermoanalyse - Festkörper idsbb Wärmemessung - Festkörper idsbb Thermochemistry Thermodynamics Condensed matter Molecular dynamics Piedade, Manuel E. Minas da Verfasser aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016737715&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Simões, José Arthur Martinho Piedade, Manuel E. Minas da Molecular energetics condensed-phase thermochemical techniques Festkörper - Thermoanalyse idsbb Festkörper - Wärmemessung idsbb Thermoanalyse - Festkörper idsbb Wärmemessung - Festkörper idsbb Thermochemistry Thermodynamics Condensed matter Molecular dynamics |
| title | Molecular energetics condensed-phase thermochemical techniques |
| title_auth | Molecular energetics condensed-phase thermochemical techniques |
| title_exact_search | Molecular energetics condensed-phase thermochemical techniques |
| title_exact_search_txtP | Molecular energetics condensed-phase thermochemical techniques |
| title_full | Molecular energetics condensed-phase thermochemical techniques José A. Martinho Simões, Manuel E. Minas da Piedade |
| title_fullStr | Molecular energetics condensed-phase thermochemical techniques José A. Martinho Simões, Manuel E. Minas da Piedade |
| title_full_unstemmed | Molecular energetics condensed-phase thermochemical techniques José A. Martinho Simões, Manuel E. Minas da Piedade |
| title_short | Molecular energetics |
| title_sort | molecular energetics condensed phase thermochemical techniques |
| title_sub | condensed-phase thermochemical techniques |
| topic | Festkörper - Thermoanalyse idsbb Festkörper - Wärmemessung idsbb Thermoanalyse - Festkörper idsbb Wärmemessung - Festkörper idsbb Thermochemistry Thermodynamics Condensed matter Molecular dynamics |
| topic_facet | Festkörper - Thermoanalyse Festkörper - Wärmemessung Thermoanalyse - Festkörper Wärmemessung - Festkörper Thermochemistry Thermodynamics Condensed matter Molecular dynamics |
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