Organometallic chemistry of the transition elements:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English Polish |
| Veröffentlicht: |
New York u.a.
Plenum Press
1990
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| Schriftenreihe: | Modern inorganic chemistry
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Aus dem Poln. übers. - Literaturangaben |
| Beschreibung: | XVI, 757 S. |
| ISBN: | 0306431920 |
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| 100 | 1 | |a Pruchnik, Florian P. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Organometallic chemistry of the transition elements |c Florian P. Pruchnik |
| 264 | 1 | |a New York u.a. |b Plenum Press |c 1990 | |
| 300 | |a XVI, 757 S. | ||
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| 490 | 0 | |a Modern inorganic chemistry | |
| 500 | |a Aus dem Poln. übers. - Literaturangaben | ||
| 650 | 4 | |a Organotransition metal compounds | |
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Datensatz im Suchindex
| _version_ | 1804118377661202432 |
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| adam_text | ORGANOMETALLIC CHEMISTRY OF THE TRANSITION ELEMENTS FLORIAN P. PRUCHNIK
UNIVERSITY OF WROCLAW WROCLAW, POLAND TRANSLATED FROM POLISH BY STAN A.
DURAJ CLEVEIAND STATE UNIVERSITY CLEVELAND, OHIO PLENUM PRESS * NEW YORK
AND LONDON CONTENTS CHAPTER 1. INTRODUCTION TO ORGANOMETALLIC CHEMISTRY
1. NUMBER OF VALENCE ELECTRONS. CHARACTERISTICS OF LIGANDS 1 2. THE MAIN
GROUP ELEMENTS 7 3. THE TRANSITION METALS 11 4. ELEMENTARY REACTIONS OF
ORGANOMETALLIC COMPOUNDS 15 5. NOMENCLATURE OF ORGANOMETALLIC COMPOUNDS
15 REFERENCES 20 CHAPTER 2. METAL CARBONYLS 1. PREPARATION OF METAL
CARBONYLS .^ 23 2. BONDING IN METAL CARBONYLS 24 3. IR SPECTRA OF METAL
CARBONYLS 32 4. ELECTRONIC SPECTRA 41 5. 13 C NMR SPECTRA 45 6.
PHOTOELECTRON SPECTROSCOPY 49 7. MASS SPECTROMETRY 53 8. PROPERTIES OF
METAL CARBONYLS 55 A. GROUP 3 METAL CARBONYLS 60 B. GROUP 4 METAL
CARBONYLS 63 C. GROUP 5 METAL CARBONYLS 64 D. GROUP 6 METAL CARBONYLS 69
E. GROUP 7 METAL CARBONYLS 75 F. GROUP 8 METAL CARBONYLS 79 G. GROUP 9
METAL CARBONYLS 85 CLUSTER COMPOUNDS OF CO, RH, AND IR 89 H. GROUP 10
METAL CARBONYLS 92 METAL CARBONYL HALIDES OF GROUP 10 METALS 94 I. GROUP
11 METAL CARBONYLS 95 9. METAL CARBONYL HYDRIDES 96 A. BONDING 96 B.
METHODS OF IDENTIFICATION 97 C. PREPARATION OF HYDRIDO COMPLEXES 104 VII
VIII CONTENTS D. ACIDIC PROPERTIES OF METAL CARBONYL HYDRIDES 107 E.
LIGAND FIELD STRENGTH AND TRANS EFFECT OF THE HYDRIDO LIGAND 107 F.
STRUCTURES OF HYDRIDO COMPLEXES 107 G. PROPERTIES OF METAL CARBONYL
HYDRIDES 108 10. METAL CARBONYLS CONTAINING BRIDGING CO GROUPS BONDED
THROUGH C AND O 110 11. THIOCARBONYL AND SELENOCARBONYL COMPLEXES 112 A.
STRUCTURE, BONDING, AND SPECTROSCOPY 112 B. PREPARATION OF THIOCARBONYL
AND SELENOCARBONYL COMPLEXES 115 C. REACTIONS OF THIOCARBONYL COMPLEXES
116 12. APPLICATIONS OF METAL CARBONYL COMPLEXES 119 13. APPLICATIONS OF
ORGANOMETALLIC COMPOUNDS FOR PREPARATION OF METALS, OXIDES, CARBIDES,
AND NITRIDES, AND FOR DEPOSITION OF METAL LAYERS AND THEIR COMPOUNDS 119
14. METAL CARBONYL COMPLEXES POSSESSING COLUMN STRUCTURES 121 REFERENCES
122 CHAPTER 3. METAL-METAL BONDS AND CLUSTERS 1. BONDING AND STRUCTURE
129 A. THEORY OF SKELETAL ELECTRON PAIRS 133 B. THE ISOLOBAL ANALOGY-OF
FRAGMENTS 141 C. TOPOLOGICAL CALCULATIONS OF CVMO 147 D. REACTIONS
BETWEEN CLUSTERS 149 E. MOLECULAR ORBITAL THEORY 150 2. CLUSTERS AS
MODELS OF METALLIC LATTICES OF CATALYSTS 155 3. INTERSTITIAL
(ENCAPSULATED) CLUSTERS 157 4. ELECTRON POOR TRANSITION METAL CLUSTERS
160 5. NMR SPECTRA OF CLUSTERS 163 6. IR SPECTRA 165 7. THE M * M BOND
ENERGY IN CLUSTERS 166 8. SYNTHESIS OF METAL CLUSTERS 166 9. PROPERTIES
OF CLUSTERS 169 A. GROUP 4 169 B. GROUP 5 170 C. GROUP 6 170 D. GROUP 7
171 E. GROUP 8 172 F. GROUP 9 174 G. GROUP 10 175 H. GROUP 11 177 10.
REACTIONS OF CLUSTERS 179 A. REACTIONS LEADING TO STRUCTURAL CHANGES IN
CLUSTERS 180 B. MIGRATION OF LIGANDS WITHIN CLUSTERS 183 C. ACID-BASE
REACTIONS 187 D. LIGAND SUBSTITUTION 190 E. OXIDATIVE ADDITION 190
REFERENCES 193 CONTENTS IX CHAPTER 4. COMPOUNDS CONTAINING LE
CARHON-DONOR LIGANDS 1. BONDING IN COMPOUNDS WITH METAL-CARBON A BONDS
200 2. STABILITY OF COMPOUNDS CONTAINING LE LIGANDS 201 3. STRUCTURE OF
COMPOUNDS CONTAINING METAL-CARBON A BONDS 208 4. IR AND RAMAN SPECTRA
212 5. NMR SPECTRA 213 6. ESR SPECTRA 215 7. PHOTOELECTRON SPECTRA 215
8. MAGNETIC PROPERTIES 217 9. ELECTRONIC SPECTRA 218 10. PREPARATION OF
COMPLEXES CONTAINING A BONDED CARBON LIGANDS 219 A. REACTIONS OF
TRANSITION METAL COMPOUNDS WITH ALKYLATING OR ARYLATING REAGENTS 219 B.
REACTIONS INVOLVING OXIDATIVE ADDITION OF ORGANIC HALIDES 220 C.
MIGRATION (INSERTION) REACTIONS 222 D. REACTIONS OF ANIONIC COMPLEXES
WITH ORGANIC HALIDES 224 E. ELIMINATION OF NEUTRAL GROUP CONNECTING
CARBON WITH METAL (DEINSERTION) 224 F. PREPARATION OF ACETYLIDE
COMPLEXES 225 G. PHOTOCHEMICAL SYNTHESIS 225 H. ELECTROCHEMICAL
SYNTHESIS 226 11. PROPERTIES OF COMPLEXES CONTAINING METAL-CARBON A
BONDS 227 A. COMPLEXES OF GROUP 3 METALS 227 B. COMPLEXES OF GROUP 4
METALS 229 C. COMPLEXES OF GROUP 5 METALS 232 D. COMPLEXES OF GROUP 6
METALS 232 E. COMPLEXES OF GROUP 7 METALS 234 F. COMPLEXES OF GROUP 8
METALS 238 G. COMPLEXES OF GROUP 9 METALS 242 H. COMPLEXES OF GROUP 10
METALS 244 I. COMPLEXES OF GROUP 11 METALS 249 12. REACTIONS OF
COMPLEXES CONTAINING METAL-CARBON A BONDS 253 A. THE BREAKING OF THE
METAL-CARBON BOND ^ 253 B. MIGRATION (INSERTION) REACTIONS 255 C.
OXIDATIVE ADDITION REACTIONS 260 D. THE O-N REARRANGEMENT OF COMPLEXES
CONTAINING A METAL-CARBON BONDS 261 13. ACTIVATION OF HYDROCARBONS 262
REFERENCES 269 CHAPTER 5. CARBENE AND CARBYNE COMPLEXES 1. BONDING 277
2. STRUCTURES OF CARBENE AND CARBYNE COMPLEXES 281 3. IR SPECTRA 285 4.
NMR SPECTRA 285 5. PHOTOELECTRON SPECTRA 287 6. ELECTRONIC SPECTRA 290
7. ESR AND MAGNETIC PROPERTIES 291 X CONTENTS 8. METHODS OF PREPARATION
OF CARBENE COMPLEXES 292 A. FROM METAL CARBONYLS 292 B. NUCLEOPHILIC
ADDITION TO ISOCYANIDE LIGANDS 292 C. HYDROGEN ATOM ABSTRACTION FROM A
BONDED CARBON LIGANDS 294 D. ALKYLATION OF COMPLEXES WITH SOME M*CA
BONDS 295 E. ELECTROPHILIC ADDITION TO COORDINATED LIGANDS 295 F.
REACTIONS OF COMPLEXES WITH MIXTURES OF ACETYLENES AND ALCOHOLS 295 G.
SYNTHESIS FROM IONIC COMPLEXES 295 H. OXIDATIVE ADDITION REACTIONS 296
I. REACTIONS OF COMPLEXES WITH NEUTRAL CARBENE PRECURSORS 297 J.
NUCLEOPHILIC ADDITION TO CARBYNE COMPLEXES 298 K. OXIDATION REACTIONS
298 1. ADDITION TO CARBONYL LIGANDS 298 M. SYNTHESIS OF /I-METHYLENE
COMPLEXES 299 9. METHODS OF PREPARATION OF CARBYNE COMPLEXES 300 A.
REMOVAF OF ALKOXY, ALKYLTHIO, AND AMINO GROUPS FROM THE CARBENE LIGAND
300 B. HYDROGEN ELIMINATION FROM THE CARBENE LIGAND 300 C. CLEAVAGE OF C
= C BONDS IN ACETYLENES AND CSN BONDS IN CYANIDES 300 D. REACTIONS OF
CARBYNE COMPLEXES WITH ANIONIC TRANSITION METAL COMPLEXES 301 E.
SPONTANEOUS CARBENE LIGAND REARRANGEMENT 301 F. REACTIONS OF ACYL
COMPLEXES WITH DIBROMOTRIPHENYL PHOSPHORUS(V) 301 G. OXYGEN ABSTRACTION
FROM ACYL LIGANDS 306 H. PROTONATION OF ISOCYANIDE LIGANDS 306 I.
MISCELLANEOUS METHODS OF SYNTHESIS OF CARBYNE COMPLEXES 306 10.
PROPERTIES OF CARBENE AND CARBYNE COMPLEXES 307 11. REACTIONS OF CARBENE
COMPLEXES 308 A. NUCLEOPHILIC SUBSTITUTION REACTIONS 308 B.
REARRANGEMENT REACTIONS CAUSED BY ADDITION 311 C. HYDROGEN SUBSTITUTION
AT A * C 312 D. REDUCTION OF CARBENE COMPLEXES 312 E. OXIDATION
REACTIONS 313 F. REACTIONS WITH ELECTROPHILES 314 G. SUBSTITUTION
REACTIONS OF NONCARBENE LIGANDS 314 H. RELEASE OF CARBENE LIGANDS 315 I.
MIGRATION REACTIONS 317 12. REACTION OF CARBYNE COMPLEXES 317 A.
REACTIONS WITH NUCLEOPHILES 317 B. REACTIONS LEADING TO BRIDGING CARBYNE
COMPLEXES 318 C. REACTIONS OF CARBYNE COMPLEXES WITH CO AND CO Z 318 D.
REMOVAL OF CARBYNE LIGANDS 319 E. EXCHANGE REACTIONS INVOLVING
NONCARBYNE LIGANDS 320 F. REACTIONS WITH ACIDS 320 G. MISCELLANEOUS
REACTIONS 320 13. REACTIONS OF COMPLEXES CONTAINING METHYLENE BRIDGES
320 14. APPLICATIONS OF CARBENE AND CARBYNE COMPLEXES 322 REFERENCES 324
CONTENTS XI CHAPTER 6. COMPOUNDS CONTAINING TWO-ELECTRON N-LIGANDS A.
OLEFIN COMPLEXES 1. BONDING AND STRUCTURE 327 2. IR SPECTRA OF OLEFIN
COMPLEXES 333 3. H NMR SPECTRA 335 4. 13 C NMR SPECTRA 337 5.
PHOTOELECTRON SPECTRA 339 6. ELECTRONIC SPECTRA 341 7. STABILITY OF
OLEFIN COMPLEXES 343 8. METHODS OF SYNTHESIS OF OLEFIN COMPOUNDS 347 A.
OLEFIN ADDITION TO THE TRANSITION METAL SALTS 347 B. ADDITION OF OLEFINS
TO COORDINATION COMPOUNDS OF THE TRANSITION METALS 347 C. SUBSTITUTION
OF COORDINATED LIGANDS WITH OLEFINS 347 D. REDUCTION IN THE PRESENCE OF
OLEFINS 349 E. PREPARATION OF OLEFIN COMPLEXES FROM HYDROCARBON LIGANDS
COORDINATED TO THE METAL 350 F. EXCHANGE REACTIONS 350 G. DEHYDRATION OF
ALCOHOLS 351 H. ELECTROCHEMICAL SYNTHESES 351 9. PROPERTIES OF
TRANSITION METAL OLEFIN COMPLEXES 351 A. GROUP 4 METAL COMPLEXES 352 B.
GROUP 5 METAL COMPLEXES 352 C. GROUP 6 METAL COMPLEXES 353 D. GROUP 7
METAL COMPLEXES 356 E. GROUP 8 METAL COMPLEXES 358 F. GROUP 9 METAL
COMPLEXES 361 G. GROUP 10 METAL COMPLEXES 368 H. GROUP 11 METAL
COMPLEXES 377 10. COMPLEXES CONTAINING HETEROOLEFINS 379 11.
APPLICATIONS OF RC-OLEFIN COMPLEXES 381 A. REACTIONS OF OLEFIN COMPLEXES
WITH NUCLEOPHILES 381 B. REACTIONS OF OLEFIN COMPLEXES WITH
ELECTROPHILES 384 C. AMINATION OF OLEFINS 386 D. OLEFIN EXCHANGE
REACTIONS 386 E. SUBSTITUTION OF OLEFIN LIGANDS 386 F. TRANSFORMATION OF
OLEFIN COMPLEXES INTO VINYL COMPOUNDS 386 G. HYDROGEN/DEUTERIUM EXCHANGE
IN OLEFIN COMPOUNDS 387 H. PHOTOCHEMICAL REACTIONS 388 B. ACETYLENE
COMPLEXES 1. BONDING AND STRUCTURE 389 2. IR SPECTRA 392 3. NMR SPECTRA
394 4. METHODS OF PREPARATION OF ACETYLENE COMPLEXES 396 A. ALKYNE
ADDITION TO THE TRANSITION METAL SALTS AND COMPLEXES 396 B. LIGAND
SUBSTITUTION IN COORDINATION COMPOUNDS 397 5. PROPERTIES OF ACETYLENE
COMPLEXES 398 6. REACTIONS OF ACETYLENE COMPLEXES 404 7.
METALLACYCLIZATION REACTIONS 409 XII CONTENTS 8. COMPLEXES CONTAINING R
*CSY AND R-YSC LIGANDS 412 C. ALLENE COMPLEXES 1. BONDING AND STRUCTURE
415 2. IR AND NMR SPECTRA. REACTIONS OF ALLENE COMPLEXES 417 REFERENCES
421 CHAPTER 7. COMPLEXES CONTAINING THREE-ELECTRON N-LIGANDS 1. THE
METAL-ALLYL BOND 427 2. IR SPECTRA OF AUYL COMPLEXES 431 3. NMR SPECTRA
432 4. ELECTRONIC SPECTRA 439 5. STRUCTURAL PROPERTIES 441 6.
PHOTOELECTRON SPECTRA 441 7. METHODS OF PREPARATION OF RC-AHYL COMPLEXES
444 A. REACTIONS OF TRANSITION METAL COMPLEXES WITH AUYL COMPOUNDS OF
MAIN GROUP METALS 444 B. REACTIONS OF AUYL HALIDES WITH TRANSITION METAL
COMPLEXES IN THE PRESENCE OF REDUCING AGENTS 444 C. OXIDATIVE ADDITION
OF AUYL HALIDES 445 D. REACTIONS OF OLEFINS WITH METAL COMPLEXES 445 E.
REACTIONS OF 1,3-DIENES WITH METAL COMPOUNDS 446 F. REARRANGEMENTS OF
A-ALLYL COMPOUNDS TO TT-AUYL COMPOUNDS 447 G. SYNTHESIS OF METAL
COMPLEXES CONTAINING CHELATED AUYL LIGANDS 447 H. MISCELLANEOUS METHODS
448 8. PROPERTIES OF 7T-AUYL METAL COMPOUNDS 450 A. COMPLEXES OF GROUP 4
METALS 450 B. COMPLEXES OF GROUP 5 METALS 451 C. COMPLEXES OF GROUP 6
METALS 451 D. COMPLEXES OF GROUP 7 METALS 453 E. COMPLEXES OF GROUP 8
METALS 454 F. COMPLEXES OF GROUP 9 METALS 458 G. COMPLEXES OF GROUP 10
METALS 459 H. COMPLEXES OF GROUP 3 METALS 460 9. CYCLOPROPENYL COMPLEXES
461 10. HETEROALLYL COMPLEXES : 462 11. REACTIONS OF AUYL COMPLEXES 463
A. THERMAL DECOMPOSITION 463 B. INTERACTIONS WITH NUCLEOPHILIC REAGENTS;
OXIDATIVE HYDROLYSIS 464 C. ELECTROPHILIC ATTACK ON AUYL GROUPS 466 D.
FORMATION OF A-AUYL COMPLEXES 466 E. REDUCTION 466 F. REDUCTIVE
ELIMINATION 467 G. MIGRATION (INSERTION) REACTIONS OF LIGANDS 467
REFERENCES 468 CHAPTER 8. COMPOUNDS CONTAINING FOUR-ELECTRON N-LIGANDS
1. THE BONDING 471 2. STRUCTURE OF COMPOUNDS WITH 4E LIGANDS 476
CONTENTS XM 3. NMR SPECTRA 480 4. PHOTOELECTRON SPECTRA 485 5. IR
SPECTRA ( 485 6. METHODS OF PREPARATION OF 1,3-DIENE COMPLEXES 485 A.
REACTION OF COORDINATION COMPOUNDS WITH DIENES 485 B. REACTIONS
INVOLVING NUCLEOPHILIC ATTACK ON DIENE COMPLEXES 488 7. METHODS OF
PREPARATION OF CYCLOBUTADIENE COMPLEXES 489 8. METHODS OF PREPARATION OF
TRIMETHYLENEMETHANE COMPLEXES 496 9. REACTIONS OF 1,3-DIENE COMPLEXES
498 10. REACTIONS OF CYCLOBUTADIENE COMPLEXES 500 A. THERMAL
DECOMPOSITION 500 B. LIGAND SUBSTITUTION REACTIONS 500 C. REACTIONS
INVOLVING THE CYCLOBUTADIENE LIGAND 501 NUCLEOPHILIC ATTACK 501
ELECTROPHILIC ATTACK 502 D. OXIDATION REACTIONS 502 E. REDUCTION
REACTIONS 503 11. REACTIONS OF TRIMETHYLENEMETHANE COMPLEXES 504 12.
PROPERTIES OF DIENE COMPLEXES 504 REFERENCES 505 CHAPTER 9. COMPOUNDS
CONTAINING FIVE-ELECTRON N-LIGANDS 1. THE METAL-CYCLOPENTADIENYL BOND
510 2. STRUCTURE OF CYCLOPENTADIENYL COMPLEXES 518 3. NMR SPECTRA 520 4.
IR SPECTRA 522 5. MAGNETIC PROPERTIES 524 6. EPR SPECTRA 525 7.
ELECTRONIC SPECTRA 525 8. PHOTOELECTRON SPECTRA 527 9. THERMOCHEMISTRY
OF CYCLOPENTADIENYL COMPLEXES 528 10. MASS SPECTRA 529 11. METHODS OF
PREPARATION OF CYCLOPENTADIENYL COMPLEXES 530 A. REACTIONS UTILIZING
CYCLOPENTADIENE IN THE PRESENCE OF BASES OR CYCLOPENTADIENYL COMPOUNDS
OF THE MAIN GROUP ELEMENTS 530 B. SYNTHESES UTILIZING FULVENES 531 C.
REACTIONS OF TRANSITION METAL COMPOUNDS WITH UNSATURATED HYDROCARBONS
532 D. SYNTHESES UTILIZING CYCLOPENTADIENE 533 E. REACTIONS OF DIENES
WITH METAL VAPORS 533 F. PREPARATION OF TRIPLE-DECKER CYCLOPENTADIENYL
COMPLEXES 534 G. PREPARATION OF COMPOUNDS CONTAINING BRIDGING
CYCLOPENTADIENYL LIGANDS 536 H. SYNTHESIS OF TRINUCLEAR M *P(0)(OR) 2
-CYCLOPENTADIENYL COMPLEXES 536 I. ELECTROCHEMICAL SYNTHESIS 537^ J.
SYNTHESIS OF DIENYL COMPLEXES 537 12. PROPERTIES OF CYCLOPENTADIENYL
COMPLEXES 538 A. GROUP 4 METAL COMPLEXES 538 B. GROUP 5 METAL COMPLEXES
541 XIV CONTENTS C. GROUP 6 METAL COMPLEXES 543 D. GROUP 7 METAL
COMPLEXES 545 E. GROUP 8 METAL COMPLEXES 545 F. GROUP 9 METAL COMPLEXES
548 G. GROUP 10 METAL COMPLEXES 550 H. GROUP 11 METAL COMPLEXES 551 I.
GROUP 3 METAL COMPLEXES INCLUDING COMPOUNDS OF THE LANTHANIDES AND THE
ACTINIDES 551 13. POLYNUCLEAR AND CLUSTER CYCLOPENTADIENYL COMPLEXES 554
14. PENTADIENYL COMPLEXES 554 15. PYRROLE COMPLEXES 555 16. MULTIDECKER
COMPLEXES 556 17. REACTIONS OF CYCLOPENTADIENYL COMPOUNDS 557 A.
OXIDATION OF METALLOCENES AND ELECTRON TRANSFER REACTIONS 557 B.
REDUCTION OF CYCLOPENTADIENYL COMPLEXES 558 C. PROTONATION 559 D. THE
M-CP BOND RUPTURE 559 E. METALLATION REACTIONS 561 F. AROMATIC
SUBSTITUTION REACTIONS 563 G. PREPARATION OF POLYMETALLOCENES 564 H.
LIGAND SUBSTITUTION REACTIONS 564 I. REACTIONS WITH SUBSTITUENTS
CONTAINING VARIOUS FUNCTIONAL GROUPS 564 J. ACTIVATION OF C * H BONDS
565 K. PHOTOCHEMISTRY OF CYCLOPENTADIENYL COMPLEXES 565 18. APPLICATION
OF CYCLOPENTADIENYL COMPLEXES 565 REFERENCES 569 CHAPTER 10. COMPLEXES
CONTAINING SIX-ELECTRON N-LIGANDS 1. THE BONDING 575 2. ELECTRONIC
SPECTRA OF ARENE COMPLEXES 578 3. MAGNETIC PROPERTIES 578 4. IR SPECTRA
579 5. NMR SPECTRA 579 6. PHOTOELECTRON SPECTRA 580 7. ESR SPECTRA 582
8. STRUCTURE OF ARENE COMPLEXES 583 9. THERMOCHEMISTRY OF ARENE
COMPLEXES 584 10. MASS SPECTRA 585 11. PROPERTIES OF ARENE COMPOUNDS 586
12. ASYMMETRIE ARENE COMPLEXES 588 13. TRIPLE LAYER AND HETEROARENE
COMPLEXES 588 14. METHODS OF PREPARATION OF ARENE COMPLEXES 590 A.
REACTIONS OF TRANSITION METAL COMPOUNDS WITH ALUMINUM AND ALUMINUM
CHLORIDE 590 B. REACTIONS OF SALTS OF METALS WITH GRIGNARD COMPOUNDS 590
C. CYCLOTRIMERIZATION OF ACETYLENES 591 D. DEHYDROGENATION OF
1,3-CYCLOHEXADIENE 592 E. SUBSTITUTION OF LIGANDS 592 CONTENTS XV F.
REACTIONS INVOLVING REARRANGEMENT OF LIGANDS 593 G. CONDENSATION OF
METAL VAPORS WITH LIGANDS 594 H. MISCELLANEOUS REACTIONS 594 15.
REACTIONS OF ARENE COMPLEXES 594 A. REDOX REACTIONS 594 B. ELECTROPHILIC
SUBSTITUTION REACTIONS 596 C. NUCLEOPHILIC SUBSTITUTION AND ADDITION
REACTIONS 596 D. DISPLACEMENT OF LIGANDS 598 16. APPLICATION OF ARENE
COMPLEXES 599 REFERENCES 600 CHAPTER 11. COMPLEXES CONTAINING SEVEN- AND
EIGHT-ELECTRON N-LIGANDS 1. BONDING, STRUCTURE, SPECTROSCOPY, AND
MAGNETIC PROPERTIES 603 2. PROPERTIES OF CYCLOHEPTATRIENYL AND
CYCLOOCTATETRAENE COMPLEXES 607 3. METHODS OF PREPARATION OF
CYCLOHEPTATRIENYL AND CYCLOOCTATETRAENE COMPLEXES 609 4. REACTIONS OF
CYCLOHEPTATRIENYL AND CYCLOOCTATETRAENE COMPLEXES 611 A. REACTIONS WITH
NUCLEOPHILES 611 B. OXIDATION AND REDUCTION REACTIONS 613 C. LIGAND
EXCHANGE REACTIONS IN COMPLEXES CONTAINING CHT 614 D. THE M-C*H* BOND
BREAKING . 614 E. METALLATION REACTIONS 615 REFERENCES 616 CHAPTER 12.
ISOCYANIDE COMPLEXES 1. BONDING AND STRUCTURE 617 2. ELECTRONIC SPECTRA
620 3. NMR SPECTRA 621 4. IR SPECTRA 622 5. ESR SPECTRA AND MAGNETIC
PROPERTIES 624 6. ULTRAVIOLET AND X-RAY PHOTOELECTRON SPECTRA 624 7.
PROPERTIES OF ISOCYANIDE COMPLEXES 624 A. GROUP 3 METAL COMPLEXES 624 B.
GROUP 4 METAL COMPLEXES 625 C. GROUP 5 METAL COMPLEXES 626 D. GROUP 6
METAL COMPLEXES 626 E. GROUP 7 METAL COMPLEXES 626 F. GROUP 8 METAL
COMPLEXES 627 G. GROUP 9 METAL COMPLEXES 627 H. GROUP 10 METAL COMPLEXES
628 I. GROUP 11 METAL COMPLEXES 629 8. METHODS OF SYNTHESIS OF
ISOCYANIDE COMPLEXES 629 A. PREPARATIONS INVOLVING METAL CYANIDES AND
CYANIDE METAL COMPLEXES.... 629 B. REACTIONS OF ISOCYANIDES WITH
TRANSITION METAL COMPOUNDS 631 C. OXIDATION AND REDUCTION REACTIONS 632
9. REACTIONS OF ISOCYANIDE COMPLEXES 632 A. CLEAVAGE OF THE M-CNR BOND
632 / XVI CONTENTS B. OXIDATION-REDUCTION REACTIONS 633 C. OXIDATIVE
ADDITION REACTIONS 634 D. NUCLEOPHILIC ADDITION 634 E. FORMATION OF
METAL CARBYNE COMPLEXES 635 F. INSERTION REACTIONS . 636 G. DIMERIZATION
OF ISOCYANIDES 639 10. APPLICATIONS OF ISOCYANIDE COMPLEXES 640
REFERENCES 641 CHAPTER 13. APPLICATION OF ORGANOMETALLIC COMPOUNDS IN
HOMOGENEOUS CATALYSIS 1. BASIC PRINCIPLES 647 A. MIGRATION REACTIONS 652
B. OXIDATIVE COUPLING REACTIONS 654 C. OXIDATIVE ADDITION REACTIONS 654
2. HYDROGENATION 655 A. OLEFIN HYDROGENATION 655 B. HYDROGENATION OF
AROMATIC COMPOUNDS 662 C. ASYMMETRIE HYDROGENATION 662 D. HYDROGENATION
OF THE C = 0, C = N, AND C = N BONDS 667 3. ISOMERIZATION OF OLEFINS 670
A. MIGRATION OF THE DOUBLE BOND 670 B. CIS-TRANS ISOMERIZATION 673 4.
OLIGOMERIZATION AND POLYMERIZATION OF OLEFINS AND ACETYLENES 674 A.
POLYMERIZATION 674 B. OLIGOMERIZATION 680 5. CARBONYLATION REACTIONS 690
A. HYDROFORMYLATION REACTIONS 690 B. CARBONYLATION REACTIONS 694 C. THE
STABILITY OF PHOSPHINE-CONTAINING CATALYSTS FOR HYDROFORMYLATION ....
701 6. HYDROCYANATION 702 7. HYDROSILATION 703 8. METATHESIS 704 A.
OLEFIN METATHESIS 704 B. MECHANISM OF THE METATHESIS REACTION 707 C.
METATHESIS OF FUNCTIONALIZED OLEFINS 713 D. METATHESIS OF ALKYNES 713 9.
DISPROPORTIONATION REACTIONS 713 10. REDUCTION OF CARBON MONOXIDE; THE
FISCHER-TROPSCH SYNTHESIS 714 A. MECHANISM OF THE FISCHER-TROPSCH
REACTION 716 11. REACTIONS OF CARBON DIOXIDE 725 12. WATER-GAS SHIFT
REACTION 729 13. AMINATION AND AMOXIDATION REACTIONS 731 14.
HETEROGENIZED HOMOGENEOUS CATALYSTS 732 REFERENCES 736 ABBREVIATIONS 745
INDEX 749
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| any_adam_object | 1 |
| author | Pruchnik, Florian P. |
| author_facet | Pruchnik, Florian P. |
| author_role | aut |
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| discipline | Chemie / Pharmazie Chemie |
| format | Book |
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| id | DE-604.BV004166483 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:09:20Z |
| institution | BVB |
| isbn | 0306431920 |
| language | English Polish |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002598139 |
| oclc_num | 20826518 |
| open_access_boolean | |
| owner | DE-12 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-355 DE-BY-UBR DE-703 |
| owner_facet | DE-12 DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-355 DE-BY-UBR DE-703 |
| physical | XVI, 757 S. |
| publishDate | 1990 |
| publishDateSearch | 1990 |
| publishDateSort | 1990 |
| publisher | Plenum Press |
| record_format | marc |
| series2 | Modern inorganic chemistry |
| spelling | Pruchnik, Florian P. Verfasser aut Organometallic chemistry of the transition elements Florian P. Pruchnik New York u.a. Plenum Press 1990 XVI, 757 S. txt rdacontent n rdamedia nc rdacarrier Modern inorganic chemistry Aus dem Poln. übers. - Literaturangaben Organotransition metal compounds Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002598139&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pruchnik, Florian P. Organometallic chemistry of the transition elements Organotransition metal compounds Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4131837-7 |
| title | Organometallic chemistry of the transition elements |
| title_auth | Organometallic chemistry of the transition elements |
| title_exact_search | Organometallic chemistry of the transition elements |
| title_full | Organometallic chemistry of the transition elements Florian P. Pruchnik |
| title_fullStr | Organometallic chemistry of the transition elements Florian P. Pruchnik |
| title_full_unstemmed | Organometallic chemistry of the transition elements Florian P. Pruchnik |
| title_short | Organometallic chemistry of the transition elements |
| title_sort | organometallic chemistry of the transition elements |
| topic | Organotransition metal compounds Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Organotransition metal compounds Übergangsmetallkomplexe |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002598139&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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