Complex organometallic catalysts: Transl. from Russian by J. Schmorak
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Jerusalem
Israel Program for Scientific Transl.
1971
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | EST: Kompleksnye metallorganicěskie katalizatory (engl.) |
| Beschreibung: | IX,181 S.m.Abb.u.Tab. |
Internformat
MARC
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| 100 | 1 | |a Korneev, Nikolai N. |e Verfasser |4 aut | |
| 240 | 1 | 0 | |a Kompleksnye metallorganičeskie katalizatory |
| 245 | 1 | 0 | |a Complex organometallic catalysts |b Transl. from Russian by J. Schmorak |c Nikolai Nikolaevič Korneev ; A. F. Popov ; B. A. Krencel'* |
| 264 | 1 | |a Jerusalem |b Israel Program for Scientific Transl. |c 1971 | |
| 300 | |a IX,181 S.m.Abb.u.Tab. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a EST: Kompleksnye metallorganicěskie katalizatory (engl.) | ||
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| 700 | 1 | |a Popov, A. F. |e Verfasser |0 (DE-588)126512094 |4 aut | |
| 700 | 1 | |a Krencel', Boris A. |d 1913-1997 |e Verfasser |0 (DE-588)115430415 |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804121414494584832 |
|---|---|
| adam_text | Titel: Complex organometallic catalysts
Autor: Korneev, Nikolaj N
Jahr: 1971
Table
of
Contents
Foreword................................
vii
Introduction
..............................
viii
Chapter
I.
ORGANOALUMINUM
COMPOUNDS.............
1
1.
Physicochemical
properties
of
alkylaluminum
compounds
.
.
1
Substituted
alkylaluminum
and
arylaluminum
compounds......................
4
2.
Chemical
properties
of
organoaluminum
compounds
....
6
Reactions
with
elements
of
Group
I
and
their
compounds
;6
Reactions
with
elements
of
Group
II
and
their
compounds
7
Reactions
with
elements
of
Group
III
and
their
compounds......................
9
Reactions
with
elements
of
Group
IV
and
their
compounds..............?........
9
Reactions
with
elements
of
Group
V
and
their
compounds......................
12
Reactions
with
elements
of
Group
VI
and
their
compounds......................
14
Reactions
with
elements
of
Group
VII
and
their
compounds......................
16
Reactions
with
compounds
containing
mobile
hydrogen.
17
3.
Synthesis
of
organoaluminum
compounds..........
18
Reaction
between
alkyl
(aryl)
halides
and
metallic
aluminum......................
18
Dehalogenation
of
alkylaluminum
halides.......
18
Reactions
between
organic
compounds
of
Group
I
—
IV
elements
and
aluminum
halides
or
metallic
aluminum......................
19
Reactions
of
trialkylaluminum
compounds
and
aluminum
with
aluminum
halides,
aluminum
alcoholates
and
ethers................
22
Reactions
of
aluminum
hydrides,
alkali
metal
hydrides
and
aluminum
halides
with
olefins..........
23
Electrolysis
of
complex
organoaluminum
compounds
.
.
24
iii
Direct
synthesis
from
metallic
aluminum,
hydrogen
and
olefins........................
25
Reactions
of
organoaluminum
compounds
with
olefins
and
acetylenes......................
26
4.
Synthesis
of
alkylaluminum
compounds
from
aluminum,
hydrogen
and
olefins
.....................
28
Two-stage
direct
synthesis
of
triethylaluminum.......
29
Synthesis
of
diethylaluminum
hydride
.......
29
Reaction
of
mixtures
of
diethylaluminum
hydride
and
triethylaluminum
with
ethylene.......
31
One-step
synthesis
of
triethylaluminum
from
hydrogen,
aluminum
and
ethylene.................
32
Synthesis
of
diisobutylaluminum
hydride
and
of
triisobutyl
-
aluminum
........................
33
Synthesis
of
higher
alkylaluminum
compounds.......
34
5.
Preparation
of
alkylaluminum
halides..............
37
Synthesis
of
alkylaluminum
sesquihalides..........
37
Synthesis
of
dialkylaluminum
halides............
38
Bibliography
................................
41
Chapter
II.
COMPOUNDS
OF
TRANSITION
METALS............
49
1.
Halides
and
alkoxides
of
transition
metals............
49
Titanium
chlorides.....................
49
Titanium
tetrachloride...............
49
Titanium
trichloride................
55
Titanium
dichloride
................
59
Other
halides
of
titanium
and
of
titanium
group
metals
...
60
Halides
of
metals
of
Group
V
and
Group
VI.........
61
Halides
of
metals
of
the
vanadium
sub-group
....
61
Halides
of
metals
of
the
chromium
sub-group.
...
63
Metal
alkoxides
and
aryloxides...............
64
Titanium
alkoxides
and
aryloxides.........
65
2.
Metal
acetylacetonates.....................
67
3.
Organic
derivatives
of
metals..................
70
Cyclopentadienyl
derivatives
of
transition
metals.....
71
Alkyl
and
aryl
derivatives
of
transition
metals.......
73
Alkyl
(aryl)
derivatives
of
Group
IV
transition
metals......................
73
Alkyl
(aryl)
derivatives
of
transition
metals
in
other
groups...................
75
Bibliography
......•..........................
78
Chapter
III.
THE
STUDY
OF
COMPLEX
ORGANOMETALLIC
COMPOUNDS
.
85
1.
Reactions
between
alkylaluminum
compounds
and
titanium
tetrachloride
.........................
86
2.
Reactions
of
alkylaluminum
compounds
with
titanium
trichloride
..........................
93
IV
3.
Reactions
between
alkylaluminum
compounds
and
bis-cyclo-
pentadienyltitanium
dichloride
.................
95
4.
Reactions
of
alkylaluminum
compounds
with
compounds
of
vanadium
and
other
transition
metals..............
104
Bibliography
.................................
108
Chapter
IV.
METHODS
USED
IN
THE
ANALYSIS
OF
COMPONENTS
OF
COMPLEX
CATALYSTS
...................
Ill
I.
Analysis
of
organoaluminum
compounds................
Ill
1.
Determination
of
the
elementary
composition
and
functional
group
assay
in
alkylaluminum
compounds............
112
Elementary
analysis......................
112
Determination
of
total
aluminum...............
114
Functional
group
assay.....................
116
Determination
of
alkyl
groups.............
116
Determination
of
alkoxy
groups............
118
2.
Determination
of
the
activity
of
organoaluminum
compounds
.
.
.
119
Chemical
methods
for
the
determination
of
concentration
of
alkylaluminum
compounds.................
120
Reduction
of
titanium
tetrachloride..........
120
Ammonolysis
.....................
120
Physicochemical
methods
of
determination
of
alkylaluminum
compounds
.........................
121
Electrical
conductivity.................
121
Potentiometric
titration................
122
Conductometric
titration
...............
123
Determination
of
dielectric
constant..........
124
Calorimetric
method
.................
125
Colorimetric
method
.................
126
II.
Analysis
of
salts
of
transition
metals..................
128
1.
Determination
of
titanium
in
the
various
valency
states......
128
2.
Principal
methods
of
analysis
of
salts
of
other
transition
metals
.
.
130
Bibliography
.................................
132
Chapter
V.
UTILIZATION
OF
COMPLEX
ORGANOMETALLIC
CATALYSTS
IN
POLYMERIZATION.....................
137
1.
Types
of
organoaluminum
constituents
of
complex
polymerization
catalysts.............................
137
2.
Effect
of
the
transition
metal
in
the
complex
catalyst
on
its
activity
and
stereospecificity
..................
139
3.
Polymerization
of
ethylene
....................
141
4.
Stereospecific
polymerization
of
propylene
and
other
unsaturated
hydrocarbons...........................
143
5.
Utilization
of
complex
organometallic
catalysts
in
the
polymerization
of
nonhydrocarbon
monomers..........
147
Bibliography
.................................
149
v
Chapter
VI.
OTHER
UTILIZATIONS
OF
COMPLEX
CATALYSTS......
151
1.
Preparation
of
low-molecular
oligomers
of
unsaturated
hydrocarbons
........................
151
Dimerization
and
oligomerization
of
olefins........
151
Linear
and
ring
oligomerization
of
diolefins........
153
Cyclic
trimerization
of
acetylenes.............
155
2.
Isomerization
of
olefins
in
the
presence
of
complex
catalysts
and
their
components.....................
156
3.
Alkylation
catalysts
......................
160
4.
Utilization
of
complex
catalysts
as
reducing
agents.......
161
Catalysis
of
hydrogenation.................
161
Preparation
of
metal
carbonyls
(reductive
carbonylation)
.
.
163
Preparation
of
ir-complexes
of
transition
metals......
164
Chemical
fixation
of
molecular
nitrogen..........
166
Bibliography
...............................
169
Chapter
VII.
TECHNIQUES
EMPLOYED
IN
WORKING
WITH
COMPONENTS
OF
CATALYST
COMPLEXES................
173
1.
Certain
characteristic
properties
of
alkylaluminum
compounds
.
173
2.
Working
techniques.......................
176
3.
Safety
measures,
first
aid
and
fire
precautions.........
177
Bibliography
...............................
178
List
of
abbreviations
appearing
in
the
text.................
180
vi
|
| any_adam_object | 1 |
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| id | DE-604.BV007204488 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:57:36Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-004611394 |
| oclc_num | 634184768 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-83 |
| owner_facet | DE-355 DE-BY-UBR DE-83 |
| physical | IX,181 S.m.Abb.u.Tab. |
| psigel | TUB-nveb |
| publishDate | 1971 |
| publishDateSearch | 1971 |
| publishDateSort | 1971 |
| publisher | Israel Program for Scientific Transl. |
| record_format | marc |
| spelling | Korneev, Nikolai N. Verfasser aut Kompleksnye metallorganičeskie katalizatory Complex organometallic catalysts Transl. from Russian by J. Schmorak Nikolai Nikolaevič Korneev ; A. F. Popov ; B. A. Krencel'* Jerusalem Israel Program for Scientific Transl. 1971 IX,181 S.m.Abb.u.Tab. txt rdacontent n rdamedia nc rdacarrier EST: Kompleksnye metallorganicěskie katalizatory (engl.) Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Aluminiumorganische Verbindungen (DE-588)4305230-7 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Aluminiumorganische Verbindungen (DE-588)4305230-7 s DE-604 Metallorganische Verbindungen (DE-588)4038906-6 s Katalyse (DE-588)4029921-1 s Popov, A. F. Verfasser (DE-588)126512094 aut Krencel', Boris A. 1913-1997 Verfasser (DE-588)115430415 aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004611394&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Korneev, Nikolai N. Popov, A. F. Krencel', Boris A. 1913-1997 Complex organometallic catalysts Transl. from Russian by J. Schmorak Metallorganische Verbindungen (DE-588)4038906-6 gnd Aluminiumorganische Verbindungen (DE-588)4305230-7 gnd Katalyse (DE-588)4029921-1 gnd |
| subject_GND | (DE-588)4038906-6 (DE-588)4305230-7 (DE-588)4029921-1 |
| title | Complex organometallic catalysts Transl. from Russian by J. Schmorak |
| title_alt | Kompleksnye metallorganičeskie katalizatory |
| title_auth | Complex organometallic catalysts Transl. from Russian by J. Schmorak |
| title_exact_search | Complex organometallic catalysts Transl. from Russian by J. Schmorak |
| title_full | Complex organometallic catalysts Transl. from Russian by J. Schmorak Nikolai Nikolaevič Korneev ; A. F. Popov ; B. A. Krencel'* |
| title_fullStr | Complex organometallic catalysts Transl. from Russian by J. Schmorak Nikolai Nikolaevič Korneev ; A. F. Popov ; B. A. Krencel'* |
| title_full_unstemmed | Complex organometallic catalysts Transl. from Russian by J. Schmorak Nikolai Nikolaevič Korneev ; A. F. Popov ; B. A. Krencel'* |
| title_short | Complex organometallic catalysts |
| title_sort | complex organometallic catalysts transl from russian by j schmorak |
| title_sub | Transl. from Russian by J. Schmorak |
| topic | Metallorganische Verbindungen (DE-588)4038906-6 gnd Aluminiumorganische Verbindungen (DE-588)4305230-7 gnd Katalyse (DE-588)4029921-1 gnd |
| topic_facet | Metallorganische Verbindungen Aluminiumorganische Verbindungen Katalyse |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004611394&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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