Energetic polymers: binders and plasticizers for enhancing performance
Gespeichert in:
Hauptverfasser: | , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH-Verl.
2012
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Schlagworte: | |
Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | Literaturangaben |
Beschreibung: | XVI, 218 S. Ill., graph. Darst. 25 cm |
ISBN: | 9783527331550 3527331557 |
Internformat
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IMAGE 1
CONTENTS
PREFACE I X
ABBREVIATIONS X I
1 POLYMERS AS BINDERS AND PLASTICIZERS -
HISTORICAL PERSPECTIVE 1 1.1 NITROCELLULOSE 1
1.2 POLYSULFIDES 2
1.3 POLYBUTADIENES (PBAA, PBAN, A N D CTPB) 3
1.4 POLYURETHANES 4
1.5 HYDROXY TERMINATED POLYBUTADIENE 5
1.6 EXPLOSIVE BINDERS 5
1.7 THERMOPLASTIC ELASTOMERS 6
1.8 ENERGETIC POLYMERS (OTHER T H A N NC) AS BINDERS 8
1.8.1 POLYGLYCIDYL NITRATE 8
1.8.2 GAP 9
1.8.3 ENERGETIC POLYOXETANES 10
1.8.4 POLYPHOSPHAZENES 11
1.8.5 ENERGETIC THERMOPLASTIC ELASTOMERS 11 1.9 ENERGETIC POLYMER
PLASTICIZERS 12
REFERENCES 15
2 HIGH NITROGEN CONTENT POLYMERS 19
2.1 INTRODUCTION 19
2.2 PREPARATION O F ENERGETIC AZIDO POLYMERS 19
2.2.1 GLYCIDYL AZIDE POLYMER 19
2.2.2 AZIDO POLYMERS FROM OXETANES 22
2.2.2.1 POLY(BAMO) 23
2.2.2.2 POLY(AMMO) 24
2.3 PHYSICAL PROPERTIES O F AZIDO POLYMERS 25
2.4 CURING O F AZIDO POLYMERS 2 5
2.4.1 CURING BY POLYISOCYANATES 25
HTTP://D-NB.INFO/1014518164
IMAGE 2
2.4.1.1 PREPARATION 26
2.4.1.2 STRUCTURE O F CURED POLYURETHANE ELASTOMER 28 2.4.1.3 KINETICS O
F CURING O F AZIDO POLYMERS 29 2.4.1.4 GEL-TIME CHARACTERISTICS 31
2.4.1.5 POST-CURE PROPERTIES 33
2.5 CURING O F AZIDO POLYMERS BY DIPOLAROPHILES 3 8
2.6 THERMAL DECOMPOSITION CHARACTERISTICS O F AZIDO POLYMERS 41 2.6.1*
MECHANISM O F THERMAL DECOMPOSITION 41 2.6.2 KINETICS O F THERMAL
DECOMPOSITION O F AZIDO POLYMERS 43
2.7 COMBUSTION O F AZIDO POLYMERS 47
2.8 THERMAL DECOMPOSITION AND COMBUSTION O F ENERGETIC FORMULATIONS WITH
AZIDO POLYMERS 49 2.8.1 THERMAL DECOMPOSITION O F AZIDO
POLYMER/NITRAMINE MIXTURES 50 2.8.2 COMBUSTION O F AZIDO
POLYMER/NITRAMINE PROPELLANT MIXTURES 54
2.8.3 COMBUSTION O F AZIDO POLYMER/AMMONIUM NITRATE COMPOSITE
PROPELLANTS 5 7 2.8.4 COMBUSTION O F AZIDO POLYMER PROPELLANTS WITH H N
F 58 2.9 PERFORMANCE O F AZIDO POLYMER-BASED PROPELLANTS 61
2.10 AZIDO POLYMERS AS EXPLOSIVE BINDERS 63
2.10.1 AZIDO POLYMER BASED PBX FORMULATIONS FOR UNDERWATER EXPLOSIVES 65
2.11 TETRAZOLE POLYMERS A N D THEIR SALTS 66
2.12 N-N-BONDED EPOXY BINDERS 69
REFERENCES 70
3 NITROPOLYMERS A S ENERGETIC BINDERS 81
3.1 INTRODUCTION 81
3.2 PREPARATION O F NITROPOLYMERS 82
3.2.1 NITROCELLULOSE 8 2
3.2.2 POLY(GLYCIDYL NITRATE) (PGN) 83
3.2.2.1 CURING O F PGN 85
3.2.3 POLY(NITRATOMETHYL-METHYL OXETANE) (POLY(NIMMO)) 88 3.2.4 NITRATED
HTPB (NHTPB) 90
3.2.5 NITRATED CYCLODEXTRIN POLYMERS (POLY(CDN)) 90 3.3 THERMAL
DECOMPOSITION BEHAVIOR O F NITROPOLYMERS 91 3.3.1 NITROCELLULOSE 91
3.3.2 POLY(NITRATOMETHYL-METHYL OXETANE) (POLY(NLMMO)) 94 3.3.3
POLY(GLYCIDYL NITRATE) (PGN) 98
3.4 COMBUSTION O F NITRATE ESTER POLYMERS AND PROPELLANTS 100
3.4.1 NC BASED DOUBLE-BASE PROPELLANTS 100 3.4.2 COMPOSITE MODIFIED
DOUBLE-BASE (CMDB) PROPELLANTS 101 3.4.3 POLY(NIMMO)-BASED COMPOSITE
PROPELLANTS 106
IMAGE 3
3.4.4 PGN-BASED COMPOSITE PROPELLANTS 109
3.5 NITROPOLYMER-BASED EXPLOSIVE COMPOSITIONS 111 REFERENCES 115 *
4 ENERGETIC THERMOPLASTIC ELASTOMERS 121
4.1 INTRODUCTION 121
4.2 PREPARATION O F ENERGETIC THERMOPLASTIC ELASTOMERS 122 4.3 THERMAL
DECOMPOSITION A N D COMBUSTION O F ETPES 132
4.4 COMBUSTION O F ETPE PROPELLANT FORMULATIONS 137
4.5 PERFORMANCE O F ETPE BASED PROPELLANT FORMULATIONS 139 4.6 MELT-CAST
EXPLOSIVES BASED ON ETPES 141
4.7 ETPE BASED POLYMER NANOCOMPOSITES 142
REFERENCES 144
5 FLUOROPOLYMERS AS BINDERS 147
5.1 INTRODUCTION 147
5.2 POLY(TETRAFLUOROETHYLENE) (PTFE) 148
5.2.1 PHASE TRANSITIONS O F PTFE 148
5.2.2 ENERGETIC COMPOSITES O F PTFE 149
5.3 COPOLYMERS O F TETRAFLUOROETHYLENE 152
5.3.1 KEL-F800 153
5.3.1.1 DYNAMIC BEHAVIOR O F KEL-F800 U N D E R SHOCK 153 5.3.1.2
THERMAL DECOMPOSITION 155 5.3.2 VITON A 156
5.3.2.1 THERMAL DECOMPOSITION O F VITON 158 5.4 ENERGETIC POLYMERS
CONTAINING FLUORINE 159
5.5 MISCELLANEOUS ENERGETIC FLUOROPOLYMERS 161 5.6 PBX FORMULATIONS WITH
FLUOROPOLYMERS 162
REFERENCES 165
6 ENERGETIC PLASTICIZERS FOR HIGH PERFORMANCE 171
6.1 INTRODUCTION 171
6.2 ENERGETIC PLASTICIZERS BASED O N AZIDO COMPOUNDS 172
6.2.1 AZIDO ACETATE ESTER BASED PLASTICIZERS 172 6.2.2 AZIDO BASED
OLIGOMERIC PLASTICIZERS 174 6.3 PERFORMANCE O F PROPELLANT FORMULATIONS
CONTAINING AZIDO PLASTICIZERS 178
6.4 NITRATE ESTER PLASTICIZERS 180
6.4.1 GENERAL CHARACTERISTICS 180
6.4.2 PERFORMANCE 183
6.5 NITRATE ESTER OLIGOMERS AS ENERGETIC PLASTICIZERS 184
6.6 MISCELLANEOUS -PLASTICIZERS BASED ON NITRO-GROUPS 186 6.6.1
POLYNITRO-ALIPHATIC PLASTICIZERS 186
IMAGE 4
6.6.2 NITRATOETHYLNITRAMINE (NENA) PLASTICIZERS 188
REFERENCES 189
7 APPLICATION O F COMPUTATIONAL TECHNIQUES T O ENERGETIC POLYMERS AND
FORMULATIONS 193 7.1 INTRODUCTION 193
7.2 OVERVIEW OFXOMPUTATIONAL TECHNIQUES 193
7.3 APPLICATION O F COMPUTATIONAL MODELING TECHNIQUES TO ENERGETIC
POLYMER FORMULATIONS 197 7.3.1 Q U A N T U M MECHANICAL METHODS 197
7.3.2 MOLECULAR DYNAMICS (MD) SIMULATIONS 201 7.3.3 MESOSCALE
SIMULATIONS 205
7.3.4 MACROSCALE SIMULATIONS 206
7.4 FUTURE OUTLOOK 207
REFERENCES 208
INDEX 211 |
any_adam_object | 1 |
author | Ang, How Ghee Pisharath, Sreekumar |
author_GND | (DE-588)1020304332 |
author_facet | Ang, How Ghee Pisharath, Sreekumar |
author_role | aut aut |
author_sort | Ang, How Ghee |
author_variant | h g a hg hga s p sp |
building | Verbundindex |
bvnumber | BV039965139 |
classification_rvk | UV 6000 VN 5480 |
ctrlnum | (OCoLC)780310378 (DE-599)DNB1014518164 |
dewey-full | 662.2 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 662 - Explosives, fuels & related products |
dewey-raw | 662.2 |
dewey-search | 662.2 |
dewey-sort | 3662.2 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie Physik |
format | Book |
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language | English |
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owner_facet | DE-11 DE-703 DE-29T DE-92 DE-19 DE-BY-UBM |
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spelling | Ang, How Ghee Verfasser aut Energetic polymers binders and plasticizers for enhancing performance How Ghee Ang and Sreekumar Pisharath Weinheim Wiley-VCH-Verl. 2012 XVI, 218 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Energetisches Material (DE-588)7643045-5 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Polymere (DE-588)4046699-1 s Energetisches Material (DE-588)7643045-5 s DE-604 Pisharath, Sreekumar Verfasser (DE-588)1020304332 aut X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3870453&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024822799&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Ang, How Ghee Pisharath, Sreekumar Energetic polymers binders and plasticizers for enhancing performance Energetisches Material (DE-588)7643045-5 gnd Polymere (DE-588)4046699-1 gnd |
subject_GND | (DE-588)7643045-5 (DE-588)4046699-1 |
title | Energetic polymers binders and plasticizers for enhancing performance |
title_auth | Energetic polymers binders and plasticizers for enhancing performance |
title_exact_search | Energetic polymers binders and plasticizers for enhancing performance |
title_full | Energetic polymers binders and plasticizers for enhancing performance How Ghee Ang and Sreekumar Pisharath |
title_fullStr | Energetic polymers binders and plasticizers for enhancing performance How Ghee Ang and Sreekumar Pisharath |
title_full_unstemmed | Energetic polymers binders and plasticizers for enhancing performance How Ghee Ang and Sreekumar Pisharath |
title_short | Energetic polymers |
title_sort | energetic polymers binders and plasticizers for enhancing performance |
title_sub | binders and plasticizers for enhancing performance |
topic | Energetisches Material (DE-588)7643045-5 gnd Polymere (DE-588)4046699-1 gnd |
topic_facet | Energetisches Material Polymere |
url | http://deposit.dnb.de/cgi-bin/dokserv?id=3870453&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024822799&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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