Organometallic reactions and polymerization:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2014
|
| Schriftenreihe: | Lecture notes in chemistry
85 |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | X, 301 S. graph. Darst. |
| ISBN: | 9783662435380 3662435381 9783662435397 |
Internformat
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Datensatz im Suchindex
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CONTENTS
1 OLEFIN POLYMERIZATION WITH METALLOCENE CATALYSTS I
TAKESHI SHIONO
1.1 INTRODUCTION 1
1.2 ELEMENTARY PROCESSES OF OLEFIN POLYMERIZATION 3
1.2.1 INITIATION AND PROPAGATION REACTIONS 3
1.2.2 CHAIN TRANSFER AND TERMINATION REACTION 3
1.2.3 MOLECULAR WEIGHT AND MOLECULAR WEIGHT DISTRIBUTION. 5
1.3 STRUCTURE OF VINYL POLYMER AND STEREOSPECIFIC
POLYMERIZATION 8
1.3.1 STEREOREGULARITY OF VINYL POLYMER 8
1.3.2 REGIOCHEMISTRY IN PROPYLENE POLYMERIZATION 8
1.3.3 ORIGIN OF STEREOSPECIFICITY 10
1.3.4 POLYMERIZATION MECHANISM AND MICROTACTICITY II
1.4 COPOLYMER AND COPOLYMERIZATION 16
1.4.1 STRUCTURE OF COPOLYMERS 16
1.4.2 COPOLYMERIZATION 16
1.5 CHARACTERISTICS OF METALLOCENE CATALYSTS 27
1.5.1 ACTIVATION PROCESS OF METALLOCENE 27
1.5.2 TACTICITY CONTROL OF POLYPROPYLENE 31
1.5.3 CONTROL OF CHAIN TRANSFER REACTION 39
1.5.4 COPOLYMERIZATION OF OLEFINS 41
1.6 CONCLUSION 46
REFERENCES 47
2 OLEFIN POLYMERIZATION WITH HALF-METALLOCENE CATALYSTS 51
KOTOHIRO NOMURA AND JINGYU LIU
2.1 INTRODUCTION 51
2.2 MODIFIED HALF-TITANOCENES AS OLEFIN POLYMERIZATION
CATALYSTS 52
2.2.1 OLEFIN POLYMERIZATION BY HALF-TITANOCENES
CONTAINING ARYLOXO LIGANDS 54
2.2.2 SELECTED EXAMPLES IN OLEFIN POLYMERIZATION
BY HALF-TITANOCENES CONTAINING THE OTHER ANIONIC
ANCILLARY DONOR LIGANDS 56
VII
HTTP://D-NB.INFO/1050307135
VIII
CONTENTS
2.2.3 COPOLYMERIZATIONS OF ETHYLENE WITH STERICALLY
ENCUMBERED A-OLEFINS 59
2.2.4 COPOLYMERIZATION WITH CYCLIC OLEFINS 67
2.3 SYNDIOSPECIFIC STYRENE POLYMERIZATION AND ETHYLENE/STYRENE
COPOLYMERIZATION USING HALF-TITANOCENES: LIGAND EFFECTS
AND SOME NEW MECHANISTIC ASPECTS 70
2.3.1 SYNDIOSPECIFIC STYRENE POLYMERIZATION USING
CP'TIX
2
(Y)-MAO CATALYST SYSTEMS 71
2.3.2 ETHYLENE/STYRENE COPOLYMERIZATION USING
HALF-TITANOCENES 73
2.3.3 ROLE OF ANIONIC DONOR LIGAND IN ETHYLENE/STYRENE
COPOLYMERIZATION AND SYNDIOSPECIFIC STYRENE
POLYMERIZATION: MECHANISTIC CONSIDERATIONS 79
2.4 SUMMARY AND OUTLOOK 81
REFERENCES 82
3 OLEFIN POLYMERIZATION WITH NON-METALLOCENE CATALYSTS
(EARLY TRANSITION METALS) 89
KOTOHIRO NOMURA AND WENJUAN ZHANG
3.1 INTRODUCTION 89
3.2 DESIGN, SYNTHESIS OF MOLECULAR CATALYST WITH EARLY
TRANSITION METALS 90
3.2.1 TITANIUM, ZIRCONIUM, AND HAFNIUM COMPLEXES 90
3.2.2 VANADIUM COMPLEXES 98
3.2.3 MISCELLANEOUS EARLY TRANSITION METAL
COMPLEX CATALYSTS 109
3.3 SUMMARY AND OUTLOOK 113
REFERENCES 113
4 OLEFIN POLYMERIZATION WITH NON-METALLOCENE CATALYSTS
(LATE TRANSITION METALS) 119
DAISUKE TAKEUCHI
4.1 INTRODUCTION: BRIEF HISTORY OF LATE TRANSITION METAL CATALYSTS
FOR OLEFIN POLYMERIZATION 120
4.2 POLYMERIZATION OF OLEFINS CATALYZED BY CATIONIC PD
AND NI COMPLEXES WITH NEUTRAL LIGANDS 121
4.2.1 CATIONIC NI AND PD CATALYSTS WITH DIIMINE LIGANDS . 122
4.2.2 CATIONIC COMPLEXES WITH OTHER BIDENTATE
NEUTRAL LIGANDS 132
4.2.3 CATIONIC COMPLEXES WITH MONODENTATE
AND TRIDENTATE LIGANDS 133
4.3 POLYMERIZATION OF OLEFINS BY NEUTRAL PD AND NI COMPLEXES
WITH MONOANIONIC LIGANDS 134
CONTENTS IX
4.3.1 NEUTRAL COMPLEXES WITH MONOANIONIC N-0 LIGANDS . 134
4.3.2 PHOSPHINESULFONATE COMPLEXES OF PD 138
4.3.3 NEUTRAL COMPLEXES WITH OTHER MONOANIONIC LIGANDS . . . 140
4.4 POLYMERIZATION OF OLEFINS BY FE AND CO COMPLEXES 141
4.5 POLYMERIZATION OF OLEFINS BY OTHER LATE TRANSITION
METAL CATALYSTS 146
4.6 MULTIMETALLIC CATALYSTS 146
4.7 OLEFIN POLYMERIZATION IN AQUEOUS MEDIA 149
4.8 CYCLOPOLYMERIZATION OF NON-CONJUGATED DIENES 150
4.9 SUMMARY 153
REFERENCES 154
5 OLIGOMERIZATION OF OLEFINS 169
DAISUKE TAKEUCHI AND KOHTARO OSAKADA
5.1 INTRODUCTION 169
5.2 OLIGOMERIZATION OF ETHYLENE 170
5.2.1 GENERAL ASPECT 170
5.2.2 ETHYLENE OLIGOMERIZATION TO OLEFINS WITH SCHULZ-FLORY
DISTRIBUTION AND DIMERIZATION 171
5.2.3 ETHYLENE OLIGOMERIZATION TO A-OLEFINS
WITH POISSON DISTRIBUTION 176
5.3 SELECTIVE TRIMERIZATION OF ETHYLENE 177
5.3.1 CHROMIUM CATALYST 177
5.3.2 TITANIUM CATALYST 189
5.3.3 TANTALUM CATALYST 192
5.3.4 RUTHENIUM CATALYST 193
5.4 TETRAMERIZATION OF ETHYLENE 194
5.4.1 EFFECT OF LIGAND STRUCTURE 195
5.4.2 EFFECT OF COCATALYSTS AND ADDITIVES 199
5.4.3 MECHANISM OF CR-CATALYZED ETHYLENE TETRAMERIZATION. . . 200
5.5 DIMERIZATION OF A-OLEFINS 201
5.6 TRIMERIZATION OF A-OLEFINS 204
5.7 COOLIGOMERIZATION OF ETHYLENE AND A-OLEFINS 205
5.8 COOLIGOMERIZATION OF OTHER VINYL MONOMERS 206
5.9 SUMMARY 207
REFERENCES 207
6 POLYMERIZATION OF POLAR MONOMERS 217
KYOKO NOZAKI
6.1 INTRODUCTION 217
6.2 COORDINATION-ADDITION POLYMERIZATION OF POLAR MONOMERS 218
6.3 BLOCK COPOLYMERIZATION OF POLAR MONOMERS
AND NON-POLAR MONOMERS 221
X
CONTENTS
6.4 RANDOM COPOLYMERIZATION OF POLAR MONOMERS
AND NON-POLAR MONOMERS 221
6.4.1 GENERAL ASPECTS ON COORDINATION-INSERTION
POLYMERIZATION OF POLAR VINYL MONOMERS 223
6.4.2 DIIMINE/PD OR NI CATALYST 224
6.4.3 PHOSPHINE-SULFONATE/PD CATALYST 229
6.5 COPOLYMERIZATION OF POLAR MONOMERS WITH OTHER MONOMERS . . . 232
6.6 CONCLUSIONS AND OUTLOOK 234
REFERENCES 234
7 METATHESIS AND POLYMERIZATION 237
KOHTARO OSAKADA
7.1 INTRODUCTION 237
7.2 CATALYSTS 240
7.2.1 MULTICOMPONENT CATALYSTS 240
7.2.2 HOMOGENEOUS CATALYSTS 241
7.3 APPLICATION OF OLEFIN METATHESIS 249
7.3.1 SYNTHESIS OF THE POLYMERS WITH NEW STRUCTURES
AND FUNCTIONALITY 249
7.3.2 SYNTHESIS AND REACTIONS OF THE LIGAND OF TRANSITION
METAL COMPLEXES 252
7.3.3 SYNTHESIS OF NATURAL PRODUCTS 257
7.3.4 INTERLOCKED MOLECULES 260
7.4 CONCLUSION 266
REFERENCES 266
8 CROSS-COUPLING POLYMERIZATION 271
TAKE-AKI KOIZUMI AND TAKAKI KANBARA
8.1 INTRODUCTION 271
8.2 NI-CATALYZED POLYCONDENSATION 272
8.3 PD-CATALYZED POLYCONDENSATION 276
8.4 CU-CATALYZED POLYCONDENSATION 289
8.5 RECENT TOPICS OF THE POLYMERS SYNTHESIZED
BY USING CROSS-COUPLING POLYMERIZATION METHODS 291
8.6 SUMMARY 297
REFERENCES 297 |
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| id | DE-604.BV042026669 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T01:43:09Z |
| institution | BVB |
| isbn | 9783662435380 3662435381 9783662435397 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027468208 |
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| owner_facet | DE-188 |
| physical | X, 301 S. graph. Darst. |
| publishDate | 2014 |
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| publisher | Springer |
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| series | Lecture notes in chemistry |
| series2 | Lecture notes in chemistry |
| spelling | Organometallic reactions and polymerization Kohtaro Osakada, ed. 201408 Berlin [u.a.] Springer 2014 X, 301 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Lecture notes in chemistry 85 Chemie Chemistry, Organic Polymers Catalysis Chemistry Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Oligomerisation (DE-588)4172549-9 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Alkene (DE-588)4001207-4 gnd rswk-swf Alkene (DE-588)4001207-4 s Polymerisation (DE-588)4046704-1 s Oligomerisation (DE-588)4172549-9 s Katalysator (DE-588)4029919-3 s Metallorganische Verbindungen (DE-588)4038906-6 s DE-604 Osakada, Kohtaro (DE-588)1057985953 edt Lecture notes in chemistry 85 (DE-604)BV041378218 85 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4648266&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027468208&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Organometallic reactions and polymerization Lecture notes in chemistry Chemie Chemistry, Organic Polymers Catalysis Chemistry Metallorganische Verbindungen (DE-588)4038906-6 gnd Oligomerisation (DE-588)4172549-9 gnd Katalysator (DE-588)4029919-3 gnd Polymerisation (DE-588)4046704-1 gnd Alkene (DE-588)4001207-4 gnd |
| subject_GND | (DE-588)4038906-6 (DE-588)4172549-9 (DE-588)4029919-3 (DE-588)4046704-1 (DE-588)4001207-4 |
| title | Organometallic reactions and polymerization |
| title_auth | Organometallic reactions and polymerization |
| title_exact_search | Organometallic reactions and polymerization |
| title_full | Organometallic reactions and polymerization Kohtaro Osakada, ed. |
| title_fullStr | Organometallic reactions and polymerization Kohtaro Osakada, ed. |
| title_full_unstemmed | Organometallic reactions and polymerization Kohtaro Osakada, ed. |
| title_short | Organometallic reactions and polymerization |
| title_sort | organometallic reactions and polymerization |
| topic | Chemie Chemistry, Organic Polymers Catalysis Chemistry Metallorganische Verbindungen (DE-588)4038906-6 gnd Oligomerisation (DE-588)4172549-9 gnd Katalysator (DE-588)4029919-3 gnd Polymerisation (DE-588)4046704-1 gnd Alkene (DE-588)4001207-4 gnd |
| topic_facet | Chemie Chemistry, Organic Polymers Catalysis Chemistry Metallorganische Verbindungen Oligomerisation Katalysator Polymerisation Alkene |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4648266&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027468208&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV041378218 |
| work_keys_str_mv | AT osakadakohtaro organometallicreactionsandpolymerization |