Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2011
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | 136 S. graph. Darst. 210 mm x 148 mm, 191 g |
| ISBN: | 9783868538311 |
Internformat
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| 245 | 1 | 0 | |a Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes |c Andreas H. Obenhuber |
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Datensatz im Suchindex
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| adam_text |
IMAGE 1
TABLE OF CONTENTS
1. INTRODUCTION 9
1.1 C-C SINGLE BOND ACTIVATION-GENERAL CONSIDERATIONS 10
1.2 CHOOSING AN ENTRANCE INTO C-C SINGLE BOND ACTIVATION 12
1.3 FROM NICKEL CHEMISTRY TO A MODEL SYSTEM 14
2. CHELATE ASSISTED ACTIVATION OF AN UNSTRAINED C(SP 2)-C(SP2) SINGLE
BOND IN A VASKA COMPLEX
ANALOGUE 17
2.1 OXIDATIVE ADDITION 18
2.2 CO EXTRUSION 22
2.3 TRANSLCIS ISOMERIZATION 26
2.4 CIS/CIS' ISOMERIZATION 30
2.5 MECHANISTIC CONSIDERATIONS 31
3. ACTIVATION OF AN UNSTRAINED C(SP 2)-C(SP2) SINGLE BOND USING
CHELATE-BISPHOSPHINITE RH(I)
COMPLEXES 37
3.1 ELUCIDATION OF THE METAL INSERTION 37
3.2 REDUCTIVE ELIMINATION 42
3.3 DYNAMIC BEHAVIOUR IN COORDINATING SOLVENTS 46
3.4 LIGAND SUBSTITUTION REACTIONS USING RHCL(CO)(PPH 3)2 50
3.5 INVESTIGATION OF THE OXIDATIVE ADDITION PROCESS 53
3.6 INVESTIGATION OF (COD)RH(K I-/ ,C-P(OC 6H4)-('C3H7)2) AS RH(I) METAL
SOURCE 60
4. FURTHER INVESTIGATION INTO THE HEAVY PLATINUM METALS 65
4.1 OSMIUM 65
4.1.1 STABLE R| 2-C,0 PRE-COORDINATION AND OXIDATIVE ADDITION 67
4.1.2 CO EXTRUSION AND MECHANISTIC CONSIDERATIONS 71
4.1.3 FIRST ATTEMPTS ON SYNTHESIZING OS-BIARYL COMPOUNDS 76
4.2 SCREENING FOR C-C SINGLE BOND ACTIVATION REACTIONS - PLATINUM 79
5. SUMMARY 83
6. EXPERIMENTAL SECTION 87
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1010823353
DIGITALISIERT DURCH
IMAGE 2
TABLE OF CONTENTS
6.1 LIGAND PRECURSOR 89
6.2 LIGANDS 94
6.3 COMPLEXES 98
6.3.1 IRIDIUM COMPOUNDS 98
6.3.2 RHODIUM COMPOUNDS 108
6.3.3 OSMIUM COMPOUNDS 114
7. X-RAY STRUCTURAL DATA 123
8. REFERENCES 127 |
| any_adam_object | 1 |
| author | Obenhuber, Andreas H. |
| author_GND | (DE-588)143983989 |
| author_facet | Obenhuber, Andreas H. |
| author_role | aut |
| author_sort | Obenhuber, Andreas H. |
| author_variant | a h o ah aho |
| building | Verbundindex |
| bvnumber | BV037330406 |
| classification_tum | CHE 376d CHE 331d CHE 334d CHE 365d |
| ctrlnum | (OCoLC)725064024 (DE-599)DNB1010823353 |
| dewey-full | 541.224 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.224 |
| dewey-search | 541.224 |
| dewey-sort | 3541.224 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-20T11:05:09Z |
| institution | BVB |
| isbn | 9783868538311 |
| language | English |
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| physical | 136 S. graph. Darst. 210 mm x 148 mm, 191 g |
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| series2 | Anorganische Chemie |
| spelling | Obenhuber, Andreas H. Verfasser (DE-588)143983989 aut Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes Andreas H. Obenhuber 1. Aufl. München Verl. Dr. Hut 2011 136 S. graph. Darst. 210 mm x 148 mm, 191 g txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2011 Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 gnd rswk-swf Chelate (DE-588)4123003-6 gnd rswk-swf Aktivierung Chemie (DE-588)4141761-6 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Chelate (DE-588)4123003-6 s Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 s Aktivierung Chemie (DE-588)4141761-6 s Übergangsmetallkomplexe (DE-588)4131837-7 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3708573&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022484347&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Obenhuber, Andreas H. Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 gnd Chelate (DE-588)4123003-6 gnd Aktivierung Chemie (DE-588)4141761-6 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4164549-2 (DE-588)4123003-6 (DE-588)4141761-6 (DE-588)4131837-7 (DE-588)4113937-9 |
| title | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes |
| title_auth | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes |
| title_exact_search | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes |
| title_full | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes Andreas H. Obenhuber |
| title_fullStr | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes Andreas H. Obenhuber |
| title_full_unstemmed | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes Andreas H. Obenhuber |
| title_short | Investigation into the chelate assisted activation of non-strained C(sp2)-C(sp2) single bonds using group 8, 9 and 10 transition metal complexes |
| title_sort | investigation into the chelate assisted activation of non strained c sp2 c sp2 single bonds using group 8 9 and 10 transition metal complexes |
| topic | Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 gnd Chelate (DE-588)4123003-6 gnd Aktivierung Chemie (DE-588)4141761-6 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Kohlenstoff-Kohlenstoff-Bindung Chelate Aktivierung Chemie Übergangsmetallkomplexe Hochschulschrift |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3708573&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022484347&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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