Thermoelectric materials and devices:
Saved in:
| Other Authors: | , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge, UK
Royal Society Of Chemistry
[2017]
|
| Series: | RSC energy and environment series
no. 17 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | xi, 255 Seiten Illustrationen, Diagramme (überwiegend farbig) |
| ISBN: | 178262323X 9781782623236 |
| ISSN: | 2044-0774 |
Staff View
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| 245 | 1 | 0 | |a Thermoelectric materials and devices |c edited by Iris Nandhakumar, University of Southampton, UK; Neil M. White, University of Southampton, UK; Stephen Beeby, University of Southampton, UK |
| 264 | 1 | |a Cambridge, UK |b Royal Society Of Chemistry |c [2017] | |
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Record in the Search Index
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| adam_text | Contents
Chapter 1 Zintl Phases: Recent Developments in Thermoelectrics and fj
Future Outlook 1
Susan M. Kauzlarich, Alex Z Eric Toberer and
G. Jeff Snyder
1.1 Introduction 1
1.1.1 Definition of Zintl Phases 1
1.1.2 Charge Counting/Formal Valence Rules 2
1.1.3 Thermoelectric Zintl Compounds 4
1.2 Thermal Properties 7
1.2.1 Theory behind Low kl in Complex Materials 8
1.2.2 Case Studies 11
1.3 Electronic Transport 13
1.3.1 Controlling and Optimizing Carrier
Concentration 14
1.3.2 Limits to Controlling Carrier Concentration 15
1.3.3 Band Structure Requirements 16
1.3.4 Carrier Relaxation Time 18
1.4 Future Opportunities for Zintl Thermoelectric
Materials 19
Acknowledgements 19
References 19
Chapter 2 Chalcogenide Thermoelectric Materials 27
Anthony V. Powell and Paz Vaqueiro
2.1 Introduction 27
RSC Energy and Environment Series No. 17
Thermoelectric Materials and Devices
Edited by Iris Nandhakumar, Neil M. White and Stephen Beeby
© The Royal Society of Chemistry 2017
Published by the Royal Society of Chemistry, www.rsc.org
vii
viii
Contents
2.2 Synthesis 30
2.3 Low-dimensionality in Chalcogenides 32
2.3.1 Layered Dichalcogenides 32
2.3.2 Intercalated Phases 35
2.3.3 Structurally-related Phases 37
2.4 Shandite-related Phases 37
2.5 Rocksalt-derived Chalcogenides 40
2.6 Tin Selenide and Related Materials 45
2.7 Oxychalcogenides 47
2.8 Copper-containing Chalcogenides with
Low Thermal Conductivities 49
2.9 Concluding Remarks 51
References 52
Chapter 3 Thermoelectric Oxides 60
Colin Norman, Feridoon Azough and Robert Freer
3.1 Introduction 60
3.2 Manufacture 63
3.3 Composition and Atomic Structure 67
3.3.1 Strontium Titanate Based Materials 67
3.3.2 Cobaltites 70
3.3.3 Calcium Manganate Based Materials 73
3.3.4 Zinc Oxide 74
3.4 Microstructure 74
3.5 Module Manufacture 76
3.6 Conclusions 77
References 78
Chapter 4 Nano- and Micro-fabrication Techniques for Improving
Thermoelectric Materials and Generators 83
Douglas J. Paul
4.1 Introduction 83
4.2 Low-dimensional Electrical Conductivity 85
4.3 The Seebeck Coefficient and Low-dimensional
Modifications 92
4.4 Thermal Conductivity 93
4.5 Potential Improvements to Thermoelectrics from
Nano- and Micro-structures 97
4.6 Micro-fabrication of Thermoelectric Generators 102
4.7 Conclusions 107
References 107
ix
109
109
109
110
112
112
116
117
118
119
123
123
125
126
128
128
128
133
133
134
134
135
137
143
146
146
147
150
151
154
155
155
Review of the Methods for Thermal Conductivity
Measurements Most Appropriate for Thermoelectric
Materials
Ekaterina Selezneva, Clark Stacey, Pablo Diaz-Chao,
Andres Muhiz-Piniella and Alexandre Cuenat
5.1 Introduction
5.1.1 Thermoelectric Challenges
5.1.2 Thermal Conductivity Measurements
5.2 Steady-state Methods
5.2.1 Guarded Hot Plate
5.2.2 High-temperature Measurements
5.2.3 Radial Heat Flow Method
5.2.4 High-temperature Measurements
5.2.5 Longitudinal Heat Flow
5.2.6 High-temperature Measurements
5.2.7 Heat-flow Meter
5.3 Transient Methods
5.3.1 Metrological Approach
5.4 Conclusions
Acknowledgements
References
High-throughput Thermoelectric Measurement
Techniques
Jorge García-Cañadas and Gao Min
6.1 Introduction
6.2 Multifunctional Probes
6.2.1 Measuring Principles
6.2.2 Design and Fabrication of Multifunctional
Probes
6.2.3 Measurement Systems and Procedures
6.2.4 Precision, Accuracy and Rapidness
6.3 Impedance Spectroscopy
6.3.1 Fundamentals of Impedance Spectroscopy
6.3.2 Theoretical Framework
6.3.3 Experimental Set-up
6.3.4 Measurement Analysis and Applications
6.4 Conclusions
Acknowledgements
References
X
Contents
Chapter 7 System Design Considerations for Thermoelectric
Energy Recovery 156
Richard Stobart, Zhijia Yang and Song Lan
7.1 Introduction 156
7.1.1 The Potential for Waste Heat Recovery 156
7.2 Modelling TEG Performance 163
7.3 The Role of the Heat Exchanger in TEG Design 165
7.4 Modelling a Thermoelectric Generator 166
7.4.1 Defining the Structure of TEG 167
7.4.2 Calculating Temperature Distributions 169
7.4.3 Thermal Resistance Network in a CV 170
7.5 Electrical-resistance Network of a TEG 175
7.6 Model Structure 176
7.7 Validation Strategy for Models 178
7.8 Using the Model to Optimize TEM Geometry 180
7.8.1 Geometric Factors 180
7.8.2 Influence of Geometric Parameters on
Maximum Power 181
7.8.3 Influence of Operating Environments on
Optimal Geometric Parameters 183
7.8.4 Three-dimensional Figures to Identify the
Optimal Geometry Parameters 183
7.9 Selecting and Evaluating Heat Exchange Designs
for TEG Applications 183
7.9.1 Identifying the Design Parameters of a
Plate Fin Heat Exchanger 183
7.9.2 Comparing Heat Exchange Architectures 189
7.10 An Example of a Family of Heat Exchangers 193
7.11 Observations on TEG Design 198
7.12 Concluding Remarks 199
Appendix A: Exhaust Gas Properties Employed
in the Simulation Model 200
Appendix B: Properties of the Simulated
Thermoelectric Module 201
Acknowledgements 201
References 202
Chapter 8 Electrodeposition of Thermoelectric Materials 204
A. J. Naylor, N. M. White and I. Nandhakumar
8.1 Introduction 204
8.1.1 Electrodeposition of Nanostructured Materials 204
Contents
xi
8.1.2 Recent Advances in the Electrodeposition of
Thermoelectric Materials 211
8.2 Experimental 215
8.3 Results and Discussion 217
8.3.1 Sodium Lignosulfonate as an Additive in the
Electrodeposition of Bismuth Telluride 217
8.3.2 Electrodeposition of n-type Copper-doped
Bismuth Tellurium Selenide 222
8.4 Conclusions 226
Acknowledgements 226
References 226
Chapter 9 Automotive Power Harvesting/Thermoelectric Applications 230
States Chiwanga, Richard Tuley, Placha,
Mark Robbins, Bob Gilchrist and Kevin Simpson
9.1 Why are Thermoelectric Devices Suitable for
Automotive Applications? 230
9.2 Automotive TEG Systems 232
9.3 Challenges/Trade-offs in Automotive TEGs 235
9.3.1 Thermoelectric Modules Packaging 235
9.3.2 TEG Hot and Cold Heat Exchangers 236
9.3.3 Exhaust Gas Flow Control (Valves and
Sensors) 240
9.3.4 TEG Overall Mechanical Packaging 241
9.3.5 TEG Electrical Output Control
Measurement and Control 244
9.4 Failure of Thermoelectric Modules in Automotive
Applications 244
9.4.1 Ceramic Failures 246
9.4.2 Pellet Failures 247
9.4.3 Interconnect and Joint Failures 247
9.4.4 Failure Modelling 247
9.4.5 Failure Summary 250
References 251
Subject Index 252
Thermal energy harvesting is predicted to become a global, billion-
pound market by 2020. This book provides a current perspective of
recent developments and trends within thermoelectric materials and
devices for power energy harvesting applications.
The book highlights the potential of thermoelectrics in the context of a
low carbon energy economy, and features in-depth coverage of a range
of different fabrication methods for thermoelectric materials. Topics
covered include layered and pseudo-layered materials, thermoelectric
oxides, nano- and micro-fabrication techniques, high-throughput
thermoelectric measurement techniques and power mining. This book
is ideal for researchers and industrialists in materials science.
RSC Energy b Environment Series
Editor-in-Chief: Laurence Peter, University of Bath, UK
Series Editors: Heinz Fret Lawrence Berkeley National Lab., USA
Roberto Rinaldi, Max Planck Institute for Coal Research, Germany
Tim S. Zhao, HKUST, Hong Kong, China
Energy lies at the heart of modern society, and it is critical that we make
informed choices of the methods by which we convert and manage
energy. The RSC Energy and Environment Series covers key themes
relating to energy conversion and storage as well as alternative fuel
technologies.
Front cover image © Shutterstock
ISBN 978-1-78262-333-6
|
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| id | DE-604.BV043558695 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:28:50Z |
| institution | BVB |
| isbn | 178262323X 9781782623236 |
| issn | 2044-0774 |
| language | English |
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| series2 | RSC energy and environment series |
| spelling | Thermoelectric materials and devices edited by Iris Nandhakumar, University of Southampton, UK; Neil M. White, University of Southampton, UK; Stephen Beeby, University of Southampton, UK Cambridge, UK Royal Society Of Chemistry [2017] © 2017 xi, 255 Seiten Illustrationen, Diagramme (überwiegend farbig) txt rdacontent n rdamedia nc rdacarrier RSC energy and environment series no. 17 2044-0774 Thermoelektrischer Effekt (DE-588)4223155-3 gnd rswk-swf Werkstoff (DE-588)4065579-9 gnd rswk-swf Thermoelektrizität (DE-588)4185148-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Thermoelektrizität (DE-588)4185148-1 s DE-604 Werkstoff (DE-588)4065579-9 s Thermoelektrischer Effekt (DE-588)4223155-3 s Nandhakumar, Iris (DE-588)1118629590 edt White, Neil M. (DE-588)1118633326 edt Beeby, Stephen (DE-588)1118634136 edt Erscheint auch als Online-Ausgabe, EPUB 978-1-78262-902-3 Erscheint auch als Online-Ausgabe, PDF 978-1-78262-404-2 RSC energy and environment series no. 17 (DE-604)BV036744686 17 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028973810&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028973810&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Thermoelectric materials and devices RSC energy and environment series Thermoelektrischer Effekt (DE-588)4223155-3 gnd Werkstoff (DE-588)4065579-9 gnd Thermoelektrizität (DE-588)4185148-1 gnd |
| subject_GND | (DE-588)4223155-3 (DE-588)4065579-9 (DE-588)4185148-1 (DE-588)4143413-4 |
| title | Thermoelectric materials and devices |
| title_auth | Thermoelectric materials and devices |
| title_exact_search | Thermoelectric materials and devices |
| title_full | Thermoelectric materials and devices edited by Iris Nandhakumar, University of Southampton, UK; Neil M. White, University of Southampton, UK; Stephen Beeby, University of Southampton, UK |
| title_fullStr | Thermoelectric materials and devices edited by Iris Nandhakumar, University of Southampton, UK; Neil M. White, University of Southampton, UK; Stephen Beeby, University of Southampton, UK |
| title_full_unstemmed | Thermoelectric materials and devices edited by Iris Nandhakumar, University of Southampton, UK; Neil M. White, University of Southampton, UK; Stephen Beeby, University of Southampton, UK |
| title_short | Thermoelectric materials and devices |
| title_sort | thermoelectric materials and devices |
| topic | Thermoelektrischer Effekt (DE-588)4223155-3 gnd Werkstoff (DE-588)4065579-9 gnd Thermoelektrizität (DE-588)4185148-1 gnd |
| topic_facet | Thermoelektrischer Effekt Werkstoff Thermoelektrizität Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028973810&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028973810&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV036744686 |
| work_keys_str_mv | AT nandhakumariris thermoelectricmaterialsanddevices AT whiteneilm thermoelectricmaterialsanddevices AT beebystephen thermoelectricmaterialsanddevices |