Molecular symmetry and group theory: approaches in spectroscopy and chemical reactions
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin ; Boston
De Gruyter
[2019]
|
| Schriftenreihe: | De Gruyter graduate
|
| Schlagworte: | |
| Online-Zugang: | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110634969&searchTitles=true Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | XIV, 464 Seiten Illustrationen, Diagramme 24 cm, 887 g |
| ISBN: | 9783110634969 |
Internformat
MARC
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| 100 | 1 | |a Maurya, R. C. |e Verfasser |0 (DE-588)1195475543 |4 aut | |
| 245 | 1 | 0 | |a Molecular symmetry and group theory |b approaches in spectroscopy and chemical reactions |c R.C. Maurya, J.M. Mir |
| 264 | 1 | |a Berlin ; Boston |b De Gruyter |c [2019] | |
| 264 | 4 | |c © 2019 | |
| 300 | |a XIV, 464 Seiten |b Illustrationen, Diagramme |c 24 cm, 887 g | ||
| 336 | |b txt |2 rdacontent | ||
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| 653 | |a Fachhochschul-/Hochschulausbildung | ||
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Datensatz im Suchindex
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|---|---|
| adam_text | CONTENTS
FOREWORD
*
VII
PREFACE
*
IX
1
SYMMETRY ELEMENTS
AND
SYMMETRY
OPERATIONS:
MOLECULAR
SYMMETRY
*
1
1.1
INTRODUCTION
*
1
1.2
MOLECULAR
SYMMETRY:
IN
NON-MATHEMATICAL
AND
GEOMETRICAL
SENSE
*
1
1.3
SYMMETRY
OPERATIONS
AND
SYMMETRY
ELEMENTS
*
2
1.4
NAMING
SYSTEMS
OF
NOTATION
FOR
SYMMETRY
OPERATIONS/
ELEMENTS
*
3
1.5
PROPER
AXIS
OF
SYMMETRY
*
4
1.6
PLANE
OF
SYMMETRY
*
9
1.7
CENTER
OF
SYMMETRY/INVERSION
CENTER
*
15
1.8
ROTATION-REFLECTION
AXIS
OR
AXIS
OF
IMPROPER
ROTATIONS
*
17
1.9
IDENTITY
*
26
EXERCISES
*
26
MULTIPLE
CHOICE
QUESTIONS
*
26
SHORT
ANSWER
TYPE
QUESTIONS
*
27
LONG
ANSWER
TYPE
QUESTIONS
*
27
2
APPLICATION
OF
GROUP
THEORY
TO
ELECTRONIC
SPECTROSCOPY
*
29
2.1
INTRODUCTION
*
29
2.2
ELECTRONIC
SPECTROSCOPY
*
29
2.2.1
ELECTRONIC
SPECTRA
OF
ORGANIC
COMPOUNDS
*
29
2.2.2
ALLOWED
AND
FORBIDDEN
TRANSITION:
PREDICTION
THROUGH
GROUP
THEORY
*
30
2.2.3
VIBRONIC
COUPLING
*
33
2.2.4
CHARGE
TRANSFER
SPECTRA
IN
SIMPLE
AND
COORDINATION
COMPOUNDS
*
45
2.2.5
ELECTRONIC
SPECTRA
OF
TRANSITION
METAL
COMPLEXES
*
49
2.2.5.1
DETERMINATION
OF
TTRMS
OR
TERM
SYMBOLS
*
49
2.2.5.2
ASSIGNMENT
OF
TERM
SYMBOLS
OF
DIFFERENT
ATOMS
*
51
2.2.5
3
TERMS
FOR
ATOMS
HAVING
MORE
THAN
ONE
ELECTRON
*
52
2.2.6
HUND
*
S
RULES:
DETERMINATION
OF
GROUND
STATE
TERMS
FOR
MANY
ELECTRON
ATOMS/IONS
*
57
2.2.7
HOLE
FORMULATION:
TERM
SYMBOLS
FOR
P
AND
P
6N
AND
F
AND
D
2 * * * * * * *
10
N
CONFIGURATIONS
*
60
2.2.8
SYMMETRY
SPECIES
OF
TERMS
*
60
2.2.9
SPLITTING
OF
TERMS:
STEP
TO
ARRIVE
TO
ORGEL
DIAGRAMS
*
62
2.2.10
HOW
TO
DECIDE
THE
GROUND
STATE
IN
GROUP
THEORETICAL
TERMS
AS
MULLIKEN
SYMBOLS
IN
CUBIC
FIELD?
*
62
2.2.10.1
TETRAHEDRAL
COMPLEXES
WITH
D
1
AND
D
9
ELECTRONIC
CONFIGURATIONS
*
65
2.2.10.2
OCTAHEDRAL
COMPLEXES
WITH
D
4
AND
D
6
ELECTRONIC
CONFIGURATIONS
*
66
2.2.10.3
OCTAHEDRAL
COMPLEXES
WITH
D
2
,
D
8
AND
T
D
COMPLEXES
WITH
D
2
ELECTRONIC
CONFIGURATIONS
*
69
2.2.10.4
OCTAHEDRAL
COMPLEXES
WITH
D
3
,
D
7
AND
T
D
COMPLEXES
WITH
D
2
,
D
3
*
D
7
,
D
8
ELECTRONIC
CONFIGURATIONS
-----
73
2.2.10.5
OCTAHEDRAL
COMPLEXES
WITH
D
5
ELECTRONIC
CONFIGURATION
*
79
2.3
EFFECT
OF
JAHN-TELLER
DISTORTION
ON
ELECTRONIC
SPECTRA
OF
COMPLEXES
*
80
2.4
CORRELATION
DIAGRAM:
ORDERING
OF
ENERGY
STATES
*
90
2.5
CORRELATION
DIAGRAM
AND
HOLE
FORMALISM
*
110
2.5.1
USES
OF
CORRELATION
DIAGRAMS
*
110
2.6
TANABE-SUGANO
CORRELATION
DIAGRAM
-----
111
2.7
VARIATION
IN
RACAH
PARAMETER
B:
NEPHELAUXETIC
SERIES
*
117
2.7.1
EVALUATION
OF
DQ,
B
AND
PARAMETERS
*
119
EXERCISES
*
139
MULTIPLE
CHOICE
QUESTIONS/FILL
IN
THE
BLANKS
-----
139
SHORT
ANSWER
TYPE
QUESTIONS
*
140
LONG
ANSWER
TYPE
QUESTIONS
*
141
3
MOLECULAR
SYMMETRY
AND
GROUP
THEORY
TO
VIBRATIONAL
SPECTROSCOPY
*
143
3.1
INTRODUCTION
*
143
3.2
GENERATION
OF
REDUCIBLE
REPRESENTATION
*
149
3.3
SYMMETRY
SELECTION
RULES
FOR
IR
AND
RAMAN
SPECTROSCOPY:
IDENTIFICATION
OF
IR
AND
RAMAN
ACTIVE
VIBRATIONS
*
202
3.4
COMPLEMENTARY
NATURE
OF
IR
AND
RAMAN
SPECTRA
*
207
3.5
THE
MUTUAL
EXCLUSION
PRINCIPLE/RULE
-----
208
3.6
POLARIZATION
OF
RAMAN
LINES
*
210
3.7
PREDICTION
OF
IR
AND
RAMAN
ACTIVE
MODES
IN
SOME
MOLECULES
OF
DIFFERENT
POINT
GROUPS
*
211
3.8
COMPLICATIONS
IN
IR
AND
RAMAN
SPECTRA
AND
DIFFICULTIES
IN
ASSIGNMENTS
*
310
3.8.1
OVERTONES,
COMBINATION
BAND,
HOT
BANDS
AND
FERMI
RESONANCE
*
310
3.8.2
OVERTONES
-----
311
3.8.3
3.8.4
3.8.5
3.8.6
3.9
3.10
3.10.1
3.10.2
3.10.3
3.11
3.11.1
3.12
3.13
3.14
3.15
4
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
4.9
4.10
4.11
4.11.1
4.11.2
4.11.3
4.11.4
METHOD
FOR
FINDING
OVERTONES
FOR
DEGENERATE
VIBRATIONAL
MODES
-----
312
COMBINATION
BANDS
*
319
HOT
BANDS
-----
323
FERMI
RESONANCE
*
323
ASCENT-DESCENT
OR
GROUP-SUBGROUP
IN
SYMMETRY:
INTERPRETATION
OF
SPECTRAL
DATA
*
325
IR
AND
RAMAN
SPECTRA
OF
LINEAR
MOLECULES
*
331
INSPECTION
METHOD
-----
333
SUBGROUP
METHOD
-----
335
INTEGRATION
METHOD
*
346
STRUCTURAL
DIAGNOSIS:
APPLICATION
OF
INFRARED
AND
RAMAN
SPECTRA
*
349
PREDICTING
/FITTING
STRUCTURE/GEOMETRY
OF
MOLECULE
*
350
PREDICTION
OF
COORDINATION
SITES
AND
LINKAGE
ISOMERISM
*
355
DENTICITY
ASSIGNMENT
FOR
ANIONIC
LIGANDS
*
359
GEOMETRICAL
ISOMERS:
DISTINCTION
-----
366
METAL
CARBONYLS:
STRUCTURAL
ELUCIDATION
-----
368
EXERCISES
-----
374
MULTIPLE
CHOICE
QUESTIONS/FILL
IN
THE
BLANK
*
374
SHORT
ANSWER
TYPE
QUESTIONS
*
375
LONG
ANSWER
TYPE
QUESTIONS
*
375
CHEMICAL
REACTIONS:
ORBITAL
SYMMETRY
RULES
*
377
INTRODUCTION
-----
377
CHEMICAL
REACTIONS:
SYMMETRY
RULES
*
378
INORGANIC/ORGANIC
REACTIONS:
SYMMETRY
CONSIDERATIONS
*
381
NUCLEOPHILIC
DISPLACEMENT
REACTIONS
*
394
BERRY
*
S
PSEUDOROTATION:
ORBITAL
SYMMETRY
CONTROL
*
396
CORRELATION
DIAGRAMS:
PREDICTION
OF
ORBITAL
SYMMETRY
ALLOWEDNESS
FOR
BERRY
*
S
PSEUDOROTATION
*
399
STABLE
SHAPE
OF
THE
MOLECULES:
SYMMETRY
RULES
*
400
SYMMETRY
CONTROLLED
PERICYCLIC
REACTIONS
*
403
CLASSES
OF
PERICYCLIC
REACTIONS
*
403
INTERPRETATION
OF
PERICYCLIC
REACTIONS:
DIFFERENT
APPROACHES
*
406
WOODWARD-HOFFMANN
APPROACH
*
407
SYMMETRY
ALLOWED
AND
SYMMETRY
FORBIDDEN
REACTIONS
IN
PERICYCLIC
REACTIONS
*
412
CONSERVATION
OF
ORBITAL
SYMMETRY
*
412
CONROTATORY
AND
DISROTATORY
WAYS
OF
MOVEMENT
IN
PERICYCLIC
REACTION
*
413
A,
7T
AND
U
ORBITALS
AND
ELECTRONS
*
415
4.11.5
4.12
COMPONENTS
IN
PERICYCLIC
REACTIONS
*
415
MECHANISTIC
INTERPRETATION
OF
SOME
PERICYCLIC
REACTIONS
WITH
SYMMETRY
PROPERTY
*
416
4.13
FRONTIER
MOLECULAR
ORBITAL
APPROACH:
INTERPRETATION
OF
PERICYCLIC
REACTIONS
*
428
4.14
WOODWARD
AND
HOFFMANN
*
S
RULES
AND
FMO
APPROACH:
ELECTROCYCLIC
REACTIONS
ON
THE
BASIS
OF
COMPONENTS
*
433
EXCERCISES
*
438
MULTIPLE
CHOICE
QUESTIONS/FILL
IN
THE
BLANK
*
438
SHORT
ANSWER
TYPE
QUESTIONS
*
439
LONG
ANSWER
TYPE
QUESTIONS
*
439
APPENDIX
I
*
441
APPENDIX
II
*
455
APPENDIX
III
*
457
BIBLIOGRAPHY
*
459
INDEX
*
461
|
| any_adam_object | 1 |
| author | Maurya, R. C. Mir, J. M. |
| author_GND | (DE-588)1195475543 (DE-588)1195475780 |
| author_facet | Maurya, R. C. Mir, J. M. |
| author_role | aut aut |
| author_sort | Maurya, R. C. |
| author_variant | r c m rc rcm j m m jm jmm |
| building | Verbundindex |
| bvnumber | BV046170453 |
| classification_rvk | VE 5700 |
| classification_tum | CHE 158f |
| ctrlnum | (OCoLC)1124792185 (DE-599)DNB1175228842 |
| dewey-full | 541.223 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.223 |
| dewey-search | 541.223 |
| dewey-sort | 3541.223 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV046170453 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T08:37:11Z |
| institution | BVB |
| institution_GND | (DE-588)10095502-2 |
| isbn | 9783110634969 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-031550226 |
| oclc_num | 1124792185 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-11 DE-83 DE-19 DE-BY-UBM |
| owner_facet | DE-91G DE-BY-TUM DE-11 DE-83 DE-19 DE-BY-UBM |
| physical | XIV, 464 Seiten Illustrationen, Diagramme 24 cm, 887 g |
| publishDate | 2019 |
| publishDateSearch | 2019 |
| publishDateSort | 2019 |
| publisher | De Gruyter |
| record_format | marc |
| series2 | De Gruyter graduate |
| spelling | Maurya, R. C. Verfasser (DE-588)1195475543 aut Molecular symmetry and group theory approaches in spectroscopy and chemical reactions R.C. Maurya, J.M. Mir Berlin ; Boston De Gruyter [2019] © 2019 XIV, 464 Seiten Illustrationen, Diagramme 24 cm, 887 g txt rdacontent n rdamedia nc rdacarrier De Gruyter graduate Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Molekülsymmetrie (DE-588)4170385-6 gnd rswk-swf Molekülspektroskopie (DE-588)4128850-6 gnd rswk-swf Gruppentheorie (DE-588)4072157-7 gnd rswk-swf Fachhochschul-/Hochschulausbildung Molekülsymmetrie Raman-Spektroskopie Spektroskopie Molekülsymmetrie (DE-588)4170385-6 s Gruppentheorie (DE-588)4072157-7 s Molekülspektroskopie (DE-588)4128850-6 s Chemische Reaktion (DE-588)4009853-9 s DE-604 Mir, J. M. Verfasser (DE-588)1195475780 aut Walter de Gruyter GmbH & Co. KG (DE-588)10095502-2 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-11-063503-4 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-063512-6 X:MVB http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110634969&searchTitles=true B:DE-101 application/pdf http://d-nb.info/1175228842/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031550226&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Maurya, R. C. Mir, J. M. Molecular symmetry and group theory approaches in spectroscopy and chemical reactions Chemische Reaktion (DE-588)4009853-9 gnd Molekülsymmetrie (DE-588)4170385-6 gnd Molekülspektroskopie (DE-588)4128850-6 gnd Gruppentheorie (DE-588)4072157-7 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4170385-6 (DE-588)4128850-6 (DE-588)4072157-7 |
| title | Molecular symmetry and group theory approaches in spectroscopy and chemical reactions |
| title_auth | Molecular symmetry and group theory approaches in spectroscopy and chemical reactions |
| title_exact_search | Molecular symmetry and group theory approaches in spectroscopy and chemical reactions |
| title_full | Molecular symmetry and group theory approaches in spectroscopy and chemical reactions R.C. Maurya, J.M. Mir |
| title_fullStr | Molecular symmetry and group theory approaches in spectroscopy and chemical reactions R.C. Maurya, J.M. Mir |
| title_full_unstemmed | Molecular symmetry and group theory approaches in spectroscopy and chemical reactions R.C. Maurya, J.M. Mir |
| title_short | Molecular symmetry and group theory |
| title_sort | molecular symmetry and group theory approaches in spectroscopy and chemical reactions |
| title_sub | approaches in spectroscopy and chemical reactions |
| topic | Chemische Reaktion (DE-588)4009853-9 gnd Molekülsymmetrie (DE-588)4170385-6 gnd Molekülspektroskopie (DE-588)4128850-6 gnd Gruppentheorie (DE-588)4072157-7 gnd |
| topic_facet | Chemische Reaktion Molekülsymmetrie Molekülspektroskopie Gruppentheorie |
| url | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110634969&searchTitles=true http://d-nb.info/1175228842/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=031550226&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mauryarc molecularsymmetryandgrouptheoryapproachesinspectroscopyandchemicalreactions AT mirjm molecularsymmetryandgrouptheoryapproachesinspectroscopyandchemicalreactions AT walterdegruytergmbhcokg molecularsymmetryandgrouptheoryapproachesinspectroscopyandchemicalreactions |
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