Muon spin spectroscopy: methods and applications in chemistry and materials science
Gespeichert in:
Hauptverfasser: | , , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Weinheim, Germany
Wiley-VCH
[2024]
|
Schlagworte: | |
Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34236-5/ Inhaltsverzeichnis Inhaltsverzeichnis |
Beschreibung: | x, 245 Seiten Illustrationen, Diagramme 25 cm, 612 g |
ISBN: | 9783527342365 3527342362 |
Internformat
MARC
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015 | |a 23,N41 |2 dnb | ||
015 | |a 24,A21 |2 dnb | ||
016 | 7 | |a 1305294475 |2 DE-101 | |
020 | |a 9783527342365 |c Festeinband : circa EUR 129.00 (DE) (freier Preis), circa EUR 132.70 (AT) (freier Preis) |9 978-3-527-34236-5 | ||
020 | |a 3527342362 |9 3-527-34236-2 | ||
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035 | |a (OCoLC)1428439426 | ||
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100 | 1 | |a Fleming, Donald G. |e Verfasser |0 (DE-588)1325326798 |4 aut | |
245 | 1 | 0 | |a Muon spin spectroscopy |b methods and applications in chemistry and materials science |c Donald G. Fleming, Iain McKenzie, Paul W. Percival |
264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2024] | |
300 | |a x, 245 Seiten |b Illustrationen, Diagramme |c 25 cm, 612 g | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
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653 | |a Chemie | ||
653 | |a Chemistry | ||
653 | |a Materials Science | ||
653 | |a Materialwissenschaften | ||
653 | |a Particle Physics | ||
653 | |a Physics | ||
653 | |a Physik | ||
653 | |a Soft Matter | ||
653 | |a Spectroscopy | ||
653 | |a Spektroskopie | ||
653 | |a Teilchenphysik | ||
653 | |a CH15: Spektroskopie | ||
653 | |a MSG0: Soft Matter | ||
653 | |a PH21: Teilchenphysik | ||
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700 | 1 | |a McKenzie, Iain |e Verfasser |0 (DE-588)1275946828 |4 aut | |
700 | 1 | |a Percival, Paul W. |e Verfasser |0 (DE-588)1325327263 |4 aut | |
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776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |z 978-3-527-80605-8 |
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Datensatz im Suchindex
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adam_text |
CONTENTS
PREFACE
IX
1
1.1
1.2
1.3
PERSPECTIVE
AND
INTRODUCTORY
REMARKS
1
WHAT
DO
MUONS
BRING
TO
CHEMISTRY?
1
MUON
FACILITIES
AND
BACKGROUND
TO
EXPERIMENTAL
MUON
TECHNIQUES
4
THE
DEVELOPMENT
OF
MUONIUM CHEMISTRY
5
REFERENCES
8
2
2.1
2.2
2.3
2.4
2.5
2.5.1
2.5.2
2.5.3
2.6
2.6.1
2.6.2
2.7
2.7.1
2.7.2
2.7.3
2.8
2.9
2.10
MUON
BEAMS
AND
SPIN
SPECTROSCOPY
11
SPIN-POLARIZED
MUON
BEAMS
11
MUON
DECAY
AND
DETECTION
OF
ITS
SPIN
POLARIZATION
13
CONTINUOUS
VERSUS
PULSED
MUON
BEAMS
14
USR
SPECTROMETERS
16
SPECTROSCOPY
OF
MUONS
IN
DIAMAGNETIC
ENVIRONMENTS
18
DIAMAGNETIC
MUONS
IN
A
LONGITUDINAL
FIELD
18
DIAMAGNETIC
MUONS
IN
A
TRANSVERSE
FIELD
19
DIAMAGNETIC
MUONS
IN
ZERO
MAGNETIC
FIELD
22
SPECTROSCOPY
OF
MUONIUM
23
MUONIUM
IN
A
TRANSVERSE
FIELD
24
MUONIUM
IN A
LONGITUDINAL
FIELD
26
TF-PSR
OF
MUONIATED
RADICALS
28
MUONIATED
RADICALS
IN
ISOTROPIC
ENVIRONMENTS
28
MUONIATED
RADICALS
IN
ANISOTROPIC
ENVIRONMENTS
32
POLARIZATION
TRANSFER
FROM
PRECURSOR
TO
RADICAL
33
AVOIDED
LEVEL-CROSSING
RESONANCE
OF
MUONIATED
RADICALS
34
RF
MUON
SPIN
RESONANCE
OF
MUONIATED
RADICALS
39
LONGITUDINAL-FIELD
REPOLARIZATION
STUDIES
OF
MUONIATED
RADICALS
40
REFERENCES
43
3
3.1
3.2
3.3
3.4
FORMATION
OF
CHEMICAL
STATES
INCORPORATING
MUONS
45
UT
CHARGE
EXCHANGE
AND
MU
FORMATION
IN
THE
GAS
PHASE
45
MU
FORMATION
AND
TRACK
EFFECTS
IN
DENSE
MEDIA
49
CHEMICAL
PROCESSES
FORMING
MUONIATED
MOLECULES
53
U
CAPTURE
AND
MUONIC
ATOMS
60
REFERENCES
61
4
4.1
4.2
4.3
CHEMICAL
REACTIVITY
AND
DYNAMICS
IN
THE
GAS
PHASE
65
MUON
SPIN
SPECTROSCOPY
APPLIED
TO
CHEMICAL
KINETICS
65
POTENTIAL
ENERGY
SURFACES
AND
QUANTUM
MASS
EFFECTS
67
THEORETICAL
BACKGROUND
TO
RATE
CALCULATIONS
FOR
BIMOLECULAR
REACTIONS
71
4.4
4.5
4.6
4.7
4.8
EARLY
EXPERIMENTAL
STUDIES:
MU
+
HALOGENS
73
H
ATOM
ABSTRACTION
REACTIONS
75
STATE-SELECTED
REACTIVITY:
MU
+
H2(V
=
1)
77
ADDITION
REACTIONS
79
A
NEW
TYPE
OF
CHEMICAL
BOND:
BR
-
MU
-
BR
VIBRATIONAL
BONDING
84
REFERENCES
86
5
MUONIUM
CHEMISTRY
AND
CHEMICAL
KINETICS
IN
CONDENSED
PHASES
89
5.1
5.2
5.3
5.4
5.5
5.6
5.7
SETTING
THE
STAGE:
CHEMICAL
REACTIVITY
IN
LIQUIDS
VS.
GASES
89
MUONIUM
DIFFUSION
IN
WATER
90
PRESSURE
AND
DENSITY
DEPENDENCE
92
MUON
SPIN
DEPHASING
DURING
REACTION
96
ADDITIONAL
EFFECTS
ON
MU
AND
H
KINETICS
IN
THE
LIQUID
PHASE
99
CAN
MU
REACT
BY
A
DIFFERENT
MECHANISM
TO
H?
101
A
CASE
STUDY
OF
A
COMPLEX
REACTION
SYSTEM:
MU
+
H
2
O
2
102
REFERENCES
105
6
6.1
6.1.1
6.1.2
6.2
6.2.1
6.2.2
6.2.3
6.3
6.3.1
6.3.2
6.3.3
6.3.4
6.4
6.4.1
6.4.2
6.4.3
6.5
6.6
6.6.1
6.6.2
MUONIATED
FREE
RADICALS
107
ISOTROPIC
HYPERFINE
COUPLING
107
ISOTROPIC
HYPERFINE
COUPLING
CONSTANTS
OF
A
NUCLEI
108
ISOTROPIC
HYPERFINE
COUPLING
CONSTANTS
OF
0
NUCLEI
110
ISOTOPE
EFFECTS
ON
MUONIATED
RADICALS
111
BOND
LENGTH
111
HYPERFINE
CONSTANTS
113
CONFORMATIONAL
PREFERENCE
114
INTRAMOLECULAR
MOTION
OF
MUONIATED
RADICALS
116
THE
MUONIATED
TERT-BUTYL
RADICAL
116
METHYL
RADICALS
116
OTHER
ALKYL
RADICALS
119
MU
ADDUCTS
OF
CARBONYLS
119
REORIENTATIONAL
DYNAMICS
OF
MUONIATED
RADICALS
120
DIPOLAR
HYPERFINE
COUPLING
CONSTANTS
120
EFFECT
OF
HYPERFINE
ANISOTROPY
ON
A1
AND
AO
RESONANCES
124
ANISOTROPIC
MOTION
OF
MUONIATED
RADICALS
IN
SOLIDS
128
SOLVENT
EFFECTS
ON
HYPERFINE
COUPLING
CONSTANTS
129
KINETICS
OF
REACTIONS
OF
MUONIATED
RADICALS
131
MEASURING
CHEMICAL
REACTION
RATES
USING
TF-USR
131
MEASURING
CHEMICAL
REACTION
RATES
USING
ALC-USR
132
6.6.3
MEASURING
CHEMICAL
REACTION
RATES
FROM
THE
TRANSFER
OF
POLARIZATION
FROM
A
PRIMARY
TO
A
SECONDARY
RADICAL
134
6.7
6.7.1
6.7.2
6.7.3
6.7.4
CHARACTERIZATION
OF
NOVEL
RADICALS BY
MUON
SPIN
SPECTROSCOPY
136
RADICALS
CONTAINING
SI
OR
GE
136
RADICALS
CONTAININGP
137
RADICALS
CONTAINING
A
METAL
ATOM
138
MUONIATED
RADICALS
CONTAINING
NO
OTHER
NUCLEAR
MOMENTS
139
REFERENCES
140
7
7.1
7.2
7.3
SPIN
RELAXATION
STUDIES
143
PROBING
SPIN
RELAXATION
WITH
MUONS
143
MOLECULAR
DYNAMICS
FROM
SPIN
RELAXATION
143
MUON
SPIN
RELAXATION
STUDIES
OF
AQUEOUS
SOLUTIONS
OF
MANGANESE(II)
IONS
145
7.4
7.5
7.6
MUONIUM
SPIN
EXCHANGE
WITH
PARAMAGNETIC
SPECIES
147
SPIN
RELAXATION
IN
MUONIATED
RADICALS
150
MUON
SPIN
RELAXATION
DURING
CHEMICAL
REACTION
153
REFERENCES
155
8
8.1
8.2
8.3
8.4
8.5
ASPECTS
OF
MATERIALS
CHEMISTRY
157
MUONIUM
IN
CONFINED
SPACES
157
MUONIUM
AND
MUONIATED
RADICALS
IN
FULLERENES
160
MUONIUM
AND
RADICALS
IN
CLATHRATES
164
MUONIATED
RADICALS
IN
ZEOLITES
167
MUONIUM
AND
RADICALS
ON
SURFACES
172
REFERENCES
178
9
9.1
9.2
9.2.1
9.2.2
9.3
9.4
9.4.1
9.4.2
9.5
9.5.1
9.5.2
9.6
9.6.1
9.6.2
9.7
SOFT
MATTER,
ORGANIC
MATERIALS
AND
BIOLOGICAL
SYSTEMS
181
SOFT
MATTER
181
THERMOTROPIC
LIQUID
CRYSTALS
181
ORIENTATIONAL
ORDERING
OF
MBBA
184
FLUCTUATIONS
OF
5CB
187
COSURFACTANTS
IN
BILAYERS
AND
MICELLES
190
POLYMERS
195
DYNAMICS
IN
NON-CONJUGATED
POLYMERS
195
ELECTRON
CONDUCTION
IN
CONJUGATED
POLYMERS
199
ORGANIC
MATERIALS
202
MAGNETIC
ORDERING
IN
ORGANIC
MATERIALS
202
LOCALIZED
DEFECTS
IN
ORGANIC
SEMICONDUCTORS
204
BIOLOGICAL
SYSTEMS
207
USR
OF
DNA
AND
ITS
CONSTITUENTS
207
MUONIATED
RADICALS
FORMED
FROM
PROTEINS
209
CONCLUDING
THOUGHTS
212
REFERENCES
212
10
FUTURE
DEVELOPMENTS
AND
OUTLOOK
215
10.1
LIGHT
MASS
AND
ISOTOPE
EFFECTS
215
10.2
MUON
SPIN
SPECTROSCOPY:
ADVANTAGES
AND
LIMITATIONS
216
10.3
NEW
METHODOLOGIES
217
10.3.1
TRANSIENT
TARGETS
217
10.3.2
OPTICAL
SPECTROSCOPY
217
10.3.3
SPIN
MANIPULATION
218
10.4
GOING
BEYOND
MUON
SPIN SPECTROSCOPY
218
10.4.1
MUON
TOMOGRAPHY
218
10.4.2
MUON-INDUCED
X-RAY
EMISSION
219
10.5
THE
OUTLOOK
FOR
MUON
SCIENCE
219
10.6
CONCLUSIONS
220
REFERENCES
220
APPENDIX
A
DERIVATION
OF
MUON
POLARIZATION
EXPRESSIONS
223
A.1
POLARIZATION
IN
A
USR
EXPERIMENT
223
A.2
DIAMAGNETIC
MUONS
IN
A
LONGITUDINAL
FIELD
223
A.3
DIAMAGNETIC
MUONS
IN
A
TRANSVERSE
FIELD
224
A.4
MUONIUM
IN
A
TRANSVERSE
FIELD
225
A.5
MUONIUM
IN
A
LONGITUDINAL
FIELD
226
A.6
MUONIATED
RADICALS
IN
ISOTROPIC
ENVIRONMENTS
227
A.7
MUONIATED
RADICALS
IN
HIGH
TRANSVERSE
FIELDS
228
A.8
MUONIATED
RADICALS
IN
LONGITUDINAL
FIELDS
OUTSIDE
LEVEL
CROSSINGS
229
A.9
AVOIDED
LEVEL-CROSSING
MUON
SPIN
RESONANCE
IN
ISOTROPIC
ENVIRONMENTS
230
A.10
AVOIDED
LEVEL-CROSSING
MUON
SPIN
RESONANCE
IN
ANISOTROPIC
ENVIRONMENTS
232
REFERENCES
234
APPENDIX
B
MUONIUM
RATE
CONSTANTS
FOR
REACTIONS
IN
SOLUTION
235
REFERENCES
239
INDEX
241 |
any_adam_object | 1 |
author | Fleming, Donald G. McKenzie, Iain Percival, Paul W. |
author_GND | (DE-588)1325326798 (DE-588)1275946828 (DE-588)1325327263 |
author_facet | Fleming, Donald G. McKenzie, Iain Percival, Paul W. |
author_role | aut aut aut |
author_sort | Fleming, Donald G. |
author_variant | d g f dg dgf i m im p w p pw pwp |
building | Verbundindex |
bvnumber | BV049784193 |
classification_rvk | UO 6330 |
ctrlnum | (OCoLC)1428439426 (DE-599)DNB1305294475 |
discipline | Physik |
format | Book |
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id | DE-604.BV049784193 |
illustrated | Illustrated |
indexdate | 2024-10-15T10:04:04Z |
institution | BVB |
institution_GND | (DE-588)16179388-5 |
isbn | 9783527342365 3527342362 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-035125114 |
oclc_num | 1428439426 |
open_access_boolean | |
owner | DE-703 |
owner_facet | DE-703 |
physical | x, 245 Seiten Illustrationen, Diagramme 25 cm, 612 g |
publishDate | 2024 |
publishDateSearch | 2024 |
publishDateSort | 2024 |
publisher | Wiley-VCH |
record_format | marc |
spelling | Fleming, Donald G. Verfasser (DE-588)1325326798 aut Muon spin spectroscopy methods and applications in chemistry and materials science Donald G. Fleming, Iain McKenzie, Paul W. Percival Weinheim, Germany Wiley-VCH [2024] x, 245 Seiten Illustrationen, Diagramme 25 cm, 612 g txt rdacontent n rdamedia nc rdacarrier Myonspinresonanz (DE-588)4312229-2 gnd rswk-swf Myon (DE-588)4170940-8 gnd rswk-swf Chemie Chemistry Materials Science Materialwissenschaften Particle Physics Physics Physik Soft Matter Spectroscopy Spektroskopie Teilchenphysik CH15: Spektroskopie MSG0: Soft Matter PH21: Teilchenphysik Myon (DE-588)4170940-8 s DE-604 Myonspinresonanz (DE-588)4312229-2 s McKenzie, Iain Verfasser (DE-588)1275946828 aut Percival, Paul W. Verfasser (DE-588)1325327263 aut Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-80608-9 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-80606-5 Erscheint auch als Online-Ausgabe 978-3-527-80605-8 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34236-5/ B:DE-101 application/pdf https://d-nb.info/1305294475/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=035125114&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p dnb 20240515 DE-101 https://d-nb.info/provenance/plan#dnb |
spellingShingle | Fleming, Donald G. McKenzie, Iain Percival, Paul W. Muon spin spectroscopy methods and applications in chemistry and materials science Myonspinresonanz (DE-588)4312229-2 gnd Myon (DE-588)4170940-8 gnd |
subject_GND | (DE-588)4312229-2 (DE-588)4170940-8 |
title | Muon spin spectroscopy methods and applications in chemistry and materials science |
title_auth | Muon spin spectroscopy methods and applications in chemistry and materials science |
title_exact_search | Muon spin spectroscopy methods and applications in chemistry and materials science |
title_full | Muon spin spectroscopy methods and applications in chemistry and materials science Donald G. Fleming, Iain McKenzie, Paul W. Percival |
title_fullStr | Muon spin spectroscopy methods and applications in chemistry and materials science Donald G. Fleming, Iain McKenzie, Paul W. Percival |
title_full_unstemmed | Muon spin spectroscopy methods and applications in chemistry and materials science Donald G. Fleming, Iain McKenzie, Paul W. Percival |
title_short | Muon spin spectroscopy |
title_sort | muon spin spectroscopy methods and applications in chemistry and materials science |
title_sub | methods and applications in chemistry and materials science |
topic | Myonspinresonanz (DE-588)4312229-2 gnd Myon (DE-588)4170940-8 gnd |
topic_facet | Myonspinresonanz Myon |
url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-34236-5/ https://d-nb.info/1305294475/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=035125114&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT flemingdonaldg muonspinspectroscopymethodsandapplicationsinchemistryandmaterialsscience AT mckenzieiain muonspinspectroscopymethodsandapplicationsinchemistryandmaterialsscience AT percivalpaulw muonspinspectroscopymethodsandapplicationsinchemistryandmaterialsscience AT wileyvch muonspinspectroscopymethodsandapplicationsinchemistryandmaterialsscience |
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