Kinetic studies of mixed gas hydrates:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 174, XXIII S. Ill., graph. Darst. |
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| 245 | 1 | 0 | |a Kinetic studies of mixed gas hydrates |c von Manja Luzi |
| 264 | 1 | |c 2012 | |
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Datensatz im Suchindex
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| adam_text | IMAGE 1
TABLE OF CONTENTS
1. INTRODUCTION 1
1.1. MOTIVATION 1
1.2. STATE O F THE ART IN HYDRATE FORMATION - THEORETICAL APPROACHES AND
EXPERIMENTAL METHODS 2 1.3. OUTLINE O F THE THESIS 4
2. OVERVIEW OF CLATHRATE HYDRATES 5
2.1. HYDRATE CRYSTAL STRUCTURES 5
2.2. NATURAL GAS HYDRATES 10
2.3. THERMODYNAMIC PROPERTIES 14
2.4. KINETICS O F HYDRATE FORMATION 20
2.4.1. HYDRATE FORMATION FROM WATER 22
2.4.2. HYDRATE FORMATION FROM ICE 23
2.4.3. MODEL DESCRIPTION FOR THE FORMATION O F GAS HYDRATES FROM ICE 24
3. EXPERIMENTAL METHODS 3 3
3.1. GAS HYDRATE SYNTHESIS 33
3.2. EXPERIMENTAL TECHNIQUES AND SETUPS 35
3.2.1. RAMAN SPECTROSCOPY 35
3.2.1.1. BASIC PRINCIPLES O F RAMAN SPECTROSCOPY 35
3.2.1.2. RAMAN SPECTROSCOPY O F GAS HYDRATES 39
3.2.1.3. EXPERIMENTAL SETUP 42
3.2.2. X-RAY DIFFRACTION 45
3.2.2.1. BASIC PRINCIPLES O F X-RAY DIFFRACTION 45
3.2.2.2. X-RAY DIFFRACTION O F GAS HYDRATES 52
3.2.2.3. EXPERIMENTAL SETUP 52
3.2.3. N M R SPECTROSCOPY 60
3.2.3.1. BASIC PRINCIPLES O F N M R SPECTROSCOPY 60
3.2.3.2. N M R SPECTROSCOPY O F GAS HYDRATES 62
3.2.4. DIFFERENTIAL SCANNING CALORIMETRY 65
3.2.4.1. BASIC PRINCIPLES O F DIFFERENTIAL SCANNING CALORIMETRY 65
3.2.4.2. DIFFERENTIAL SCANNING CALORIMETRY O F GAS HYDRATES 66
4. CHARACTERIZATION OF MIXED GAS HYDRATES 69
4.1. RESULTS FROM L3 C N M R SPECTROSCOPY 69
4.1.1. PEAK ASSIGNMENT 69
4.1.2. QUANTITATIVE RESULTS 74
4.2. RESULTS FROM RAMAN SPECTROSCOPY 75
4.2.1. PEAK ASSIGNMENT 75
4.2.2. QUANTITATIVE RESULTS 84
4.3. RESULTS FROM X-RAY DIFFRACTION 87
4.3.1. POWDER X-RAY DIFFRACTION 87
4.3.2. SINGLE CRYSTAL X-RAY DIFFRACTION 92
4.4. RESULTS FOR TERNARY METHANE + NEO-PENTANE + ISO-PENTANE HYDRATE 94
4.5. SUMMARY 97
5. HYDRATE PHASE EQUILIBRIUM MEASUREMENTS 99
5.1. PHASE EQUILIBRIUM DATA 99
5.2. INSIGHTS FROM IN SITU DSC EXPERIMENTS 104
6. KINETIC PROPERTIES OF MIXED GAS HYDRATES 109
6.1. RESULTS FROM L3 C N M R QUENCH EXPERIMENTS FOR SLL HYDRATES 109
6.2. RESULTS FROM IN SITU RAMAN EXPERIMENTS FOR SLL HYDRATES 116
6.3. RESULTS FROM IN SITU XRD EXPERIMENTS FOR SLL HYDRATES 125
6.3.1. RESULTS FROM IN SITU XRD EXPERIMENTS RELATED TO PRESSURE 126
6.3.2. RESULTS FROM IN SITU XRD EXPERIMENTS RELATED TO THE GUEST
MOLECULE 147
6.3.3. CONCLUSIONS FOR IN SITU XRD EXPERIMENTS 151
X V
HTTP://D-NB.INFO/1025062779
IMAGE 2
6.4. RESULTS FROM IN SITU RAMAN AND XRD EXPERIMENTS FOR METHANE +
ISO-PENTANE
HYDRATE 155
6.5. SUMMARY 158
7. SUMMARY AND CONCLUSIONS 161
8. REFERENCES 165
A APPENDIX I
A. I: CHEMICAL SHIFTS FOR ISO-BUTANE AND NEO-PENTANE OBTAINED FROM
LITERATURE II
A.2: X-RAY DIFFRACTION PATTERNS O F BINARY STRUCTURE II HYDRATES ILL
A.3: X-RAY DIFFRACTION PATTERN O F METHANE + ISO-BUTANE + N-BUTANE
HYDRATE VII
A.4: FIT O F HYDRATE FORMATION DATA OBTAINED FROM THE IN SITU XRD
EXPERIMENTS WITH RESPECT TO THE AVRAMI AND THE LEVENSPIEL MODEL VIII
A.5: PHASE DIAGRAM FOR STRUCTURE I METHANE HYDRATE AND STRUCTURE H
METHANE + ISO-PENTANE HYDRATE XII
A.6: LIST O F FIGURES XIII
A. 7: LIST O F TABLES XIX
XVI
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| language | English |
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| physical | XVI, 174, XXIII S. Ill., graph. Darst. |
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| spelling | Luzi, Manja Verfasser aut Kinetic studies of mixed gas hydrates von Manja Luzi 2012 XVI, 174, XXIII S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Potsdam, Univ., Diss., 2012 Gashydrate (DE-588)4282527-1 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Gashydrate (DE-588)4282527-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025157620&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Luzi, Manja Kinetic studies of mixed gas hydrates Gashydrate (DE-588)4282527-1 gnd |
| subject_GND | (DE-588)4282527-1 (DE-588)4113937-9 |
| title | Kinetic studies of mixed gas hydrates |
| title_auth | Kinetic studies of mixed gas hydrates |
| title_exact_search | Kinetic studies of mixed gas hydrates |
| title_full | Kinetic studies of mixed gas hydrates von Manja Luzi |
| title_fullStr | Kinetic studies of mixed gas hydrates von Manja Luzi |
| title_full_unstemmed | Kinetic studies of mixed gas hydrates von Manja Luzi |
| title_short | Kinetic studies of mixed gas hydrates |
| title_sort | kinetic studies of mixed gas hydrates |
| topic | Gashydrate (DE-588)4282527-1 gnd |
| topic_facet | Gashydrate Hochschulschrift |
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