Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online-Zugang: | Volltext Inhaltsverzeichnis |
| Beschreibung: | 244 S. Ill., graph. Darst. |
Internformat
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| 246 | 1 | 3 | |a Donor-Brücke-Akzeptor Systeme mit variierenden Brückeneinheiten zur Untersuchung von intramolekularen und intermolekularen Elektronentransferprozessen |
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Datensatz im Suchindex
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| adam_text | DONOR-BRIDGE-ACCEPTOR SYSTEMS
WITH VARYING BRIDGE UNITS FOR THE INVESTIGATION OF
INTRAMOLECULAR AND INTERMOLECULAR ELECTRON TRANSFER PROCESSES
DISSERTATION ZUR ERLANGUNG DES
NATURWISSENSCHAFTLICHEN DOKTORGRADES
DER JULIUS-MAXIMILIANS-UNIVERSITAT WURZBURG
VORGELEGT VON
CONRAD KAISER
AUS MILTENBERG
WURZBURG 2014
HTTP://D-NB.INFO/1052956599
0 INTRAMOLECULAR ELECTRON TRANSFER VIA ENERGETICALLY DIFFERENT
BRIDGE UNITS IN FERROCENE-HVDROAUINONE DERIVATIVE-GOLD MODEL
SYSTEMS IN A MONOLAYER ENVIRONMENT
1 INTRODUCTION 6
2 PROJECT AIM 10
3 THEORETICAL SECTION 14
3.1 FORMATION OF MONOLAYERS 14
3.2 SURFACE COVERAGE DETERMINATION BY CYCLIC
VOLTAMMETRY 17
3.3 CHARGE TRANSFER RATE ACQUISITION BY IMPEDANCE
SPECTROSCOPY 19
4 RESULTS AND DISCUSSION 24
4.1 MOLECULES 24
4.1.1 RETROSYNTHETIC SCHEMES OF MOLECULES A, B AND C 24
4.1.2 SYNTHESIS OF FERROCENE COMPOUND F3 26
4.1.3 SYNTHESIS OF DIBROMIDE PRECURSORS OF A; B AND C 27
4.1.4 SYNTHESIS OF A, B AND C 29
4.1.5 CYCLIC VOLTAMMETRY 30
4.2 MONOLAYERS 33
4.2.1 PREPARATION CONDITIONS 33
4.2.2 MEASUREMENT CONDITIONS 38
4.2.3 ADAPTED PROTOCOL FOR IMPEDANCE MEASUREMENT
ANALYSIS 44
4.2.4 IMPEDANCE MEASUREMENT PARAMETERS 49
4.2.5 ELECTROCHEMICAL CHARACTERIZATION TEST 51
4.2.6 ELECTROCHEMICAL CHARACTERIZATION 55
4
5 SUMMARY AND CONCLUSION 73
6 EXPERIMENTAL SECTION 76
6.1 PREPARATIVE AND ANALYTICAL METHODS 76
6.2 SYNTHESIS 79
6.2.1 SYNTHESIS OF FERROCENE COMPOUND F3 79
6.2.2 SYNTHESIS OF DIBROMIDE PRECURSOR OF A 82
6.2.3 SYNTHESIS OF DIBROMIDE PRECURSOR OF B 83
6.2.4 SYNTHESIS OF DIBROMIDE PRECURSOR OF C 85
6.2.5 SYNTHESIS OF A 86
6.2.6 SYNTHESIS OF B 90
6.2.7 SYNTHESIS OF C 94
7 LITERATURE 98
8 STRUCTURAL FORMULA TABLE 106
5
|
| any_adam_object | 1 |
| author | Kaiser, Conrad |
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| bvnumber | BV041946463 |
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| collection | ebook |
| ctrlnum | (OCoLC)882511594 (DE-599)BVBBV041946463 |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| language | English |
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| physical | 244 S. Ill., graph. Darst. |
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| spelling | Kaiser, Conrad Verfasser (DE-588)1052832598 aut Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes von Conrad Kaiser Donor-Brücke-Akzeptor Systeme mit variierenden Brückeneinheiten zur Untersuchung von intramolekularen und intermolekularen Elektronentransferprozessen 2014 244 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Würzburg, Univ., Diss., 2014 Impedanzspektroskopie (DE-588)4161400-8 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 gnd rswk-swf Laserspektroskopie (DE-588)4034620-1 gnd rswk-swf Monoschicht (DE-588)4250307-3 gnd rswk-swf Femtosekundenspektroskopie (DE-588)4276916-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Elektronentransfer (DE-588)4151907-3 s Femtosekundenspektroskopie (DE-588)4276916-4 s Impedanzspektroskopie (DE-588)4161400-8 s Laserspektroskopie (DE-588)4034620-1 s Monoschicht (DE-588)4250307-3 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:20-opus-97614 https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-97614 Resolving-System kostenfrei Volltext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027389531&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kaiser, Conrad Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes Impedanzspektroskopie (DE-588)4161400-8 gnd Elektronentransfer (DE-588)4151907-3 gnd Laserspektroskopie (DE-588)4034620-1 gnd Monoschicht (DE-588)4250307-3 gnd Femtosekundenspektroskopie (DE-588)4276916-4 gnd |
| subject_GND | (DE-588)4161400-8 (DE-588)4151907-3 (DE-588)4034620-1 (DE-588)4250307-3 (DE-588)4276916-4 (DE-588)4113937-9 |
| title | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes |
| title_alt | Donor-Brücke-Akzeptor Systeme mit variierenden Brückeneinheiten zur Untersuchung von intramolekularen und intermolekularen Elektronentransferprozessen |
| title_auth | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes |
| title_exact_search | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes |
| title_full | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes von Conrad Kaiser |
| title_fullStr | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes von Conrad Kaiser |
| title_full_unstemmed | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes von Conrad Kaiser |
| title_short | Donor-Bridge-Acceptor Systems with Varying Bridge Units for the Investigation of Intramolecular and Intermolecular Electron Transfer Processes |
| title_sort | donor bridge acceptor systems with varying bridge units for the investigation of intramolecular and intermolecular electron transfer processes |
| topic | Impedanzspektroskopie (DE-588)4161400-8 gnd Elektronentransfer (DE-588)4151907-3 gnd Laserspektroskopie (DE-588)4034620-1 gnd Monoschicht (DE-588)4250307-3 gnd Femtosekundenspektroskopie (DE-588)4276916-4 gnd |
| topic_facet | Impedanzspektroskopie Elektronentransfer Laserspektroskopie Monoschicht Femtosekundenspektroskopie Hochschulschrift |
| url | https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-97614 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027389531&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT kaiserconrad donorbridgeacceptorsystemswithvaryingbridgeunitsfortheinvestigationofintramolecularandintermolecularelectrontransferprocesses AT kaiserconrad donorbruckeakzeptorsystememitvariierendenbruckeneinheitenzuruntersuchungvonintramolekularenundintermolekularenelektronentransferprozessen |