Cyclic distannenes: synthesis and characterization of intramolecular alkene homologs of tin
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2014
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | IV, 203 S. graph. Darst. |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV041918382 | ||
| 003 | DE-604 | ||
| 005 | 00000000000000.0 | ||
| 007 | t | ||
| 008 | 140616s2014 d||| m||| 00||| eng d | ||
| 015 | |a 14,H05 |2 dnb | ||
| 016 | 7 | |a 1049715284 |2 DE-101 | |
| 035 | |a (OCoLC)880390658 | ||
| 035 | |a (DE-599)DNB1049715284 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-188 |a DE-29T | ||
| 082 | 0 | |a 547.05686 |2 22/ger | |
| 084 | |a 540 |2 sdnb | ||
| 100 | 1 | |a Henning, Jens |d 1985- |e Verfasser |0 (DE-588)1048483452 |4 aut | |
| 245 | 1 | 0 | |a Cyclic distannenes |b synthesis and characterization of intramolecular alkene homologs of tin |c vorgelegt von Jens Henning |
| 264 | 1 | |c 2014 | |
| 300 | |a IV, 203 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Tübingen, Univ., Diss., 2014 | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027361952&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-027361952 | ||
Datensatz im Suchindex
| _version_ | 1804152285665689600 |
|---|---|
| adam_text | CONTENTS
CONTENTS
1 INTRODUCTION 1
1.1 PIONEER WORK 1
1.2 MULTIPLE BONDING MODELS OF GROUP 14 ELEMENTS 2
1.3 ADDITIONAL
STRUCTURE MOTIFS FOR E2H4 [E =
(C), SI,
GE, SN, PB] 5
1.4 PERSISTENT STANNYLENES AND
DISTANNENES 6
1.4.1 SYNTHESIS OF PERSISTENT
STANNYLENES AND DISTANNENES 12
1.4.2 CHEMICAL PROPERTIES
OF DISTANNENES 14
1.4.2.1 INSERTION REACTIONS 15
1.4.2.2 REACTIVITY TOWARD
CHALCOGENS 16
1.4.2.3 REACTION WITH
ALKYNES 17
1.4.2.4 REACTION WITH
AZIDE 18
1.4.3 COORDINATION CHEMISTRY
OF DIMETALLENES 19
1.4.4 POLYDENTATE SI(II),
GE(LL) AND SN(Q) LIGANDS 21
1.5 SPECTROSCOPIC PROPERTIES
OF TIN
COMPOUNDS 23
1.5.1 TIN-119 NMR
SPECTROSCOPY 23
1.5.1.1 SPIN-SPIN COUPLING 23
1.5.1.2 TIN-119 NMR CHEMICAL
SHIFT 24
1.5.1.3 EXAMPLES FOR
TIN-119 NMR CHEMICAL
SHIFT 27
1.5.2 U M/IS SPECTROSCOPY 28
1.6 SUMMARIZING REMARKS
ON THE MULTIPLE BONDING OF HEAVY MAIN
GROUP
ELEMENTS 28
1.7 MOTIVATION 29
2 RESULTS AND DISCUSSION 30
2.1 BIS(STANNYLENE) 7 AND CYCLIC
DISTANNENES 8,9
AND
10 30
2.1.1 GENERAL PREPARATIVE
STRATEGY 30
2.1.2 SYNTHESIS OF M-TERPHENYLTIN(II)
CHLORIDES 3 AND 6 30
2.1.3 PREPARATION OF BIS(STANNYLENE)
7 AND
DISTANNENES 8,9
AND
10 32
2.1.3.1 BIS(STANNYLENE) 7 32
2.1.3.2 DISTANNENE 8 32
2.1.3.3 DISTANNENE 9 33
HTTP://D-NB.INFO/1049715284
CONTENTS
2.1.3.4 DISTANNENELO 34
2.1.4 STRUCTURAL CHARACTERIZATION 35
2.1.4.1 CRYSTAL STRUCTURE
OF BIS(STANNYLENE) 7 35
2.1.4.2 CRYSTAL STRUCTURE OF DISTANNENE 8 36
2.1.4.3 CRYSTAL STRUCTURE
OF DISTANNENE
9 38
2.1.4.4 CRYSTAL STRUCTURE
OF DISTANNENE 10 39
2.1.4.5 SUMMARY OF STRUCTURAL ASPECTS 41
2.1.5 SPECTROSCOPIC CHARACTERIZATION 42
2.1.5.1 TIN-119 NMR AT 26 *C 42
2.1.5.2 PROTON NMR
AT 26 C 45
2.1.5.3 VARIABLE TEMPERATURE
PROTON NMR 47
2.1.5.4 VARIABLE TEMPERATURE
TIN-119 NMR 54
2.1.5.5 UV-VIS SPECTROSCOPY 60
2.1.6 QUANTUM CHEMICAL
CALCULATIONS 62
2.1.6.1 GEOMETRY OPTIMIZATION 62
2.1.6.2 VARIATION OF THE TIN-TIN DISTANCE 64
2.1.6.3 ELECTRONIC EXCITATIONS (TDDFT)
AND CANONICAL
ORBITALS 69
2.1.6.4 SUMMARY OF SPECTROSCOPIC AND
THEORETICAL ASPECTS 76
2.2 REACTIONS OF DISTANNENE 8 AND BIS(STANNYLENE) 7 77
2.2.1 COORDINATION EXPERIMENTS 77
2.2.1.1 REACTION OF DISTANNENE 8 WITH NI(COD)
2
77
2.2.1.2 REACTION OF DISTANNENE 8 WITH [(COD)RHCLH 87
2.2.2 OXIDATION OF BIS(STANNYLENE) 7 AND
DISTANNENE 8 BY EXPOSURE TO AIR 89
2.2.3 REDUCTION OF DISTANNENE
8 94
2.2.4 REACTION OF DISTANNENE
8 WITH POTASSIUM CHLORIDE AND
[2.2.2]-CRYPTAND
..95
2.2.5 REACTION WITH
TERMINAL ALKYNES 101
2.2.6 REACTION WITH BORANE
DIMETHYL SULFIDE 107
2.3 ADDITIONAL COMPOUNDS 114
2.3.1 STANNYLSTANNYLENE 21 114
2.3.2 BIS(STANNIDE) 22 121
2.3.3 TETRASTANNETANE 24 123
3 SUMMARY 127
II
CONTENTS
4 EXPERIMENTAL SECTION 132
4.1 METHODS 132
4.2 PREPARATIONS 134
4.2.1 [AR
ME
LI]
2
(5) 134
4.2.2 [AR
ME
SNCIJI (6) 134
4.2.3 BIS(STANNYLENE) 7 135
4.2.4 DISTANNENE 8 136
4.2.5 DISTANNENE 9 137
4.2.6 DISTANNENE 10 139
4.2.7 DISTANNENE NICKEL(O) COMPLEX
11 140
4.2.8 DISTANNOXANE 14 141
4.2.9 BIS(DIHYDROXYSTANNANE) 15 142
4.2.10 {[2.2.2]-CRYPTAND}POTASSIUM CHLORODISTANNANIDE
16 143
4.2.11 3-PHENYL-L,2-DISTANNACYDOBUT-3-ENE 17 145
4.2.12 STANNYLSTANNYLENE 21 146
4.3 EXPERIMENTAL DETAILS OF X-RAY STRUCTURE
ANALYSES 148
APPENDIX. 152
APPENDIX A CRYSTALLOGRAPHY DATA 152
APPENDIX B SPECTROSCOPIC DATA 167
APPENDIX C THEORETICAL DATA 171
APPENDIX D ABBREVIATIONS AND
UNITS 185
APPENDIX E LIST OF COMPOUNDS 187
APPENDIX F PUBLICATIONS FROM
THIS WORK 192
REFERENCES 193
III
|
| any_adam_object | 1 |
| author | Henning, Jens 1985- |
| author_GND | (DE-588)1048483452 |
| author_facet | Henning, Jens 1985- |
| author_role | aut |
| author_sort | Henning, Jens 1985- |
| author_variant | j h jh |
| building | Verbundindex |
| bvnumber | BV041918382 |
| ctrlnum | (OCoLC)880390658 (DE-599)DNB1049715284 |
| dewey-full | 547.05686 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.05686 |
| dewey-search | 547.05686 |
| dewey-sort | 3547.05686 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01218nam a2200325 c 4500</leader><controlfield tag="001">BV041918382</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">00000000000000.0</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">140616s2014 d||| m||| 00||| eng d</controlfield><datafield tag="015" ind1=" " ind2=" "><subfield code="a">14,H05</subfield><subfield code="2">dnb</subfield></datafield><datafield tag="016" ind1="7" ind2=" "><subfield code="a">1049715284</subfield><subfield code="2">DE-101</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)880390658</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DNB1049715284</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-188</subfield><subfield code="a">DE-29T</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">547.05686</subfield><subfield code="2">22/ger</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">540</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Henning, Jens</subfield><subfield code="d">1985-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1048483452</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Cyclic distannenes</subfield><subfield code="b">synthesis and characterization of intramolecular alkene homologs of tin</subfield><subfield code="c">vorgelegt von Jens Henning</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2014</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">IV, 203 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">Tübingen, Univ., Diss., 2014</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027361952&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-027361952</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV041918382 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:08:17Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027361952 |
| oclc_num | 880390658 |
| open_access_boolean | |
| owner | DE-188 DE-29T |
| owner_facet | DE-188 DE-29T |
| physical | IV, 203 S. graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| record_format | marc |
| spelling | Henning, Jens 1985- Verfasser (DE-588)1048483452 aut Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin vorgelegt von Jens Henning 2014 IV, 203 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Tübingen, Univ., Diss., 2014 (DE-588)4113937-9 Hochschulschrift gnd-content DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027361952&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Henning, Jens 1985- Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin |
| subject_GND | (DE-588)4113937-9 |
| title | Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin |
| title_auth | Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin |
| title_exact_search | Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin |
| title_full | Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin vorgelegt von Jens Henning |
| title_fullStr | Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin vorgelegt von Jens Henning |
| title_full_unstemmed | Cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin vorgelegt von Jens Henning |
| title_short | Cyclic distannenes |
| title_sort | cyclic distannenes synthesis and characterization of intramolecular alkene homologs of tin |
| title_sub | synthesis and characterization of intramolecular alkene homologs of tin |
| topic_facet | Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027361952&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT henningjens cyclicdistannenessynthesisandcharacterizationofintramolecularalkenehomologsoftin |