Thermodynamics for chemical engineers:
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| Hauptverfasser: | , |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim, Germany
Wiley-VCH
[2022]
|
| Schlagworte: | |
| Online-Zugang: | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35030-8/ Inhaltsverzeichnis |
| Beschreibung: | xi, 465 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm |
| ISBN: | 9783527350308 3527350306 |
Internformat
MARC
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| 003 | DE-604 | ||
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| 015 | |a 22,N03 |2 dnb | ||
| 016 | 7 | |a 1249500958 |2 DE-101 | |
| 020 | |a 9783527350308 |c hbk: circa EUR 89.90 (DE) (freier Preis) |9 978-3-527-35030-8 | ||
| 020 | |a 3527350306 |9 3-527-35030-6 | ||
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| 049 | |a DE-29T |a DE-91G |a DE-83 |a DE-1102 |a DE-92 |a DE-703 | ||
| 084 | |a UG 1200 |0 (DE-625)145614: |2 rvk | ||
| 084 | |a VE 6001 |0 (DE-625)147131:254 |2 rvk | ||
| 084 | |a MTA 600 |2 stub | ||
| 084 | |8 1\p |a 540 |2 23sdnb | ||
| 084 | |a CHE 170 |2 stub | ||
| 100 | 1 | |a Hall, Kenneth R. |d 1939- |e Verfasser |0 (DE-588)1265222959 |4 aut | |
| 245 | 1 | 0 | |a Thermodynamics for chemical engineers |c Kenneth R. Hall, Gustavo A. Iglesias-Silva |
| 264 | 1 | |a Weinheim, Germany |b Wiley-VCH |c [2022] | |
| 264 | 4 | |c © 2022 | |
| 300 | |a xi, 465 Seiten |b Illustrationen, Diagramme |c 24.4 cm x 17 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Thermodynamik |0 (DE-588)4059827-5 |2 gnd |9 rswk-swf |
| 653 | |a CG01: Grundlagen der Chemischen Verfahrenstechnik | ||
| 653 | |a CH34: Petrochemie / Brennstoffindustrie | ||
| 653 | |a CH94: Chemische Thermodynamik | ||
| 653 | |a Chemical Engineering | ||
| 653 | |a Chemical Engineering Fundamentals | ||
| 653 | |a Chemical Thermodynamics | ||
| 653 | |a Chemie | ||
| 653 | |a Chemische Thermodynamik | ||
| 653 | |a Chemische Verfahrenstechnik | ||
| 653 | |a Chemistry | ||
| 653 | |a Grundlagen der Chemischen Verfahrenstechnik | ||
| 653 | |a Petrochemie / Brennstoffindustrie | ||
| 653 | |a Petrochemistry / Fuel | ||
| 689 | 0 | 0 | |a Thermodynamik |0 (DE-588)4059827-5 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Iglesias-Silva, Gustavo A. |e Verfasser |4 aut | |
| 710 | 2 | |a Wiley-VCH |0 (DE-588)16179388-5 |4 pbl | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-83678-9 |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, EPUB |z 978-3-527-83679-6 |
| 856 | 4 | 2 | |m X:MVB |u http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35030-8/ |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033670215&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-033670215 | ||
| 883 | 1 | |8 1\p |a vlb |d 20220114 |q DE-101 |u https://d-nb.info/provenance/plan#vlb | |
Datensatz im Suchindex
| _version_ | 1804184122848968704 |
|---|---|
| adam_text | CONTENTS
PREFACE
XL
1
INTRODUCTION
1
1.1
DEFINITION
1
1.2
DIMENSIONS,
FUNDAMENTAL
QUANTITIES,
AND
UNITS
2
1.3
SECONDARY
OR
DERIVED
PHYSICAL
QUANTITIES
4
1.4
SI
USAGE
OF
UNITS
AND
SYMBOLS
13
1.5
THERMODYNAMIC
SYSTEMS
AND
VARIABLES
14
1.6
ZEROTH
LAW
16
PROBLEMS
FOR
CHAPTER
1
16
2
ENERGY
AND
THE
FIRST
LAW
21
2.1
INTRODUCTION
21
2.2
ENERGY
22
2.3
FIRST
LAW
OF
THERMODYNAMICS
24
2.4
APPLICATION
OF
SOLUTION
PROCEDURE
TO
SIMPLE
CASES
30
2.5
PRACTICAL
APPLICATION
EXAMPLES
34
2.5.1
COMPRESSORS/PUMPS
34
2.5.2
TURBINES/EXPANDERS
35
2.5.3
CONDENSERS/VAPORIZERS/REBOILERS
36
2.5.4
HEAT
EXCHANGER
36
2.5.5
SAMPLE
CYLINDER
38
2.6
DIFFERENTIAL
FORM
39
2.7
INSERTING
TIME:
UNSTEADY-STATE
FLOW
PROCESS
39
2.8
RECAP
40
PROBLEMS
FOR
CHAPTER
2
40
REFERENCE
45
3
PVT
RELATIONS
AND
EQUATIONS
OF
STATE
47
3.1
INTRODUCTION
47
3.2
GRAPHICAL
REPRESENTATIONS
47
3.3
CRITICAL
REGION
53
3.4
TABULAR
REPRESENTATIONS
54
VI
CONTENTS
3.5
3.5.1
3.5.2
3.5.2.1
3.5.2.2
3.5.2.3
3.5.2.4
3.5.2.5
3.5.3
3.5.3.1
3.5.4
3.5.4.1
3.5.4.2
3.5.4.3
3.5.4.4
3.5.4.5
3.5.4.6
3.5.5
3.5.5.1
3.5.5.2
3.5.5.3
3.5.5.4
3.5.5.5
3.5.6
3.5.6.1
3.5.6.2
3.5.7
3.6
3.7
3.8
3.8.1
3.8.1.1
3.8.1.2
3.8.1.3
3.8.2
3.8.3
3.8.3.1
3.8.3.2
MATHEMATICAL
REPRESENTATIONS
56
PERFECT
AND
IDEAL
GAS
EOS
57
REVERSIBLE
PROCESSES
INVOLVING
IDEAL
GASES
IN
CLOSED
SYSTEMS
58
CONSTANT
VOLUME
(ISOCHORIC)
PROCESS
59
CONSTANT
PRESSURE
(ISOBARIC)
PROCESS
59
CONSTANT
TEMPERATURE
(ISOTHERMAL)
PROCESS
60
ADIABATIC
PROCESS
60
POLYTROPIC
PROCESSES
62
VIRIAL
EQUATION
OF
STATE
65
CORRELATIONS
FOR
THE
SECOND
AND
THIRD
VIRIAL
COEFFICIENT
69
OTHER
SPECIAL
EQUATIONS
75
TAIT
EQUATION
75
RACKETT
EQUATION
75
RIEDEL
EQUATION
75
YEN
AND
WOODS
EQUATION
76
CHUEH
AND
PRAUSNITZ
EQUATION
76
GENERALIZED
LEE-KESLER
CORRELATION
76
CUBIC
EQUATIONS
OF
STATE
77
VAN
DER
WAALS
(VDW)
EQUATION
OF
STATE
77
OTHER
CUBIC
EOS
79
REDLICH-KWONG
(RK)
EOS
80
SOAVE-REDLICH-KWONG
(SRK)
EQUATION
OF
STATE
82
PENG-ROBINSON
(PR)
EQUATION
OF
STATE
82
MULTIPARAMETER
EQUATIONS
OF
STATE
83
BENEDICT-WEBB-RUBIN
(BWR)
EQUATION
OF
STATE
83
BOUBLIK-ALDER-CHEN-KREGLEWSKI
83
REFERENCE
EQUATION
OF
STATE
85
CALCULATION
OF
VOLUMES
FROM
EOS
86
VAPOR
PRESSURE
AND
ENTHALPY
OF
VAPORIZATION
CORRELATIONS
89
IDEAL
GAS
ENTHALPY
CHANGES:
APPLICATIONS
91
HEAT
OF
REACTION
91
STANDARD HEAT
OF
REACTION
91
STANDARD HEAT
OF
FORMATION
92
STANDARD
HEAT
OF
COMBUSTION
92
TEMPERATURE
DEPENDENCE
OF
THE
HEAT
OF
REACTION
92
PRACTICAL
CALCULATIONS
94
ADIABATIC
FLAME
TEMPERATURE
95
REACTION
WITH
HEAT
TRANSFER
95
PROBLEMS
FOR
CHAPTER
3
99
REFERENCES
109
4
4.1
4.2
4.3
SECOND
LAW
OF
THERMODYNAMICS
113
INTRODUCTION
113
GENERAL
AND
CLASSICAL
STATEMENTS
OF
THE
SECOND
LAW
114
HEAT
ENGINES,
REFRIGERATORS,
AND
CYCLES
116
CONTENTS
VII
4.4
4.5
4.6
4.6.1
4.7
4.8
IMPLICATIONS
OF
THE
SECOND
LAW
117
EFFICIENCY
127
SPECIFIC
HEAT/HEAT
CAPACITY
128
ENTROPY
CHANGES
FOR
IDEAL
GASES
130
ENTROPY
BALANCE
EQUATION
FOR
OPEN
SYSTEMS
133
AVAILABILITY
AND
MAXIMUM/MINIMUM
WORK
137
PROBLEMS
FOR
CHAPTER
4
139
5
5.1
5.2
5.2.1
5.2.2
5.2.3
5.3
5.4
5.5
5.6
5.7
5.8
5.8.1
5.8.2
5.8.3
5.9
5.10
5.11
5.12
THERMODYNAMIC
RELATIONS
145
INTRODUCTION
145
MATHEMATICS
REVIEW
145
EXACT
DIFFERENTIALS
145
INEXACT
DIFFERENTIALS
AND
LINE
INTEGRATION
146
PROPERTIES
OF
FUNCTIONS
OF
SEVERAL
VARIABLES
147
FUNDAMENTAL
THERMODYNAMICS
EQUATION
148
LEGENDRE
TRANSFORMS
149
MAXWELL
RELATIONS
151
DERIVATION
OF
THERMODYNAMIC
RELATIONSHIPS
153
OPEN
SYSTEMS:
CHEMICAL
POTENTIAL
155
PROPERTY
CHANGE
CALCULATIONS
157
TEMPERATURE
DERIVATIVES
157
VOLUME
DERIVATIVES
158
PRESSURE
DERIVATIVES
159
RESIDUAL
PROPERTIES
160
PROPERTY
CHANGES
USING
RESIDUAL
FUNCTIONS
163
GENERALIZED
CORRELATIONS
FOR
RESIDUAL
FUNCTIONS
166
TWO-PHASE
SYSTEMS
-
CLAPEYRON
EQUATION
169
PROBLEMS
FOR
CHAPTER
5
172
6
6.1
6.1.1
6.1.2
6.1.3
6.2
6.2.1
6.2.2
6.2.3
6.2.4
6.2.4.1
6.2.4.2
6.2.4.3
6.2.5
6.2.5.1
6.2.5.2
PRACTICAL
APPLICATIONS
FOR
THERMODYNAMICS
179
FLUID
FLOW
179
FLOW
THROUGH
DUCTS
179
PROPERTIES
OF
SUB-COOLED
LIQUIDS
(COMPRESSED
LIQUID)
184
PUMPS,
COMPRESSORS,
AND
EXPANDERS
186
HEAT
ENGINES
AND
REFRIGERATION
UNITS
196
HEAT
AND
WORK
196
RANKINE
CYCLE
198
MODIFICATIONS
OF
THE
RANKINE
CYCLE
204
INTERNAL
COMBUSTION
ENGINES
211
OTTO
CYCLE
211
DIESEL
ENGINE
CYCLE
216
GAS
TURBINE
CYCLE
220
REFRIGERATION:
THE
CARNOT
CYCLE
FOR
A
REFRIGERATION
UNIT
225
VAPOR
COMPRESSION
CYCLE
226
AIR
REFRIGERATION
CYCLE
229
VIII
CONTENTS
6.2.53
6.2.5.4
6.2.5.5
6.2.6
ABSORPTION
REFRIGERATION
233
HEAT
PUMP
235
LIQUEFACTION
PROCESS
235
PROCESS
SIMULATORS:
USING
PROCESS
SIMULATION
FOR
FLUID
FLOW
PROBLEMS
241
PROBLEMS
FOR
CHAPTER
6
249
7
7.1
7.2
7.3
7.3.1
7.4
7.5
7.6
SOLUTION
THEORY
257
INTRODUCTION
257
COMPOSITION
VARIABLES
257
CHEMICAL
POTENTIAL
260
MORE
MAXWELL
RELATIONS
261
PARTIAL
MOLAR
PROPERTIES
262
GENERAL
GIBBS-DUHEM
EQUATION
268
DIFFERENTIAL
THERMODYNAMIC
PROPERTIES
IN
OPEN
SYSTEMS
IN
TERMS
OF
MEASURABLES
270
7.6.1
7.6.2
7.7
7.8
7.9
7.9.1
7.9.2
7.9.3
7.9.4
7.9.5
7.10
7.11
7.12
7.12.1
7.12.1.1
7.13
7.14
7.15
7.16
USING
T
AND
NV
270
USING
T,P
271
IDEAL
GAS
MIXTURES
271
FUGACITY
AND
FUGACITY
COEFFICIENT
FOR
PURE
SUBSTANCES
275
EQUATIONS
FOR
CALCULATING
FUGACITY
277
FUGACITY
OF
A
VAPOR
(POINT
A)
277
FUGACITY
OF
A
VAPOR
OR
SATURATED
LIQUID
(POINT
B)
277
FUGACITY
OF
LIQUID
(POINT
C)
278
FUGACITY
OF
SOLID
AT
THE
MELTING
POINT
(POINT
D)
279
FUGACITY
OF
A
SOLID
(POINT
E)
279
APPLICATION
OF
FUGACITY
EQUATION
TO
GASES
AND
LIQUIDS
280
FUGACITY
AND
FUGACITY
COEFFICIENT
IN
A
SOLUTION
284
CALCULATION
OF
THE
FUGACITY
AND
FUGACITY
COEFFICIENT
IN
SOLUTION
287
USING
CUBIC
EOS
291
MIXING
RULES
292
IDEAL
SOLUTIONS
298
EXCESS
PROPERTIES.
ACTIVITY
COEFFICIENTS
301
ACTIVITY
COEFFICIENTS
WITH
DIFFERENT
STANDARD
STATES
303
EFFECT
OF
PRESSURE
ON
THE
FUGACITY
IN
SOLUTION
AND
ACTIVITY
COEFFICIENTS
USING
THE
LEWIS-RANDALL
RULE
305
7.17
7.18
PROPERTY
CHANGE
ON
MIXING
307
EXCESS
GIBBS
ENERGY
MODELS
310
PROBLEMS
FOR
CHAPTER
7
318
REFERENCES
323
8
8.1
8.2
8.3
PHASE
EQUILIBRIUM
325
INTRODUCTION
325
EQUILIBRIUM
325
GIBBS
PHASE
RULE
329
CONTENTS
|
IX
8.4
8.5
8.6
8.7
8.7.1
8.7.2
8.7.3
8.7.4
8.7.5
8.8
8.9
8.9.1
8.9.2
8.10
8.11
8.12
8.13
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
9.10
9.11
9.11.1
9.11.1.1
9.11.1.2
9.11.1.3
9.11.2
9.12
9.13
9.14
PURE
COMPONENTS
AND
PHASE
EQUILIBRIA
330
DIFFERENT
PHASE
DIAGRAMS
FOR
BINARY
MIXTURES
AT
VAPOR-LIQUID
EQUILIBRIUM
(VLE)
332
VAPOR/LIQUID
EQUILIBRIUM
RELATIONSHIP
336
PHASE
CALCULATIONS
USING
THE
GAMMA-PHI
FORMULATION
338
BUBBLE
PRESSURE
339
BUBBLE
TEMPERATURE
340
DEW
PRESSURE
341
DEW
TEMPERATURE
342
FLASH
342
PHASE
CALCULATIONS
USING
THE
PHI-PHI
FORMULATION
349
MODERN
APPROACH
TO
PHASE
EQUILIBRIUM
CALCULATIONS
358
EQUAL
AREA
RULE
FOR
BINARY
MIXTURES
359
A
GENERAL
APPROACH
FOR
MULTICOMPONENT
AND
MULTIPHASE
SYSTEMS
365
BINARY
LIQUID-LIQUID
EQUILIBRIUM
(LLE)
374
BINARY
VAPOR-LIQUID-LIQUID
EQUILIBRIUM
(VLLE)
381
BINARY
VAPOR-SOLID
EQUILIBRIUM
(VSE)
387
BINARY
LIQUID-SOLID
EQUILIBRIUM
(LSE)
391
PROBLEMS
FOR
CHAPTER
8
397
REFERENCES
403
CHEMICAL
REACTION
EQUILIBRIA
405
INTRODUCTION
405
NATURE
OF
REACTIONS
406
CHEMICAL
REACTION
STOICHIOMETRY
406
EXTENT
OF
REACTION
407
PHASE
RULE
FOR
REACTING
SYSTEMS
408
PRINCIPLES
OF
REACTION
EQUILIBRIA
410
UNDERSTANDING
THE
REACTION
EQUILIBRIA
413
EQUILIBRIUM
CONSTANT
415
TEMPERATURE
DEPENDENCE
OF
THE
EQUILIBRIUM
CONSTANT
417
STANDARD
STATES
420
APPLICATIONS
TO
DIFFERENT
TYPES
OF
REACTIONS
420
REACTIONS
IN
SINGLE-PHASE
SYSTEMS
421
GAS-PHASE
REACTIONS
421
LIQUID-PHASE
REACTIONS
422
SOLID
REACTIONS
424
HETEROGENEOUS
REACTIONS
(DIFFERENT
PHASE
SYSTEMS)
425
MULTI-REACTIONS
429
NONSTOICHIOMETRIC
SOLUTION
431
EQUAL
AREA
RULE
FOR
REACTIVE
THERMODYNAMIC EQUILIBRIUM
CALCULATIONS
434
PROBLEMS
FOR
CHAPTER
9
440
REFERENCES
447
X
CONTENTS
A
A.1
A.2
A3
A.4
A.5
A.6
A.7
APPENDICES
449
INSTRUCTIONS
TO
ADD
AN
ADD-IN
YOUR
COMPUTER
449
EXCEL
LK
CALC
ADD-IN
449
EXCEL
STEAM
CALC
ADD-IN
451
HEAT
CAPACITY
EQUATIONS
FOR
AN
IDEAL
GAS
453
ANTOINE
EQUATION
CONSTANTS
454
HEAT
CAPACITY
EQUATIONS
FOR
LIQUIDS
454
ITERATIVE
PROCEDURES
FOR
THE
CALCULATION
OF
VAPOR
LIQUID
EQUILIBRIUM
454
A.7.1
A.7.1.1
A.7.1.2
A.7.2
A.7.2.1
A.7.2.2
A.73
BUBBLE
POINT
CALCULATIONS
454
BUBBLE
PRESSURE
CALCULATION
454
BUBBLE
TEMPERATURE
CALCULATION
455
DEW
POINT
CALCULATIONS
456
DEW
PRESSURE
CALCULATION
456
DEW
TEMPERATURE
CALCULATION
457
FLASH
CALCULATION
458
REFERENCES
460
INDEX
461
|
| adam_txt |
CONTENTS
PREFACE
XL
1
INTRODUCTION
1
1.1
DEFINITION
1
1.2
DIMENSIONS,
FUNDAMENTAL
QUANTITIES,
AND
UNITS
2
1.3
SECONDARY
OR
DERIVED
PHYSICAL
QUANTITIES
4
1.4
SI
USAGE
OF
UNITS
AND
SYMBOLS
13
1.5
THERMODYNAMIC
SYSTEMS
AND
VARIABLES
14
1.6
ZEROTH
LAW
16
PROBLEMS
FOR
CHAPTER
1
16
2
ENERGY
AND
THE
FIRST
LAW
21
2.1
INTRODUCTION
21
2.2
ENERGY
22
2.3
FIRST
LAW
OF
THERMODYNAMICS
24
2.4
APPLICATION
OF
SOLUTION
PROCEDURE
TO
SIMPLE
CASES
30
2.5
PRACTICAL
APPLICATION
EXAMPLES
34
2.5.1
COMPRESSORS/PUMPS
34
2.5.2
TURBINES/EXPANDERS
35
2.5.3
CONDENSERS/VAPORIZERS/REBOILERS
36
2.5.4
HEAT
EXCHANGER
36
2.5.5
SAMPLE
CYLINDER
38
2.6
DIFFERENTIAL
FORM
39
2.7
INSERTING
TIME:
UNSTEADY-STATE
FLOW
PROCESS
39
2.8
RECAP
40
PROBLEMS
FOR
CHAPTER
2
40
REFERENCE
45
3
PVT
RELATIONS
AND
EQUATIONS
OF
STATE
47
3.1
INTRODUCTION
47
3.2
GRAPHICAL
REPRESENTATIONS
47
3.3
CRITICAL
REGION
53
3.4
TABULAR
REPRESENTATIONS
54
VI
CONTENTS
3.5
3.5.1
3.5.2
3.5.2.1
3.5.2.2
3.5.2.3
3.5.2.4
3.5.2.5
3.5.3
3.5.3.1
3.5.4
3.5.4.1
3.5.4.2
3.5.4.3
3.5.4.4
3.5.4.5
3.5.4.6
3.5.5
3.5.5.1
3.5.5.2
3.5.5.3
3.5.5.4
3.5.5.5
3.5.6
3.5.6.1
3.5.6.2
3.5.7
3.6
3.7
3.8
3.8.1
3.8.1.1
3.8.1.2
3.8.1.3
3.8.2
3.8.3
3.8.3.1
3.8.3.2
MATHEMATICAL
REPRESENTATIONS
56
PERFECT
AND
IDEAL
GAS
EOS
57
REVERSIBLE
PROCESSES
INVOLVING
IDEAL
GASES
IN
CLOSED
SYSTEMS
58
CONSTANT
VOLUME
(ISOCHORIC)
PROCESS
59
CONSTANT
PRESSURE
(ISOBARIC)
PROCESS
59
CONSTANT
TEMPERATURE
(ISOTHERMAL)
PROCESS
60
ADIABATIC
PROCESS
60
POLYTROPIC
PROCESSES
62
VIRIAL
EQUATION
OF
STATE
65
CORRELATIONS
FOR
THE
SECOND
AND
THIRD
VIRIAL
COEFFICIENT
69
OTHER
SPECIAL
EQUATIONS
75
TAIT
EQUATION
75
RACKETT
EQUATION
75
RIEDEL
EQUATION
75
YEN
AND
WOODS
EQUATION
76
CHUEH
AND
PRAUSNITZ
EQUATION
76
GENERALIZED
LEE-KESLER
CORRELATION
76
CUBIC
EQUATIONS
OF
STATE
77
VAN
DER
WAALS
(VDW)
EQUATION
OF
STATE
77
OTHER
CUBIC
EOS
79
REDLICH-KWONG
(RK)
EOS
80
SOAVE-REDLICH-KWONG
(SRK)
EQUATION
OF
STATE
82
PENG-ROBINSON
(PR)
EQUATION
OF
STATE
82
MULTIPARAMETER
EQUATIONS
OF
STATE
83
BENEDICT-WEBB-RUBIN
(BWR)
EQUATION
OF
STATE
83
BOUBLIK-ALDER-CHEN-KREGLEWSKI
83
REFERENCE
EQUATION
OF
STATE
85
CALCULATION
OF
VOLUMES
FROM
EOS
86
VAPOR
PRESSURE
AND
ENTHALPY
OF
VAPORIZATION
CORRELATIONS
89
IDEAL
GAS
ENTHALPY
CHANGES:
APPLICATIONS
91
HEAT
OF
REACTION
91
STANDARD HEAT
OF
REACTION
91
STANDARD HEAT
OF
FORMATION
92
STANDARD
HEAT
OF
COMBUSTION
92
TEMPERATURE
DEPENDENCE
OF
THE
HEAT
OF
REACTION
92
PRACTICAL
CALCULATIONS
94
ADIABATIC
FLAME
TEMPERATURE
95
REACTION
WITH
HEAT
TRANSFER
95
PROBLEMS
FOR
CHAPTER
3
99
REFERENCES
109
4
4.1
4.2
4.3
SECOND
LAW
OF
THERMODYNAMICS
113
INTRODUCTION
113
GENERAL
AND
CLASSICAL
STATEMENTS
OF
THE
SECOND
LAW
114
HEAT
ENGINES,
REFRIGERATORS,
AND
CYCLES
116
CONTENTS
VII
4.4
4.5
4.6
4.6.1
4.7
4.8
IMPLICATIONS
OF
THE
SECOND
LAW
117
EFFICIENCY
127
SPECIFIC
HEAT/HEAT
CAPACITY
128
ENTROPY
CHANGES
FOR
IDEAL
GASES
130
ENTROPY
BALANCE
EQUATION
FOR
OPEN
SYSTEMS
133
AVAILABILITY
AND
MAXIMUM/MINIMUM
WORK
137
PROBLEMS
FOR
CHAPTER
4
139
5
5.1
5.2
5.2.1
5.2.2
5.2.3
5.3
5.4
5.5
5.6
5.7
5.8
5.8.1
5.8.2
5.8.3
5.9
5.10
5.11
5.12
THERMODYNAMIC
RELATIONS
145
INTRODUCTION
145
MATHEMATICS
REVIEW
145
EXACT
DIFFERENTIALS
145
INEXACT
DIFFERENTIALS
AND
LINE
INTEGRATION
146
PROPERTIES
OF
FUNCTIONS
OF
SEVERAL
VARIABLES
147
FUNDAMENTAL
THERMODYNAMICS
EQUATION
148
LEGENDRE
TRANSFORMS
149
MAXWELL
RELATIONS
151
DERIVATION
OF
THERMODYNAMIC
RELATIONSHIPS
153
OPEN
SYSTEMS:
CHEMICAL
POTENTIAL
155
PROPERTY
CHANGE
CALCULATIONS
157
TEMPERATURE
DERIVATIVES
157
VOLUME
DERIVATIVES
158
PRESSURE
DERIVATIVES
159
RESIDUAL
PROPERTIES
160
PROPERTY
CHANGES
USING
RESIDUAL
FUNCTIONS
163
GENERALIZED
CORRELATIONS
FOR
RESIDUAL
FUNCTIONS
166
TWO-PHASE
SYSTEMS
-
CLAPEYRON
EQUATION
169
PROBLEMS
FOR
CHAPTER
5
172
6
6.1
6.1.1
6.1.2
6.1.3
6.2
6.2.1
6.2.2
6.2.3
6.2.4
6.2.4.1
6.2.4.2
6.2.4.3
6.2.5
6.2.5.1
6.2.5.2
PRACTICAL
APPLICATIONS
FOR
THERMODYNAMICS
179
FLUID
FLOW
179
FLOW
THROUGH
DUCTS
179
PROPERTIES
OF
SUB-COOLED
LIQUIDS
(COMPRESSED
LIQUID)
184
PUMPS,
COMPRESSORS,
AND
EXPANDERS
186
HEAT
ENGINES
AND
REFRIGERATION
UNITS
196
HEAT
AND
WORK
196
RANKINE
CYCLE
198
MODIFICATIONS
OF
THE
RANKINE
CYCLE
204
INTERNAL
COMBUSTION
ENGINES
211
OTTO
CYCLE
211
DIESEL
ENGINE
CYCLE
216
GAS
TURBINE
CYCLE
220
REFRIGERATION:
THE
CARNOT
CYCLE
FOR
A
REFRIGERATION
UNIT
225
VAPOR
COMPRESSION
CYCLE
226
AIR
REFRIGERATION
CYCLE
229
VIII
CONTENTS
6.2.53
6.2.5.4
6.2.5.5
6.2.6
ABSORPTION
REFRIGERATION
233
HEAT
PUMP
235
LIQUEFACTION
PROCESS
235
PROCESS
SIMULATORS:
USING
PROCESS
SIMULATION
FOR
FLUID
FLOW
PROBLEMS
241
PROBLEMS
FOR
CHAPTER
6
249
7
7.1
7.2
7.3
7.3.1
7.4
7.5
7.6
SOLUTION
THEORY
257
INTRODUCTION
257
COMPOSITION
VARIABLES
257
CHEMICAL
POTENTIAL
260
MORE
MAXWELL
RELATIONS
261
PARTIAL
MOLAR
PROPERTIES
262
GENERAL
GIBBS-DUHEM
EQUATION
268
DIFFERENTIAL
THERMODYNAMIC
PROPERTIES
IN
OPEN
SYSTEMS
IN
TERMS
OF
MEASURABLES
270
7.6.1
7.6.2
7.7
7.8
7.9
7.9.1
7.9.2
7.9.3
7.9.4
7.9.5
7.10
7.11
7.12
7.12.1
7.12.1.1
7.13
7.14
7.15
7.16
USING
T
AND
NV
270
USING
T,P
271
IDEAL
GAS
MIXTURES
271
FUGACITY
AND
FUGACITY
COEFFICIENT
FOR
PURE
SUBSTANCES
275
EQUATIONS
FOR
CALCULATING
FUGACITY
277
FUGACITY
OF
A
VAPOR
(POINT
A)
277
FUGACITY
OF
A
VAPOR
OR
SATURATED
LIQUID
(POINT
B)
277
FUGACITY
OF
LIQUID
(POINT
C)
278
FUGACITY
OF
SOLID
AT
THE
MELTING
POINT
(POINT
D)
279
FUGACITY
OF
A
SOLID
(POINT
E)
279
APPLICATION
OF
FUGACITY
EQUATION
TO
GASES
AND
LIQUIDS
280
FUGACITY
AND
FUGACITY
COEFFICIENT
IN
A
SOLUTION
284
CALCULATION
OF
THE
FUGACITY
AND
FUGACITY
COEFFICIENT
IN
SOLUTION
287
USING
CUBIC
EOS
291
MIXING
RULES
292
IDEAL
SOLUTIONS
298
EXCESS
PROPERTIES.
ACTIVITY
COEFFICIENTS
301
ACTIVITY
COEFFICIENTS
WITH
DIFFERENT
STANDARD
STATES
303
EFFECT
OF
PRESSURE
ON
THE
FUGACITY
IN
SOLUTION
AND
ACTIVITY
COEFFICIENTS
USING
THE
LEWIS-RANDALL
RULE
305
7.17
7.18
PROPERTY
CHANGE
ON
MIXING
307
EXCESS
GIBBS
ENERGY
MODELS
310
PROBLEMS
FOR
CHAPTER
7
318
REFERENCES
323
8
8.1
8.2
8.3
PHASE
EQUILIBRIUM
325
INTRODUCTION
325
EQUILIBRIUM
325
GIBBS
PHASE
RULE
329
CONTENTS
|
IX
8.4
8.5
8.6
8.7
8.7.1
8.7.2
8.7.3
8.7.4
8.7.5
8.8
8.9
8.9.1
8.9.2
8.10
8.11
8.12
8.13
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
9.10
9.11
9.11.1
9.11.1.1
9.11.1.2
9.11.1.3
9.11.2
9.12
9.13
9.14
PURE
COMPONENTS
AND
PHASE
EQUILIBRIA
330
DIFFERENT
PHASE
DIAGRAMS
FOR
BINARY
MIXTURES
AT
VAPOR-LIQUID
EQUILIBRIUM
(VLE)
332
VAPOR/LIQUID
EQUILIBRIUM
RELATIONSHIP
336
PHASE
CALCULATIONS
USING
THE
GAMMA-PHI
FORMULATION
338
BUBBLE
PRESSURE
339
BUBBLE
TEMPERATURE
340
DEW
PRESSURE
341
DEW
TEMPERATURE
342
FLASH
342
PHASE
CALCULATIONS
USING
THE
PHI-PHI
FORMULATION
349
MODERN
APPROACH
TO
PHASE
EQUILIBRIUM
CALCULATIONS
358
EQUAL
AREA
RULE
FOR
BINARY
MIXTURES
359
A
GENERAL
APPROACH
FOR
MULTICOMPONENT
AND
MULTIPHASE
SYSTEMS
365
BINARY
LIQUID-LIQUID
EQUILIBRIUM
(LLE)
374
BINARY
VAPOR-LIQUID-LIQUID
EQUILIBRIUM
(VLLE)
381
BINARY
VAPOR-SOLID
EQUILIBRIUM
(VSE)
387
BINARY
LIQUID-SOLID
EQUILIBRIUM
(LSE)
391
PROBLEMS
FOR
CHAPTER
8
397
REFERENCES
403
CHEMICAL
REACTION
EQUILIBRIA
405
INTRODUCTION
405
NATURE
OF
REACTIONS
406
CHEMICAL
REACTION
STOICHIOMETRY
406
EXTENT
OF
REACTION
407
PHASE
RULE
FOR
REACTING
SYSTEMS
408
PRINCIPLES
OF
REACTION
EQUILIBRIA
410
UNDERSTANDING
THE
REACTION
EQUILIBRIA
413
EQUILIBRIUM
CONSTANT
415
TEMPERATURE
DEPENDENCE
OF
THE
EQUILIBRIUM
CONSTANT
417
STANDARD
STATES
420
APPLICATIONS
TO
DIFFERENT
TYPES
OF
REACTIONS
420
REACTIONS
IN
SINGLE-PHASE
SYSTEMS
421
GAS-PHASE
REACTIONS
421
LIQUID-PHASE
REACTIONS
422
SOLID
REACTIONS
424
HETEROGENEOUS
REACTIONS
(DIFFERENT
PHASE
SYSTEMS)
425
MULTI-REACTIONS
429
NONSTOICHIOMETRIC
SOLUTION
431
EQUAL
AREA
RULE
FOR
REACTIVE
THERMODYNAMIC EQUILIBRIUM
CALCULATIONS
434
PROBLEMS
FOR
CHAPTER
9
440
REFERENCES
447
X
CONTENTS
A
A.1
A.2
A3
A.4
A.5
A.6
A.7
APPENDICES
449
INSTRUCTIONS
TO
ADD
AN
ADD-IN
YOUR
COMPUTER
449
EXCEL
LK
CALC
ADD-IN
449
EXCEL
STEAM
CALC
ADD-IN
451
HEAT
CAPACITY
EQUATIONS
FOR
AN
IDEAL
GAS
453
ANTOINE
EQUATION
CONSTANTS
454
HEAT
CAPACITY
EQUATIONS
FOR
LIQUIDS
454
ITERATIVE
PROCEDURES
FOR
THE
CALCULATION
OF
VAPOR
LIQUID
EQUILIBRIUM
454
A.7.1
A.7.1.1
A.7.1.2
A.7.2
A.7.2.1
A.7.2.2
A.73
BUBBLE
POINT
CALCULATIONS
454
BUBBLE
PRESSURE
CALCULATION
454
BUBBLE
TEMPERATURE
CALCULATION
455
DEW
POINT
CALCULATIONS
456
DEW
PRESSURE
CALCULATION
456
DEW
TEMPERATURE
CALCULATION
457
FLASH
CALCULATION
458
REFERENCES
460
INDEX
461 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Hall, Kenneth R. 1939- Iglesias-Silva, Gustavo A. |
| author_GND | (DE-588)1265222959 |
| author_facet | Hall, Kenneth R. 1939- Iglesias-Silva, Gustavo A. |
| author_role | aut aut |
| author_sort | Hall, Kenneth R. 1939- |
| author_variant | k r h kr krh g a i s gai gais |
| building | Verbundindex |
| bvnumber | BV048290199 |
| classification_rvk | UG 1200 VE 6001 |
| classification_tum | MTA 600 CHE 170 |
| ctrlnum | (OCoLC)1339059110 (DE-599)DNB1249500958 |
| discipline | Chemie / Pharmazie Physik Chemie |
| discipline_str_mv | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV048290199 |
| illustrated | Illustrated |
| index_date | 2024-07-03T20:03:20Z |
| indexdate | 2024-07-10T09:34:19Z |
| institution | BVB |
| institution_GND | (DE-588)16179388-5 |
| isbn | 9783527350308 3527350306 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-033670215 |
| oclc_num | 1339059110 |
| open_access_boolean | |
| owner | DE-29T DE-91G DE-BY-TUM DE-83 DE-1102 DE-92 DE-703 |
| owner_facet | DE-29T DE-91G DE-BY-TUM DE-83 DE-1102 DE-92 DE-703 |
| physical | xi, 465 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm |
| publishDate | 2022 |
| publishDateSearch | 2022 |
| publishDateSort | 2022 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Hall, Kenneth R. 1939- Verfasser (DE-588)1265222959 aut Thermodynamics for chemical engineers Kenneth R. Hall, Gustavo A. Iglesias-Silva Weinheim, Germany Wiley-VCH [2022] © 2022 xi, 465 Seiten Illustrationen, Diagramme 24.4 cm x 17 cm txt rdacontent n rdamedia nc rdacarrier Thermodynamik (DE-588)4059827-5 gnd rswk-swf CG01: Grundlagen der Chemischen Verfahrenstechnik CH34: Petrochemie / Brennstoffindustrie CH94: Chemische Thermodynamik Chemical Engineering Chemical Engineering Fundamentals Chemical Thermodynamics Chemie Chemische Thermodynamik Chemische Verfahrenstechnik Chemistry Grundlagen der Chemischen Verfahrenstechnik Petrochemie / Brennstoffindustrie Petrochemistry / Fuel Thermodynamik (DE-588)4059827-5 s DE-604 Iglesias-Silva, Gustavo A. Verfasser aut Wiley-VCH (DE-588)16179388-5 pbl Erscheint auch als Online-Ausgabe, PDF 978-3-527-83678-9 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-83679-6 X:MVB http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35030-8/ DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033670215&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p vlb 20220114 DE-101 https://d-nb.info/provenance/plan#vlb |
| spellingShingle | Hall, Kenneth R. 1939- Iglesias-Silva, Gustavo A. Thermodynamics for chemical engineers Thermodynamik (DE-588)4059827-5 gnd |
| subject_GND | (DE-588)4059827-5 |
| title | Thermodynamics for chemical engineers |
| title_auth | Thermodynamics for chemical engineers |
| title_exact_search | Thermodynamics for chemical engineers |
| title_exact_search_txtP | Thermodynamics for chemical engineers |
| title_full | Thermodynamics for chemical engineers Kenneth R. Hall, Gustavo A. Iglesias-Silva |
| title_fullStr | Thermodynamics for chemical engineers Kenneth R. Hall, Gustavo A. Iglesias-Silva |
| title_full_unstemmed | Thermodynamics for chemical engineers Kenneth R. Hall, Gustavo A. Iglesias-Silva |
| title_short | Thermodynamics for chemical engineers |
| title_sort | thermodynamics for chemical engineers |
| topic | Thermodynamik (DE-588)4059827-5 gnd |
| topic_facet | Thermodynamik |
| url | http://www.wiley-vch.de/publish/dt/books/ISBN978-3-527-35030-8/ http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=033670215&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT hallkennethr thermodynamicsforchemicalengineers AT iglesiassilvagustavoa thermodynamicsforchemicalengineers AT wileyvch thermodynamicsforchemicalengineers |