Columns for gas chromatography: performance and selection
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, N.J.
Wiley-Interscience
2007
|
| Schlagworte: | |
| Online-Zugang: | Table of contents only Inhaltsverzeichnis |
| Beschreibung: | Includes index. |
| Beschreibung: | XIII, 298 S. Ill., graph. Darst. |
| ISBN: | 9780471740438 |
Internformat
MARC
| LEADER | 00000nam a2200000zc 4500 | ||
|---|---|---|---|
| 001 | BV022447842 | ||
| 003 | DE-604 | ||
| 005 | 20150213 | ||
| 007 | t | ||
| 008 | 070531s2007 xxuad|| |||| 00||| eng d | ||
| 010 | |a 2006026963 | ||
| 020 | |a 9780471740438 |9 978-0-471-74043-8 | ||
| 035 | |a (OCoLC)71006716 | ||
| 035 | |a (DE-599)BVBBV022447842 | ||
| 040 | |a DE-604 |b ger |e aacr | ||
| 041 | 0 | |a eng | |
| 044 | |a xxu |c US | ||
| 049 | |a DE-1102 |a DE-91G |a DE-19 |a DE-83 |a DE-703 | ||
| 050 | 0 | |a QD79.C45 | |
| 082 | 0 | |a 543/.85 | |
| 084 | |a VG 7400 |0 (DE-625)147205:253 |2 rvk | ||
| 084 | |a CHE 234f |2 stub | ||
| 100 | 1 | |a Barry, Eugene F. |e Verfasser |0 (DE-588)173935419 |4 aut | |
| 245 | 1 | 0 | |a Columns for gas chromatography |b performance and selection |c Eugene F. Barry ; Robert L. Grob |
| 264 | 1 | |a Hoboken, N.J. |b Wiley-Interscience |c 2007 | |
| 300 | |a XIII, 298 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes index. | ||
| 650 | 4 | |a Gas chromatography | |
| 650 | 0 | 7 | |a Chromatographiesäule |0 (DE-588)4290388-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Gaschromatographie |0 (DE-588)4019330-5 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Gaschromatographie |0 (DE-588)4019330-5 |D s |
| 689 | 0 | 1 | |a Chromatographiesäule |0 (DE-588)4290388-9 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Grob, Robert Lee |d 1927- |e Verfasser |0 (DE-588)1055790764 |4 aut | |
| 856 | 4 | |u http://www.loc.gov/catdir/toc/ecip0619/2006026963.html |3 Table of contents only | |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015655783&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-015655783 | ||
Datensatz im Suchindex
| _version_ | 1804136526301364224 |
|---|---|
| adam_text | CONTENTS
Preface xi
Acknowledgments xiii
1 Introduction 1
1.1 Evolution of Gas Chromatographie Columns 1
1.2 Central Role Played by the Column 6
1.3 Justification for Column Selection and Care 8
1.4 Literature on Gas Chromatographie Columns 11
1.5 Gas Chromatographie Resources on the Internet 12
References 13
2 Packed Column Gas Chromatography 15
2.1 Introduction 15
2.2 Solid Supports and Adsorbents 15
Supports for Gas-Liquid Chromatography 15
Adsorbents for Gas-Solid Chromatography 22
2.3 Stationary Phases 33
Requirements of a Stationary Phase 33
USP Designation of Stationary Phases 36
Kovats Retention Index 36
McReynolds and Rohrschneider Classifications
of Stationary Phases 41
Evaluation of Column Operation 45
Optimization of Packed Column Separations 53
2.4 Column Preparation 54
Coating Methods 56
Tubing Materials and Dimensions 56
Glass Wool Plugs and Column Fittings 57
Filling the Column 58
Conditioning the Column and Column Care 59
2.5 United States Pharmacopeia and National Formulary
Chromatographie Methods 60
References 91
vii
viii CONTENTS
3 Capillary Column Gas Chromatography 94
3.1 Introduction 94
Significance and Impact of Capillary Gas Chromatography 94
Chronology of Achievements in Capillary Gas Chromatography 95
Comparison of Packed and Capillary Columns 98
3.2 Capillary Column Technology 100
Capillary Column Materials 100
Fused Silica and Other Glasses 100
Extrusion of a Fused-Silica Capillary Column 103
Aluminum-Clad Fused-Silica Capillary Columns 106
Fused-Silica-Lined Stainless Steel Capillary Columns 106
3.3 Preparation of Fused-Silica Capillary Columns 110
Silanol Deactivation Procedures 110
Static Coating of Capillary Columns 116
Capillary Cages 116
Test Mixtures for Monitoring Column Performance 117
Diagnostic Role Played by Components of Test Mixtures 119
3.4 Chromatographie Performance of Capillary Columns 122
Golay Equation Versus the van Deemter Expression 122
Choice of Carrier Gas 124
Measurement of Linear Velocity and Flow Rate 126
Effect of Carrier Gas Viscosity on Linear Velocity 127
Phase Ratio 129
Coating Efficiency 132
3.5 Stationary-Phase Selection for Capillary Gas Chromatography 132
Requirements 132
History 132
Comparison of Columns from Manufacturers 134
Polysiloxane Phases 140
Polyethylene Glycol Phases 141
Cross-Linked Versus Chemically Bonded Phase 142
Chemical Bonding 149
MS-Grade Phases Versus Polysilarylene or Polysilphenylene
Phases 150
Sol-Gel Stationary Phases 150
Phenylpolycarborane-Siloxane Phases 151
3.6 Specialty Columns 153
s EPA Methods 153
CONTENTS ix
Chiral Stationary Phases 153
Gas-Solid Adsorption Capillary Columns: PLOT Columns 156
3.7 Capillary Column Selection 159
Practical Considerations of Column Diameter, Film Thickness,
and Column Length 159
Capillary Columns of 0.53 mm i.d.: Megabore Columns 165
Correlation of Column Dimensions and Film Thickness with
Parameters in the Fundamental Resolution Equation 167
Column Selection for Gas Chromatography by Specifications 172
3.8 Column Installation and Care 186
Carrier Gas Purifiers 186
Ferrule Materials and Fittings 187
Column Installation 191
Column Conditioning 192
Column Bleed 194
Retention Gap and Guard Columns 196
Column Fatigue and Regeneration 200
3.9 Special Gas Chromatographie Techniques 200
Simulated Distillation 200
Multidimensional Gas Chromatography 201
Computer Modeling of Stationary Phases 203
References 204
4 Column Oven Temperature Control 210
4.1 Thermal Performance Variables and Electronic Considerations 210
4.2 Advantages of Temperature Programming over
Isothermal Operation 211
4.3 Oven Temperature Profiles for Programmed-Temperature
Gas Chromatography 212
4.4 Role of Computer Assistance in Optimizing Separations
in Gas Chromatography 214
DryLab (LC Resources) 214
ProezGC (Restek Corporation) 215
GC-SOS (Chem SW) 216
4.5 Fast or High-Speed Gas Chromatography 217
Selectivity Tuning 219
Resistively Heated Columns and Column Jackets 223
4.6 Subambient Oven Temperature Control 228
References 229
X CONTENTS
Selected References 230
Appendix A: Guide to Selection of Packed Columns 232
Appendix B: Column Selection 277
Index 281
|
| adam_txt |
CONTENTS
Preface xi
Acknowledgments xiii
1 Introduction 1
1.1 Evolution of Gas Chromatographie Columns 1
1.2 Central Role Played by the Column 6
1.3 Justification for Column Selection and Care 8
1.4 Literature on Gas Chromatographie Columns 11
1.5 Gas Chromatographie Resources on the Internet 12
References 13
2 Packed Column Gas Chromatography 15
2.1 Introduction 15
2.2 Solid Supports and Adsorbents 15
Supports for Gas-Liquid Chromatography 15
Adsorbents for Gas-Solid Chromatography 22
2.3 Stationary Phases 33
Requirements of a Stationary Phase 33
USP Designation of Stationary Phases 36
Kovats Retention Index 36
McReynolds and Rohrschneider Classifications
of Stationary Phases 41
Evaluation of Column Operation 45
Optimization of Packed Column Separations 53
2.4 Column Preparation 54
Coating Methods 56
Tubing Materials and Dimensions 56
Glass Wool Plugs and Column Fittings 57
Filling the Column 58
Conditioning the Column and Column Care 59
2.5 United States Pharmacopeia and National Formulary
Chromatographie Methods 60
References 91
vii
viii CONTENTS
3 Capillary Column Gas Chromatography 94
3.1 Introduction 94
Significance and Impact of Capillary Gas Chromatography 94
Chronology of Achievements in Capillary Gas Chromatography 95
Comparison of Packed and Capillary Columns 98
3.2 Capillary Column Technology 100
Capillary Column Materials 100
Fused Silica and Other Glasses 100
Extrusion of a Fused-Silica Capillary Column 103
Aluminum-Clad Fused-Silica Capillary Columns 106
Fused-Silica-Lined Stainless Steel Capillary Columns 106
3.3 Preparation of Fused-Silica Capillary Columns 110
Silanol Deactivation Procedures 110
Static Coating of Capillary Columns 116
Capillary Cages 116
Test Mixtures for Monitoring Column Performance 117
Diagnostic Role Played by Components of Test Mixtures 119
3.4 Chromatographie Performance of Capillary Columns 122
Golay Equation Versus the van Deemter Expression 122
Choice of Carrier Gas 124
Measurement of Linear Velocity and Flow Rate 126
Effect of Carrier Gas Viscosity on Linear Velocity 127
Phase Ratio 129
Coating Efficiency 132
3.5 Stationary-Phase Selection for Capillary Gas Chromatography 132
Requirements 132
History 132
Comparison of Columns from Manufacturers 134
Polysiloxane Phases 140
Polyethylene Glycol Phases 141
Cross-Linked Versus Chemically Bonded Phase 142
Chemical Bonding 149
MS-Grade Phases Versus Polysilarylene or Polysilphenylene
Phases 150
Sol-Gel Stationary Phases 150
Phenylpolycarborane-Siloxane Phases 151
3.6 Specialty Columns 153
s EPA Methods 153
CONTENTS ix
Chiral Stationary Phases 153
Gas-Solid Adsorption Capillary Columns: PLOT Columns 156
3.7 Capillary Column Selection 159
Practical Considerations of Column Diameter, Film Thickness,
and Column Length 159
Capillary Columns of 0.53 mm i.d.: Megabore Columns 165
Correlation of Column Dimensions and Film Thickness with
Parameters in the Fundamental Resolution Equation 167
Column Selection for Gas Chromatography by Specifications 172
3.8 Column Installation and Care 186
Carrier Gas Purifiers 186
Ferrule Materials and Fittings 187
Column Installation 191
Column Conditioning 192
Column Bleed 194
Retention Gap and Guard Columns 196
Column Fatigue and Regeneration 200
3.9 Special Gas Chromatographie Techniques 200
Simulated Distillation 200
Multidimensional Gas Chromatography 201
Computer Modeling of Stationary Phases 203
References 204
4 Column Oven Temperature Control 210
4.1 Thermal Performance Variables and Electronic Considerations 210
4.2 Advantages of Temperature Programming over
Isothermal Operation 211
4.3 Oven Temperature Profiles for Programmed-Temperature
Gas Chromatography 212
4.4 Role of Computer Assistance in Optimizing Separations
in Gas Chromatography 214
DryLab (LC Resources) 214
ProezGC (Restek Corporation) 215
GC-SOS (Chem SW) 216
4.5 Fast or High-Speed Gas Chromatography 217
Selectivity Tuning 219
Resistively Heated Columns and Column Jackets 223
4.6 Subambient Oven Temperature Control 228
References 229
X CONTENTS
Selected References 230
Appendix A: Guide to Selection of Packed Columns 232
Appendix B: Column Selection 277
Index 281 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Barry, Eugene F. Grob, Robert Lee 1927- |
| author_GND | (DE-588)173935419 (DE-588)1055790764 |
| author_facet | Barry, Eugene F. Grob, Robert Lee 1927- |
| author_role | aut aut |
| author_sort | Barry, Eugene F. |
| author_variant | e f b ef efb r l g rl rlg |
| building | Verbundindex |
| bvnumber | BV022447842 |
| callnumber-first | Q - Science |
| callnumber-label | QD79 |
| callnumber-raw | QD79.C45 |
| callnumber-search | QD79.C45 |
| callnumber-sort | QD 279 C45 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VG 7400 |
| classification_tum | CHE 234f |
| ctrlnum | (OCoLC)71006716 (DE-599)BVBBV022447842 |
| dewey-full | 543/.85 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 543 - Analytical chemistry |
| dewey-raw | 543/.85 |
| dewey-search | 543/.85 |
| dewey-sort | 3543 285 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| discipline_str_mv | Chemie / Pharmazie Chemie |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01763nam a2200445zc 4500</leader><controlfield tag="001">BV022447842</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20150213 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">070531s2007 xxuad|| |||| 00||| eng d</controlfield><datafield tag="010" ind1=" " ind2=" "><subfield code="a">2006026963</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9780471740438</subfield><subfield code="9">978-0-471-74043-8</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)71006716</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV022447842</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">aacr</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="044" ind1=" " ind2=" "><subfield code="a">xxu</subfield><subfield code="c">US</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-1102</subfield><subfield code="a">DE-91G</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-83</subfield><subfield code="a">DE-703</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD79.C45</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">543/.85</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VG 7400</subfield><subfield code="0">(DE-625)147205:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 234f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Barry, Eugene F.</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)173935419</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Columns for gas chromatography</subfield><subfield code="b">performance and selection</subfield><subfield code="c">Eugene F. Barry ; Robert L. Grob</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Hoboken, N.J.</subfield><subfield code="b">Wiley-Interscience</subfield><subfield code="c">2007</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XIII, 298 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">Includes index.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Gas chromatography</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Chromatographiesäule</subfield><subfield code="0">(DE-588)4290388-9</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Gaschromatographie</subfield><subfield code="0">(DE-588)4019330-5</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Gaschromatographie</subfield><subfield code="0">(DE-588)4019330-5</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Chromatographiesäule</subfield><subfield code="0">(DE-588)4290388-9</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Grob, Robert Lee</subfield><subfield code="d">1927-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1055790764</subfield><subfield code="4">aut</subfield></datafield><datafield tag="856" ind1="4" ind2=" "><subfield code="u">http://www.loc.gov/catdir/toc/ecip0619/2006026963.html</subfield><subfield code="3">Table of contents only</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015655783&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-015655783</subfield></datafield></record></collection> |
| id | DE-604.BV022447842 |
| illustrated | Illustrated |
| index_date | 2024-07-02T17:35:15Z |
| indexdate | 2024-07-09T20:57:48Z |
| institution | BVB |
| isbn | 9780471740438 |
| language | English |
| lccn | 2006026963 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015655783 |
| oclc_num | 71006716 |
| open_access_boolean | |
| owner | DE-1102 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-83 DE-703 |
| owner_facet | DE-1102 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-83 DE-703 |
| physical | XIII, 298 S. Ill., graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Wiley-Interscience |
| record_format | marc |
| spelling | Barry, Eugene F. Verfasser (DE-588)173935419 aut Columns for gas chromatography performance and selection Eugene F. Barry ; Robert L. Grob Hoboken, N.J. Wiley-Interscience 2007 XIII, 298 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes index. Gas chromatography Chromatographiesäule (DE-588)4290388-9 gnd rswk-swf Gaschromatographie (DE-588)4019330-5 gnd rswk-swf Gaschromatographie (DE-588)4019330-5 s Chromatographiesäule (DE-588)4290388-9 s DE-604 Grob, Robert Lee 1927- Verfasser (DE-588)1055790764 aut http://www.loc.gov/catdir/toc/ecip0619/2006026963.html Table of contents only HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015655783&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Barry, Eugene F. Grob, Robert Lee 1927- Columns for gas chromatography performance and selection Gas chromatography Chromatographiesäule (DE-588)4290388-9 gnd Gaschromatographie (DE-588)4019330-5 gnd |
| subject_GND | (DE-588)4290388-9 (DE-588)4019330-5 |
| title | Columns for gas chromatography performance and selection |
| title_auth | Columns for gas chromatography performance and selection |
| title_exact_search | Columns for gas chromatography performance and selection |
| title_exact_search_txtP | Columns for gas chromatography performance and selection |
| title_full | Columns for gas chromatography performance and selection Eugene F. Barry ; Robert L. Grob |
| title_fullStr | Columns for gas chromatography performance and selection Eugene F. Barry ; Robert L. Grob |
| title_full_unstemmed | Columns for gas chromatography performance and selection Eugene F. Barry ; Robert L. Grob |
| title_short | Columns for gas chromatography |
| title_sort | columns for gas chromatography performance and selection |
| title_sub | performance and selection |
| topic | Gas chromatography Chromatographiesäule (DE-588)4290388-9 gnd Gaschromatographie (DE-588)4019330-5 gnd |
| topic_facet | Gas chromatography Chromatographiesäule Gaschromatographie |
| url | http://www.loc.gov/catdir/toc/ecip0619/2006026963.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015655783&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT barryeugenef columnsforgaschromatographyperformanceandselection AT grobrobertlee columnsforgaschromatographyperformanceandselection |