Cellulose hydrolysis:
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
1987
|
| Series: | Biotechnology monographs
3 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIII, 198 S. |
| ISBN: | 0387176713 3540176713 |
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MARC
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Record in the Search Index
| _version_ | 1823676174638776320 |
|---|---|
| adam_text |
L T Fan M M Gharpuray Y -H Lee
Cellulose Hydrolysis
With 65 Figures
Springer-Verlag
Berlin Heidelberg New York
London Paris Tokyo
PiHiofrhük und Archer
ztUCHEMING
Oc rm stadt
Table of Contents
1 Introduction 1
References 3
2 Nature of Cellulosic Material 5
2 1 Components of Cellulosic Materials 5
211 Extraneous Materials 5
212 Polysaccharides 6
213 Lignin 8
2 2 Composition of Wood and Straw 11
2 3 Structure of Plant Cell Walls 11
2 4 Structure of Cellulose 14
241 Chemical and Molecular Structure of Cellulose 14
242 Structure and Morphology of Cellulose Fibers 16
References 19
3 Enzymatic Hydrolysis 21
3 1 Nature of Lignocellulosic Structural Resistance 21
311 Degree of Water Swelling of Cellulose Fiber 21
312 Crystallinity of Cellulose 22
313 Molecular Structure of Cellulose 23
314 Extraneous Material - Lignin 24
315 Presence of Substituent Groups 26
316 Capillary Structure of Cellulose 26
3 2 Properties and Mode of Cellulase Biodegradation 29
321 Effect of Cellulase on some Properties of Cellulose Fibers 39
3211 Fragmentation of Cellulose Fibers 39
3212 Swelling of Cellulose Fibers and the Swelling Factor 40
322 Mode of Action of the Cellulase 41
3221 (Q-CJ Concept 41
3222 /?-l,4-Glucan Cellobiohydrolase 43
XI
3223 Cx Components 45
3224 ß-Glucosidase 47
3225 Synergism Among Components 48
323 Physical Properties of Cellulase 51
3231 Molecular Weights of Cellulase Components 51
3232 Diffusion Coefficient and Sedimentation Constant of Cellulase 52
3233 Size and Shape of Cellulase Molecules 52
3 3 Pretreatment Methods 52
331 Physical Pretreatments 53
3311 Milling and Grinding 54
3312 Pyrolysis 57
3313 High Energy Radiation 58
3314 High Pressure Steaming 58
3315 Extrusion and Expansion 59
3316 Microwave Treatment 60
332 Chemical Pretreatments 60
3321 Alkalis 60
3322 Acids 61
3323 Gases 63
3324 Oxidizing Agents 64
3325 Cellulose Solvents 64
3326 Solvent Extraction 65
3327 Swelling Agents 66
333 Biological Pretreatments 67
334 Economic Analysis of Pretreatments 68
3 4 Kinetics of Enzymatic Hydrolysis of Cellulose 69
341 Kinetic Characteristics of the
Heterogeneous Cellulose-Cellulase System 71
3411 Mass Transfer Limitation - Diffusion of Enzyme 71
3412 Adsorption and Desorption of Enzyme 71
3413 Surface Reaction, Fragmentation,
and Changes of Surface Area During Hydrolysis 74
3414 Product Inhibition and its Mechanism 76
342 Kinetic Models of Insoluble Cellulose Hydrolysis by Cellulase 78
3421 Empirical Representations of the Kinetics of Enzymatic Hydrolysis 78
3422 Michaelis-Menten Mechanism Applied
to an Insoluble Cellulose-Cellulase System 79
3423 McLaren’s Approach to Enzyme Reactions
in a Structurally Restricted System 85
3424 Kinetic Models Based on the Combination of the Enzyme
Adsorption Equation and the Michaelis-Menten Type Equation 87
3425 Kinetic Model Based on the Depolymerization Mechanism 92
3426 Distributed Parameter Kinetic Models 94
3427 Mechanistic Kinetic Model 97
3428 Miscellaneous Models 102
XII
343 Kinetics of Cellulases on /M ,4-Oligoglucosides 104
344 Kinetics of ß-Glucosidase 108
Nomenclature 109
References 112
4 Acid Hydrolysis of Cellulose 121
4 1 Mechanism of Acid Hydrolysis 121
411 Course of Hydrolysis Reaction 121
412 Identification of Mechanism 127
413 Degree of Polymerization 128
414 Recrystallization 131
4 2 Kinetics of Acid Hydrolysis of Cellulose 133
421 Homogeneous Kinetics 133
422 Heterogeneous Kinetics 138
Nomenclature 144
References 145
5 Design and Economic Evaluation of Cellulose Hydrolysis Processes 149
5 1 Enzymatic Hydrolysis 149
511 Pure Cellulose Substrate 149
512 Lignocellulosic Substrate 157
5 2 Acid Hydrolysis 164
521 Dilute Sulfuric Acid Processes 164
522 Concentrated Sulfuric Acid Processes 170
523 Hydrochloric Acid Processes 172
524 Hydrofluoric Acid Process 174
Nomenclature 185
References 186
6 Epilogue 189
Author Index 191
Subject Index 197
XIII |
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| author | Fan, Liangzeng Gharpuray, Mahendra M. Lee, Yong-Hyun |
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| id | DE-604.BV000702578 |
| illustrated | Not Illustrated |
| indexdate | 2025-02-10T13:12:09Z |
| institution | BVB |
| isbn | 0387176713 3540176713 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-000438577 |
| oclc_num | 721883290 |
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| owner | DE-12 DE-355 DE-BY-UBR DE-188 |
| owner_facet | DE-12 DE-355 DE-BY-UBR DE-188 |
| physical | XIII, 198 S. |
| psigel | TUB-nvmb |
| publishDate | 1987 |
| publishDateSearch | 1987 |
| publishDateSort | 1987 |
| publisher | Springer |
| record_format | marc |
| series | Biotechnology monographs |
| series2 | Biotechnology monographs |
| spelling | Fan, Liangzeng Verfasser aut Cellulose hydrolysis L. T. Fan ; M. M. Gharpuray ; Y.-H. Lee Berlin [u.a.] Springer 1987 XIII, 198 S. txt rdacontent n rdamedia nc rdacarrier Biotechnology monographs 3 Anatomi Fysiologi Morfologi Biologi Hydrolyse (DE-588)4160918-9 gnd rswk-swf Cellulose (DE-588)4147454-5 gnd rswk-swf Cellulose (DE-588)4147454-5 s Hydrolyse (DE-588)4160918-9 s DE-604 Gharpuray, Mahendra M. Verfasser aut Lee, Yong-Hyun Verfasser aut Biotechnology monographs 3 (DE-604)BV000017604 3 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000438577&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fan, Liangzeng Gharpuray, Mahendra M. Lee, Yong-Hyun Cellulose hydrolysis Biotechnology monographs Anatomi Fysiologi Morfologi Biologi Hydrolyse (DE-588)4160918-9 gnd Cellulose (DE-588)4147454-5 gnd |
| subject_GND | (DE-588)4160918-9 (DE-588)4147454-5 |
| title | Cellulose hydrolysis |
| title_auth | Cellulose hydrolysis |
| title_exact_search | Cellulose hydrolysis |
| title_full | Cellulose hydrolysis L. T. Fan ; M. M. Gharpuray ; Y.-H. Lee |
| title_fullStr | Cellulose hydrolysis L. T. Fan ; M. M. Gharpuray ; Y.-H. Lee |
| title_full_unstemmed | Cellulose hydrolysis L. T. Fan ; M. M. Gharpuray ; Y.-H. Lee |
| title_short | Cellulose hydrolysis |
| title_sort | cellulose hydrolysis |
| topic | Anatomi Fysiologi Morfologi Biologi Hydrolyse (DE-588)4160918-9 gnd Cellulose (DE-588)4147454-5 gnd |
| topic_facet | Anatomi Fysiologi Morfologi Biologi Hydrolyse Cellulose |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=000438577&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000017604 |
| work_keys_str_mv | AT fanliangzeng cellulosehydrolysis AT gharpuraymahendram cellulosehydrolysis AT leeyonghyun cellulosehydrolysis |