Functionalization of group III-nitrides for biosensor applications:
Gespeichert in:
1. Verfasser: | |
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Format: | Abschlussarbeit Buch |
Sprache: | English |
Veröffentlicht: |
Garching
Verein zur Förderung des Walter Schottky Inst. der Techn. Univ. München e.V.
2011
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Ausgabe: | 1. Aufl. |
Schriftenreihe: | Selected topics of semiconductor physics and technology
128 |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | VI, 215 S. Ill., graph. Darst. |
ISBN: | 9783941650282 |
Internformat
MARC
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245 | 1 | 0 | |a Functionalization of group III-nitrides for biosensor applications |c Barbara Annemarie Kathrin Baur |
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264 | 1 | |a Garching |b Verein zur Förderung des Walter Schottky Inst. der Techn. Univ. München e.V. |c 2011 | |
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Datensatz im Suchindex
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adam_text | IMAGE 1
CONTENTS
ZUSAMMENFASSUNG I
1 INTRODUCTION 1
1.1 BIOSENSOR CONCEPTS 2
1.2 GROUP M-NITRIDES FOR BIOSENSING APPLICATIONS 4
1.3 SCOPE OF THIS WORK 9
2 CHEMICAL FUNCTIONALIZATION OF GROUP HI-NITRIDES 11
2.1 INTRODUCTION TO ORGANIC MONOLAYERS 12
2.1.1 CONCEPT OF SELF-ASSEMBLED MONOLAYERS 12
2.1.2 SILANIZATION 14
2.2 SURFACE PRETREATMENT - OH-TERMINATION OF GAN AND A1N 17
2.2.1 HYDROXYLATION METHODS AND SAMPLE PREPARATION 18
2.2.2 ANALYSIS OF HYDROXYLATED GROUP ILL-NITRIDES 19
2.3 APTES-MODIFIED GAN AND A1N SURFACES 32
2.3.1 APTES SAM FORMATION 32
2.3.2 STRUCTURAL AND CHEMICAL ANALYSIS 33
2.4 ODTMS-MODIFIED GAN AND A1N SURFACES 49
2.4.1 SAM FORMATION 50
2.4.2 STRUCTURAL AND CHEMICAL ANALYSIS 50
2.5 PHOTOLYSIS OF SILANESAMS 61
2.5.1 MICROPATTEMED SILANE SAMS ON GAN 62
2.5.2 UV-INDUCED DEGRADATION OF ODTMS SAMS ON GAN 63
2.6 CONCLUSION 69
TV
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1013285808
DIGITALISIERT DURCH
IMAGE 2
CONTENTS V
3 IMMOBILIZATION OF BIOFUNCTIONAL LAYERS 71
3.1 COUPLING VIA SCHIFF-BASE FORMATION 72
3.2 ATTACHMENT OF OLIGO-NUCLEOTIDES ON GAN 73
3.3 ENZYMES IMMOBILIZED ON GAN 74
3.3.1 ENZYME FUNCTION 76
3.3.2 KINETICS OF ENZYME-CATALYZED REACTIONS 76
3.3.3 IMMOBILIZATION OF ENZYMES ON GAN 78
3.3.4 ACTIVITY OF IMMOBILIZED PENICILLINASE 82
3.4 CONCLUSION 89
4 ELECTRONIC PROPERTIES OF SILANE SAMS ON GAN 93
4.1 MOLECULAR INTERACTIONS WITH SEMICONDUCTOR SURFACES 95
4.1.1 SEMICONDUCTOR SURFACES 95
4.1.2 CHEMISORBED MOLECULES 97
4.2 MIS-JUNCTIONS 99
4.2.1 CARRIER TRANSPORT MECHANISMS IN SCHOTTKY DIODES 99
4.2.2 ELECTRONIC CONDUCTION THROUGH SAMS 103
4.2.3 CAPACITANCE-VOLTAGE MEASUREMENTS 104
4.3 ELECTRICAL CHARACTERIZATION OF ODTMS-MODIFIED GAN 106
4.3.1 I-U CHARACTERISTICS 107
4.3.2 CAPACITANCE-VOLTAGE CHARACTERISTICS 114
4.4 IMPACT OF UV ILLUMINATION ON ELECTRONIC PROPERTIES 119
4.5 CONCLUSION 122
5 ENZYME MODIFIED ALGAN/GAN FETS 123
5.1 REVIEW 125
5.2 DETECTION MECHANISM 126
5.3 ELECTROCHEMICAL MEASUREMENT SETUP 128
5.4 PENICILLINASE MODIFIED ALGAN/GAN EGFETS 129
5.4.1 PROCESSING OF TRANSDUCER DEVICES 129
5.4.2 IMMOBILIZATION OF PENICILLINASE 130
5.4.3 CHARACTERIZATION OF FUNCTIONALIZED ALGAN/GAN EGFETS 132 5.5
ELECTRONIC RESPONSE OF ENZYMATIC REACTION 136
5.5.1 TRANSIENT RESPONSE 136
IMAGE 3
VI CONTENTS
5.5.2 RESPONSE CHARACTERISTICS OF C-ENFETS AND P-ENFETS 140
5.6 KINETIC MODEL OF PH-BASED ENFETS 143
5.6.1 REVIEW 143
5.6.2 PROPOSED MODEL 145
5.6.3 SUMMARY 156
5.7 EXPERIMENTAL VERIFICATION OF THE PROPOSED MODEL 157
5.7.1 INFLUENCE OF ENZYME KINETICS 157
5.7.2 INFLUENCE OF RELATIVE MASS TRANSPORT 161
5.7.3 INFLUENCE OF BUFFER CONCENTRATION 163
5.7.4 INFLUENCE OF PH OF ANALYZED TEST SOLUTION 164
5.7.5 SUMMARY 167
5.8 STABILITY OF PENICILLINASE-ALGAN/GAN EGFETS 168
5.8.1 DEGRADATION 169
5.8.2 STABILIZED ENZYME LAYER 170
5.8.3 LIFETIME FACTORS 171
5.8.4 SUMMARY 174
5.9 CONCLUSION 175
6 SUMMARY AND OUTLOOK 177
APPENDIX - EXPERIMENTAL SETUPS 183
REFERENCES 188
LIST OF PUBLICATIONS 211
ACKNOWLEDGEMENTS 213
|
any_adam_object | 1 |
author | Baur, Barbara Annemarie Kathrin |
author_facet | Baur, Barbara Annemarie Kathrin |
author_role | aut |
author_sort | Baur, Barbara Annemarie Kathrin |
author_variant | b a k b bak bakb |
building | Verbundindex |
bvnumber | BV037481228 |
classification_tum | CHE 180d PHY 693d PHY 855d |
ctrlnum | (OCoLC)734082433 (DE-599)BVBBV037481228 |
dewey-full | 541.33 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 541 - Physical chemistry |
dewey-raw | 541.33 |
dewey-search | 541.33 |
dewey-sort | 3541.33 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Physik Biologie Chemie |
edition | 1. Aufl. |
format | Thesis Book |
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indexdate | 2024-07-09T23:25:04Z |
institution | BVB |
isbn | 9783941650282 |
language | English |
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spelling | Baur, Barbara Annemarie Kathrin Verfasser aut Functionalization of group III-nitrides for biosensor applications Barbara Annemarie Kathrin Baur 1. Aufl. Garching Verein zur Förderung des Walter Schottky Inst. der Techn. Univ. München e.V. 2011 VI, 215 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Selected topics of semiconductor physics and technology 128 Zugl.: München, Techn. Univ., Diss., 2011 Borgruppe (DE-588)4326018-4 gnd rswk-swf Halbleiter (DE-588)4022993-2 gnd rswk-swf Nitride (DE-588)4171929-3 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Biosensor (DE-588)4193016-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Borgruppe (DE-588)4326018-4 s Halbleiter (DE-588)4022993-2 s Nitride (DE-588)4171929-3 s Oberflächenchemie (DE-588)4126166-5 s Biosensor (DE-588)4193016-2 s DE-604 Selected topics of semiconductor physics and technology 128 (DE-604)BV011499438 128 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022632800&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Baur, Barbara Annemarie Kathrin Functionalization of group III-nitrides for biosensor applications Selected topics of semiconductor physics and technology Borgruppe (DE-588)4326018-4 gnd Halbleiter (DE-588)4022993-2 gnd Nitride (DE-588)4171929-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd Biosensor (DE-588)4193016-2 gnd |
subject_GND | (DE-588)4326018-4 (DE-588)4022993-2 (DE-588)4171929-3 (DE-588)4126166-5 (DE-588)4193016-2 (DE-588)4113937-9 |
title | Functionalization of group III-nitrides for biosensor applications |
title_auth | Functionalization of group III-nitrides for biosensor applications |
title_exact_search | Functionalization of group III-nitrides for biosensor applications |
title_full | Functionalization of group III-nitrides for biosensor applications Barbara Annemarie Kathrin Baur |
title_fullStr | Functionalization of group III-nitrides for biosensor applications Barbara Annemarie Kathrin Baur |
title_full_unstemmed | Functionalization of group III-nitrides for biosensor applications Barbara Annemarie Kathrin Baur |
title_short | Functionalization of group III-nitrides for biosensor applications |
title_sort | functionalization of group iii nitrides for biosensor applications |
topic | Borgruppe (DE-588)4326018-4 gnd Halbleiter (DE-588)4022993-2 gnd Nitride (DE-588)4171929-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd Biosensor (DE-588)4193016-2 gnd |
topic_facet | Borgruppe Halbleiter Nitride Oberflächenchemie Biosensor Hochschulschrift |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022632800&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV011499438 |
work_keys_str_mv | AT baurbarbaraannemariekathrin functionalizationofgroupiiinitridesforbiosensorapplications |