Understanding spin crossover: a contribution
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2011
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext http://edoc.ub.uni-muenchen.de/13169/ https://nbn-resolving.org/urn:nbn:de:bvb:19-131697 Inhaltsverzeichnis |
| Beschreibung: | V, 282 S. graph. Darst. 210 mm x 148 mm, 529 g |
| ISBN: | 9783843900010 3843900019 |
Internformat
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Datensatz im Suchindex
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| adam_text |
IMAGE 1
CONTENTS
CONTENTS I
ABBREVIATIONS ILL
1 INTRODUCTION 1
1.1 THERMAL SPIN TRANSITION 2
1.2 THEORETICAL ASPECTS OF THE SPIN CROSSOVER 4
1.3 DETECTING THE SPIN CROSSOVER 7
2 SUMMARY 9
2.1 THE LIGAND SYSTEM 9
2.2 THE PURPOSEFUL DESIGN OF STEPWISE SPIN TRANSITIONS 11
2.3 SPIN TRANSITIONS IN SOLUTION 14
2.4 THE CRYSTAL CONTACT INDEX 15
2.5 THE SOLVENT EFFECT 15
2.6 A NEW MODEL FOR THE EXPLANATION OF WIDE HYSTERESIS LOOPS 17
2.7 SYNTHESIS OF SCO COMPOUNDS IN A CRYSTAL ENGINEERING-LIKE APPROACH 19
2.8 REFERENCES 21
3 INDIVIDUAL CONTRIBUTION TO JOINT PUBLICATION 27
4 TWO-STEP VERSUS ONE-STEP SPIN TRANSITION IN IRON(II) ID CHAIN
COMPOUNDS 33 4.1 INTRODUCTION 34
4.2 RESULTS 38
4.3 DISCUSSION 59
4.4 CONCLUSION 61
4.5 EXPERIMENTAL SECTION 62
4.6 REFERENCES 66
4.7 SUPPORTING INFORMATION 70
5 X-RAY STRUCTURE AND MAGNETIC PROPERTIES OF DINUCLEAR AND POLYMER
IRON(II) COMPLEXES 75
5.1 INTRODUCTION 76
5.2 RESULTS AND DISCUSSION 78
5.3 CONCLUSION 85
5.4 EXPERIMENTAL SECTION 86
5.5 REFERENCES 89
5.6 SUPPORTING INFORMATION 91
6 X-RAY STRUCTURE AND MAGNETIC PROPERTIES OF TWO NEW IRON(II) ID
COORDINATION POLYMERS WITH BIS(IMIDAZOLYLE)-METHANE AS BRIDGING LIGAND
95
6.1 INTRODUCTION 95
6.2 RESULTS AND DISCUSSION 97
6.3 CONCLUSION 102
6.4 EXPERIMENTAL SECTION 103
6.5 REFERENCES 105
6.6 SUPPORTING INFORMATION 108
7 COMPLETE AND INCOMPLETE SPIN TRANSITIONS IN ID CHAIN IRON(H) COMPOUNDS
I LL 7.1 INTRODUCTION 112
7.2 RESULTS AND DISCUSSION 113
7.3 CONCLUSION 129
7.4 EXPERIMENTAL SECTION 130
7.5 REFERENCES 132
I
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1014217296
DIGITALISIERT DURCH
IMAGE 2
CONTENTS
7.6 SUPPORTING INFORMATION 136
8 A PROMISING NEW SCHIFF BASE-LIKE LIGAND FOR THE SYNTHESIS OF
OCTAHEDRAL IRON(II) SPIN CROSSOVER COMPLEXES 139
8.1 INTRODUCTION 139
8.2 RESULTS AND DISCUSSION 140
8.3 CONCLUSION 146
8.4 EXPERIMENTAL SECTION 147
8.5 REFERENCES 149
8.6 SUPPORTING INFORMATION 151
9 COMPLETE TWO-STEP SPIN-TRANSITION IN A ID CHAIN IRON(II) COMPLEX WITH
110 K WIDE INTERMEDIATE PLATEAU 153
9.1 INTRODUCTION 154
9.2 RESULTS 156
9.3 DISCUSSION 170
9.4 CONCLUSION 171
9.5 EXPERIMENTAL SECTION 172
9.6 REFERENCES 175
9.7 SUPPORTING INFORMATION 179
10 INFLUENCE OF HYDROGEN BONDING ON THE HYSTERESIS WIDTH IN IRON(II)
SPIN CROSSOVER COMPLEXES 181
10.1 INTRODUCTION 182
10.2 RESULTS 184
10.3 DISCUSSION 202
10.4 CONCLUSION 207
10.5 EXPERIMENTAL SECTION 208
10.6 REFERENCES 212
10.7 SUPPORTING INFORMATION 217
11 UNUSUAL STEPPED SPIN TRANSITIONS AT IRON(II) COORDINATION POLYMERS
WITH ZIGZAG- STRUCTURE 221
11.1 INTRODUCTION 221
11.2 RESULTS 223
11.3 CONCLUSION 234
11.4 EXPERIMENTAL SECTION 235
11.5 REFERENCES 238
11.6 SUPPORTING INFORMATION 241
12 INCREASING THE HYSTERESIS WIDTH OF IRON(II) SCO COMPOUNDS IN A
CRYSTAL ENGINEERING-LIKE APPROACH 243
12.1 INTRODUCTION 243
12.2 RESULTS 246
12.2.1 THE LIGAND SYSTEM H 2L1 247
12.2.2 THE LIGAND SYSTEM H 4L2 256
12.2.3 THE LIGAND SYSTEM H 2L3 260
12.3 DISCUSSION 267
12.4 CONCLUSION 269
12.5 EXPERIMENTAL SECTION 270
12.6 REFERENCES 278
12.7 SUPPORTING INFORMATION 281 |
| any_adam_object | 1 |
| author | Bauer, Wolfgang 1981- |
| author_GND | (DE-588)1014474477 |
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| dewey-full | 541.28 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.28 |
| dewey-search | 541.28 |
| dewey-sort | 3541.28 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| edition | 1. Aufl. |
| format | Thesis Book |
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| spelling | Bauer, Wolfgang 1981- Verfasser (DE-588)1014474477 aut Understanding spin crossover a contribution Wolfgang Manfred Bauer 1. Aufl. München Verl. Dr. Hut 2011 V, 282 S. graph. Darst. 210 mm x 148 mm, 529 g txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Univ., Diss., 2011 Spindynamik (DE-588)4417075-0 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Spindynamik (DE-588)4417075-0 s Übergangsmetallkomplexe (DE-588)4131837-7 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:19-131697 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3865791&prov=M&dok_var=1&dok_ext=htm Verlag kostenfrei Inhaltstext http://edoc.ub.uni-muenchen.de/13169/ https://nbn-resolving.org/urn:nbn:de:bvb:19-131697 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024389642&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bauer, Wolfgang 1981- Understanding spin crossover a contribution Spindynamik (DE-588)4417075-0 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4417075-0 (DE-588)4131837-7 (DE-588)4113937-9 |
| title | Understanding spin crossover a contribution |
| title_auth | Understanding spin crossover a contribution |
| title_exact_search | Understanding spin crossover a contribution |
| title_full | Understanding spin crossover a contribution Wolfgang Manfred Bauer |
| title_fullStr | Understanding spin crossover a contribution Wolfgang Manfred Bauer |
| title_full_unstemmed | Understanding spin crossover a contribution Wolfgang Manfred Bauer |
| title_short | Understanding spin crossover |
| title_sort | understanding spin crossover a contribution |
| title_sub | a contribution |
| topic | Spindynamik (DE-588)4417075-0 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Spindynamik Übergangsmetallkomplexe Hochschulschrift |
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