Polymers: chemistry and physics of modern materials
"Extensively revised and updated to keep abreast of recent advances, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide a broad-based, high-information text at an introductory, reader-friendly level that illustrates the multidisciplinary nature of polymer sc...
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| Format: | Buch |
| Sprache: | English |
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Boca Raton, FL
CRC Press
2008
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| Ausgabe: | 3. ed. |
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| Zusammenfassung: | "Extensively revised and updated to keep abreast of recent advances, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide a broad-based, high-information text at an introductory, reader-friendly level that illustrates the multidisciplinary nature of polymer science. Adding or amending roughly 50 percent of the material, this new edition strengthens the original's aim to contribute a comprehensive treatment by offering a wide and balanced selection of topics across all aspects of the chemistry and physics of polymer science, from synthesis and physical properties to applications."--BOOK JACKET. |
| Beschreibung: | 499 S. Ill., graph. Darst. |
| ISBN: | 9780849398131 0849398134 |
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Datensatz im Suchindex
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| adam_text | POLYMERS: CHEMISTRY AND PHYSICS OF MODERN MATERIALS THIRD EDITION J.M.G.
COWIE HERIOT-WATT UNIVERSITY SCOTLAND,UK VALERIA ARRIGHI HERIOT-WATT
UNIVERSITY SCOTLAND,UK CONTENTS PREFACE XV THE AUTHORS XVII CHAPTER 1
INTRODUCTION 1 1.1 BIRTH OF A CONCEPT 1 1.2 SOME BASIC DEFINITIONS 2 1.3
SYNTHESIS OF POLYMERS 4 1.4 NOMENCLATURE 4 1.5 AVERAGE MOLAR MASSES AND
DISTRIBUTIONS 8 1.6 SIZE AND SHAPE 10 1.7 CONFIGURATION 12 1.8 THE GLASS
TRANSITION TEMPERATURE T G AND THE MELTING TEMPERATURE T M .... 14 1.9
ELASTOMERS, FIBERS, AND PLASTICS 16 1.10 FIBER-FORMING POLYMERS 18 1.11
PLASTICS 18 1.12 THERMOSETTING POLYMERS 21 1.13 ELASTOMERS 21 PROBLEMS
25 REFERENCES 27 BIBLIOGRAPHY 27 CHAPTER 2 STEP-GROWTH POLYMERIZATION 29
2.1 GENERAL REACTIONS 29 2.2 REACTIVITY OF FUNCTIONAL GROUPS , 30 2.3
CAROTHERS EQUATION 31 2.4 CONTROL OF THE MOLAR MASS 32 2.5
STOICHIOMETRIC CONTROL OF M* 34 2.6 KINETICS 36 2.7 MOLAR MASS
DISTRIBUTION IN LINEAR SYSTEMS 38 2.8 AVERAGE MOLAR MASSES 39 2.9
CHARACTERISTICS OF STEP-GROWTH POLYMERIZATION 40 2.10 TYPICAL
STEP-GROWTH REACTIONS 40 2.11 RING FORMATION 41 2.12 NONLINEAR
STEP-GROWTH REACTIONS 42 2.13 STATISTICAL DERIVATION 43 2.14 COMPARISON
WITH EXPERIMENT 44 2.15 POLYURETHANES 46 2.16 THERMOSETTING POLYMERS 49
PROBLEMS 52 REFERENCES 56 BIBLIOGRAPHY 56 CHAPTER 3 FREE-RADICAL
ADDITION POLYMERIZATION 57 3.1 ADDITION POLYMERIZATION 57 3.2 CHOICE OF
INITIATORS 57 3.3 FREE-RADICAL POLYMERIZATION 58 3.4 INITIATORS 59 3.4.1
INITIATOR EFFICIENCY 60 3.5 CHAIN GROWTH 62 3.6 TERMINATION 62 3.7
STEADY-STATE KINETICS 63 3.8 HIGH-CONVERSION BULK POLYMERIZATIONS 65 3.9
CHAIN TRANSFER 67 3.9.1 CONSEQUENCES OF CHAIN TRANSFER 70 3.10
INHIBITORS AND RETARDERS 70 3.11 ACTIVATION ENERGIES AND THE EFFECT OF
TEMPERATURE 72 3.12 THERMODYNAMICS OF RADICAL POLYMERIZATION 73 3.13
HEATS OF POLYMERIZATION 76 3.14 POLYMERIZATION PROCESSES 76 3.15
FEATURES OF FREE-RADICAL POLYMERIZATION 79 3.16 CONTROLLED RADICAL
POLYMERIZATION 79 3.17 NITROXIDE-MEDIATED POLYMERIZATIONS 81 3.18 ATOM
TRANSFER RADICAL POLYMERIZATION (ATRP) 82 3.19 REVERSE ATRP 83 3.20
DEGENERATIVE CHAIN TRANSFER REACTION (DT) 84 3.21 REVERSIBLE ADDITION
FRAGMENTATION CHAIN TRANSFER (RAFT) 84 3.22 CRP OFVINYL CHLORIDE 87 3.23
THE KINETICS OF CRP PROCESSES 87 3.24 APPLICATION TO EXPERIMENTAL DATA
90 PROBLEMS 92 REFERENCES 96 BIBLIOGRAPHY 96 CHAPTER 4 IONIC
POLYMERIZATION 99 4.1 GENERAL CHARACTERISTICS 99 4.2 CATIONIC
POLYMERIZATION 100 4.3 PROPAGATION BY CATIONIC CHAIN CARRIERS 101 4.4
TERMINATION 102 4.5 GENERAL KINETIC SCHEME 103 4.6 ENERGETICS OF
CATIONIC POLYMERIZATION 103 4.7 TELECHELIC POLYMERS VIA CATIONIC
POLYMERIZATION 104 4.8 CATIONIC RING OPENING POLYMERIZATION 105 4.9
STABLE CARBOCATIONS 107 4.10 ANIONIC POLYMERIZATION 108 4.11 LIVING
POLYMERS 109 4.12 KINETICS AND MOLAR MASS DISTRIBUTION IN LIVING ANIONIC
SYSTEMS 110 4.13 METAL ALKYL INITIATORS 114 4.14 SOLVENT AND GEGEN ION
EFFECTS 114 4.15 ANIONIC RING-OPENING POLYMERIZATION 114 PROBLEMS 116
REFERENCES 118 BIBLIOGRAPHY 119 CHAPTER 5 LINEAR COPOLYMERS AND OTHER
ARCHITECTURES 121 5.1 GENERAL CHARACTERISTICS 121 5.2 COMPOSITION DRIFT
122 5.3 THE COPOLYMER EQUATION 122 5.4 MONOMER REACTIVITY RATIOS 123 5.5
REACTIVITY RATIOS AND COPOLYMER STRUCTURE 124 5.6 MONOMER REACTIVITIES
AND CHAIN INITIATION 127 5.7 INFLUENCE OF STRUCTURAL EFFECTS ON MONOMER
REACTIVITY RATIOS 127 5.7.1 RESONANCE EFFECTS 127 5.7.2 POLAR EFFECTS
129 5.8 THE Q-E SCHEME 129 5.9 ALTERNATING COPOLYMERS 131 5.10 BLOCK
COPOLYMER SYNTHESIS 133 5.10.1 TRANSFORMATION REACTIONS 135 5.10.1.1
CATIONIC TO CRP 137 5.10.1.2 ANIONIC TO CRP 138 5.10.1.3 ROMP TO ATRP
139 5.10.1.4 STEP-GROWTH ATRP 139 5.10.2 COUPLING REACTIONS 140 5.10.3
USE OF CRP METHODS 142 5.11 GRAFT COPOLYMER SYNTHESIS 145 5.12
STATISTICAL AND GRADIENT COPOLYMERS 147 5.13 COMPLEX MOLECULAR
ARCHITECTURES 148 5.14 DENDRIMERS 149 5.14.1 DIVERGENT GROWTH 150 5.14.2
CONVERGENT GROWTH 151 5.14.3 DENDRIMER MOLECULAR WEIGHT 152 5.14.4
PROPERTIES OF DENDRIMERS 153 5.14.5 APPLICATIONS OF DENDRIMERS 154
PROBLEMS 155 REFERENCES 156 BIBLIOGRAPHY 156 CHAPTER 6 POLYMER
STEREOCHEMISTRY 157 6.1 ARCHITECTURE 157 6.2 ORIENTATION 157 6.3
CONFIGURATION 158 6.3.1 MONOTACTIC POLYMERS 159 6.3.2 DITACTIC POLYMERS
160 6.3.3 POLYETHERS 160 6.4 GEOMETRIE ISOMERISM 162 6.5 CONFORMATION OF
STEREOREGULAR POLYMERS 163 6.6 FACTORS INFLUENCING STEREOREGULATION 165
6.7 HOMOGENEOUS STEREOSPECIFIC CATIONIC POLYMERIZATIONS 167 6.8
HOMOGENEOUS STEREOSELECTIVE ANIONIC POLYMERIZATIONS 168 6.9 HOMOGENEOUS
DIENE POLYMERIZATION 170 6.10 SUMMARY 172 PROBLEMS 172 REFERENCES 173
BIBLIOGRAPHY 173 CHAPTER 7 POLYMERIZATION REACTIONS INITIATED BY METAL
CATALYSTS AND TRANSFER REACTIONS 175 7.1 POLYMERIZATION USING
ZIEGLER-NATTA CATALYSTS 175 7.2 NATURE OF THE CATALYST 176 7.3 NATURE OF
ACTIVE CENTERS 177 7.4 BIMETALLIC MECHANISM 177 7.5 MONOMETALLIC
MECHANISM 178 7.6 STEREOREGULATION 180 7.7 RING-OPENING METATHESIS
POLYMERIZATION (ROMP) 181 7.8 MONOCYCLIC MONOMERS 182 7.9 BICYCLO- AND
TRICYCLOMONOMERS 183 7.10 COPOLYALKENAMERS 184 7.11 LIVING SYSTEMS 184
7.12 GROUP TRANSFER POLYMERIZATION (GTP) 186 7.13 ALDOL GROUP TRANSFER
POLYMERIZATION 187 7.14 METALLOCENE CATALYSTS 188 7.14.1
METALLOCENE/ALUMINOXANE CATALYSTS 189 7.14.2 STEREOREGULATION 189 7.14.3
CATIONIC METALLOCENES 192 7.14.4 MECHANISM OF STEREOREGULATION 192 7.15
CONCLUDING REMARKS 193 PROBLEMS 194 REFERENCES 194 BIBLIOGRAPHY 194
CHAPTER 8 POLYMERS IN SOLUTION 197 8.1 THERMODYNAMICS OF POLYMER
SOLUTIONS 197 8.2 IDEAL MIXTURES OF SMALL MOLECULES 197 8.3 NONIDEAL
SOLUTIONS 199 8.4 FLORY-HUGGINS THEORY: ENTROPY OF MIXING 199 8.5
ENTHALPY CHANGE ON MIXING 203 8.6 FREE ENERGY OF MIXING 204 8.7
LIMITATIONS OF THE FLORY-HUGGINS THEORY 205 8.8 PHASE EQUILIBRIA 206 8.9
FLORY-KRIGBAUM THEORY 208 8.10 LOCATION OF THE THETA TEMPERATURE 210
8.11 LOWER CRITICAL SOLUTION TEMPERATURES 213 8.12 SOLUBILITY AND THE
COHESIVE ENERGY DENSITY 216 8.13 POLYMER-POLYMER MIXTURES 219 8.14
KINETICS OF PHASE SEPARATION 223 PROBLEMS 224 REFERENCES 227
BIBLIOGRAPHY 227 CHAPTER 9 POLYMER CHARACTERIZATION * MOLAR MASSES 229
9.1 INTRODUCTION 229 9.2 MOLAR MASSES, MOLECULAR WEIGHTS, AND SI UNITS
229 9.3 NUMBER-AVERAGE MOLAR MASS M N 229 9.4 END-GROUP ASSAY 230 9.5
COLLIGATIVE PROPERTIES OF SOLUTIONS 230 9.6 OSMOTIC PRESSURE 231 9.7
LIGHT SCATTERING 234 9.7.1 SCATTERING FROM LARGE PARTICLES 236 9.8
DYNAMIC LIGHT SCATTERING 239 9.9 VISCOSITY 240 9.9.1 VISCOSITY-AVERAGE
MOLECULAR WEIGHT 242 9.10 GEL PERMEATION CHROMATOGRAPHY 243 9.11 MALDI
247 PROBLEMS 248 REFERENCES 251 BIBLIOGRAPHY 252 CHAPTER 10 POLYMER
CHARACTERIZATION * CHAIN DIMENSIONS, STRUCTURES, AND MORPHOLOGY 253 10.1
AVERAGE CHAIN DIMENSIONS 253 10.2 FREELY JOINTED CHAIN MODEL 254 10.3
SHORT-RANGE EFFECTS 255 10.4 CHAIN STIFFNESS 255 10.5 TREATMENT OF
DILUTE SOLUTION DATA 256 10.5.1 THE SECOND VIRIAL COEFFICIENT 256 10.5.2
EXPANSION FACTOR A 257 10.5.3 FLORY-FOX THEORY 258 10.5.4 INDIRECT
ESTIMATES OF UNPERTURBED CHAIN DIMENSIONS 259 10.5.5 INFLUENCE OF
TACTICITY ON CHAIN DIMENSIONS 259 10.6 NUCLEAR MAGNETIC RESONANCE (NMR)
260 10.7 INFRARED SPECTROSCOPY 262 10.8 THERMAL ANALYSIS 264 10.9
WIDE-ANGLE AND SMALL-ANGLE SCATTERING 265 10.9.1 WIDE-ANGLE X-RAY
SCATTERING 266 10.9.2 SMALL-ANGLE X-RAY SCATTERING (SAXS) 267 10.9.3
SMALL-ANGLE NEUTRON SCATTERING (SANS) 268 10.10 MICROSCOPY 271 10.10.1
OPTICAL MICROSCOPY 272 10.10.2 SCANNING ELECTRON MICROSCOPY 273 10.10.3
TRANSMISSION ELECTRON MICROSCOPY 274 10.10.4 ATOMIC FORCE MICROSCOPY AND
SCANNING TUNNELING MICROSCOPY 274 PROBLEMS 276 REFERENCES 277
BIBLIOGRAPHY 277 CHAPTER 11 THE CRY STALLINE STATE AND PARTIALLY ORDERED
STRUCTURES 279 11.1 INTRODUCTION 279 11.2 MECHANISM OF CRYSTALLIZATION
279 11.3 TEMPERATURE AND GROWTH RATE 281 11.4 MELTING 282 11.4.1 EFFECT
OF CRYSTALLITE SIZE ON MELTING 282 11.5 THERMODYNAMIC PARAMETERS 282
11.6 CRYSTALLINE ARRANGEMENT OF POLYMERS 285 11.6.1 FACTORS AFFECTING
CRYSTALLINITY AND T M 285 11.6.1.1 SYMMETRY 285 11.6.1.2 INTERMOLECULAR
BONDING 286 11.6.1.3 TACTICITY 287 11.6.1.4 BRANCHING AND MOLAR MASS 287
11.7 MORPHOLOGY AND KINETICS 287 11.8 MORPHOLOGY 287 11.8.1 CRYSTALLITES
288 11.8.2 SINGLE CRYSTALS 288 11.8.3 HEDRITES 289 11.8.4
CRYSTALLIZATION FROM THE MELT 289 11.8.5 SPHERULITES 291 11.9 KINETICS
OF CRYSTALLIZATION 292 11.9.1 ISOTHERMAL CRYSTALLIZATION 293 11.9.2 THE
AVRAMI EQUATION 293 11.9.3 DEVIATIONS FROM AVRAMI EQUATION 294 11.10
BLOCK COPOLYMERS 294 11.11 HISTORICAL DEVELOPMENT OF POLYMER LIQUID
CRYSTALS 296 11.12 LIQUID CRYSTALLINE PHASES 297 11.13 IDENTIFICATION OF
THE MESOPHASES 300 11.14 LYOTROPIC MAIN-CHAIN LIQUID CRYSTAL POLYMERS
302 11.15 THERMOTROPIC MAIN-CHAIN LIQUID CRYSTAL POLYMERS 304 11.16
SIDE-CHAIN LIQUID CRYSTAL POLYMERS 309 11.17 CHIRAL NEMATIC LIQUID
CRYSTAL POLYMERS 311 PROBLEMS 314 REFERENCES 318 BIBLIOGRAPHY 318
CHAPTER 12 THE GLASSY STATE AND GLASS TRANSITION 321 12.1 THE AMORPHOUS
STATE 321 12.2 THE GLASSY STATE 321 12.3 RELAXATION PROCESSES IN THE
GLASSY STATE 321 12.4 GLASS TRANSITION REGION 323 12.4.1 THE GLASS
TRANSITION TEMPERATURE, T G 323 12.4.2 EXPERIMENTAL DEMONSTRATION OF T
324 12.4.2.1 MEASUREMENT OF T G FROM V-T CURVES 325 12.4.2.2 THERMAL
METHODS 326 12.4.3 FACTORS AFFECTING T G 327 12.4.3.1 CHAIN FLEXIBILITY
328 12.4.3.2 STERIC EFFECTS 328 12.4.3.3 CONFIGURATIONAL EFFECTS 330
12.4.3.4 EFFECT OF CROSS-LINKS ON T G 330 12.5 THEORETICAL TREATMENTS
330 12.5.1 THE FREE-VOLUME THEORY 331 12.5.2 GIBBS-DI MARZIO
THERMODYNAMIC THEORY 335 12.5.3 ADAM-GIBBS THEORY 336 12.6 DEPENDENCE OF
T G ON MOLAR MASS 337 12.7 STRUCTURAL RELAXATION AND PHYSICAL AGING 338
PROBLEMS 339 REFERENCES 342 BIBLIOGRAPHY 343 CHAPTER 13 RHEOLOGY AND
MECHANICAL PROPERTIES 345 13.1 INTRODUCTION TO RHEOLOGY 345 13.2 THE
FIVE REGIONS OF VISCOELASTIC BEHAVIOR 346 13.3 THE VISCOUS REGION 347
13.3.1 SHEAR DEPENDENCE OF VISCOSITY 349 13.3.2 KINETIC UNITS IN POLYMER
CHAINS 351 13.3.3 EFFECT OF CHAIN LENGTH 352 13.3.4 TEMPERATURE
DEPENDENCE OF R| 353 13.3.5 CONCENTRATION DEPENDENCE OF VISCOSITY 353
13.3.6 TIME-DEPENDENT BEHAVIOR 354 13.4 MECHANICAL PROPERTIES 355 13.4.1
INTERRELATION OF MODULI 357 13.5 MECHANICAL MODELS DESCRIBING
VISCOELASTICITY 357 13.6 LINEAR VISCOELASTIC BEHAVIOR OF AMORPHOUS
POLYMERS 360 13.6.1 CREEP 360 13.6.2 STRESS-STRAIN MEASUREMENTS 363
13.6.3 EFFECT OF TEMPERATURE ON STRESS-STRAIN RESPONSE 363 13.6.4
BOLTZMANN SUPERPOSITION PRINCIPLE 364 13.6.5 STRESS RELAXATION 365 13.7
DYNAMIC MECHANICAL AND DIELECTRIC THERMAL ANALYSIS 366 13.7.1 DYNAMIC
MECHANICAL THERMAL ANALYSIS (DMTA) 366 13.7.2 DIELECTRIC THERMAL
ANALYSIS (DETA) 369 13.7.3 COMPARISON BETWEEN DMTA AND DETA 371 13.8
TIME-TEMPERATURE SUPERPOSITION PRINCIPLE 373 13.9 DYNAMIC VISCOSITY 377
13.10 A MOLECULAR THEORY FOR VISCOELASTICITY 378 13.11 THE REPTATION
MODEL 380 PROBLEMS 382 REFERENCES 387 BIBLIOGRAPHY 388 CHAPTER 14 THE
ELASTOMERIC STATE 389 14.1 GENERAL INTRODUCTION 389 14.1.1 NATURAL
RUBBER 390 14.2 EXPERIMENTAL VULCANIZATION 391 14.3 PROPERTIES OF
ELASTOMERS 391 14.4 THERMODYNAMIC ASPECTS OF RUBBERLIKE ELASTICITY 392
14.5 NONIDEAL ELASTOMERS 394 14.6 DISTRIBUTION FUNCTION FOR POLYMER
CONFORMATION 395 14.7 STATISTICAL APPROACH 398 14.7.1 EXPERIMENTAL
STRESS-STRAIN RESULTS 398 14.7.1.1 SIMPLE EXTENSION 398 14.7.1.2 SIMPLE
COMPRESSION 400 14.7.1.3 PURE SHEAR 400 14.7.1.4 LARGE ELASTIC
DEFORMATION 400 14.8 SWELLING OF ELASTOMERIC NETWORKS 400 14.9 NETWORK
DEFECTS 401 14.10 RESILIENCE OF ELASTOMERS 403 PROBLEMS 405 REFERENCES
408 BIBLIOGRAPHY 408 CHAPTER 15 STRUCTURE-PROPERTY RELATIONS 409 15.1
GENERAL CONSIDERATIONS 409 15.2 CONTROL OF T M AND T G 409 15.2.1 CHAIN
STIFFNESS 410 15.2.2 INTERMOLECULAR BONDING : 411 15.3 RELATION BETWEEN
T M AND T G 413 15.4 RANDOM COPOLYMERS 413 15.5 DEPENDENCE OF T M AND T
G ON COPOLYMER COMPOSITION 414 15.6 BLOCK COPOLYMERS 417 15.7
PLASTICIZERS 419 15.8 CRYSTALLINITY AND MECHANICAL RESPONSE 420 15.9
APPLICATION TO FIBERS, ELASTOMERS, AND PLASTICS 422 15.10 FIBERS 422
15.10.1 CHEMICAL REQUIREMENTS 423 15.10.1.1 LINEAR POLYESTERS 425
15.10.2 MECHANICAL REQUIREMENTS FOR FIBERS 426 15.10.2.1 SPINNING
TECHNIQUES 426 15.10.2.1.1 MELT SPINNING 426 15.10.2.1.2 WET AND DRY
SPINNING 426 15.10.2.2 DRAWING, ORIENTATION, AND CRYSTALLINITY 427
15.10.2.3 MODULUS AND CHAIN STIFFNESS 428 15.10.2.4 OTHER FACTORS 428
15.11 AROMATIC POLYAMIDES 429 15.12 POLYETHYLENE 431 15.13 ELASTOMERS
AND CROSS-LINKED NETWORKS 434 15.13.1 CROSS-LINKING 435 15.13.2 CREEP IN
CROSS-LINKED POLYMERS 435 15.13.3 ADDITIVES 435 15.14 PLASTICS 435
15.14.1 PLASTIC SELECTION FOR BOTTLE CRATE MANUFACTURE 437 15.14.2
MEDICAL APPLICATIONS 438 15.15 HIGH-TEMPERATURE SPECIALITY POLYMERS 439
15.16 CARBON FIBERS 446 15.17 CONCLUDING REMARKS 446 PROBLEMS 448
REFERENCES 453 BIBLIOGRAPHY 454 CHAPTER 16 POLYMERS FOR THE ELECTRONICS
INDUSTRY 455 16.1 INTRODUCTION 455 16.2 POLYMER RESISTS FOR IC
FABRICATION 455 16.3 THE LITHOGRAPHIE PROCESS 456 16.4 POLYMER RESISTS
457 16.4.1 SENSITIVITY 458 16.4.2 RESOLUTION 459 16.5 PHOTOLITHOGRAPHY
459 16.5.1 POSITIVE PHOTORESISTS 459 16.5.2 NEGATIVE PHOTORESISTS 460
16.6 ELECTRON BEAM SENSITIVE RESISTS 463 16.6.1 POSITIVE RESISTS 463
16.6.2 NEGATIVE RESISTS 464 16.7 X-RAY AND ION SENSITIVE RESISTS 464
16.8 ELECTROACTIVE POLYMERS 465 16.9 CONDUCTION MECHANISMS 466 16.10
PREPARATION OF CONDUCTIVE POLYMERS 467 16.11 POLYACETYLENE 469 16.12
POLY(JC-PHENYLENE) 472 16.13 POLYHETEROCYCLIC SYSTEMS 474 16.13.1
POLYPYRROLE 475 16.13.2 SULFUR COMPOUNDS 475 16.14 POLYANILINE 476 16.15
POLY(PHENYLENE SULFIDE) 476 16.16 POLY(L,6-HEPTADIYNE) 476 16.17
APPLICATIONS 476 16.18 PHOTONIC APPLICATIONS 477 16.19 LIGHT-EMITTING
POLYMERS 477 16.19.1 APPLICATIONS 478 16.20 NONLINEAR OPTICS 478 16.21
LANGMUIR-BLODGETT FILMS 481 16.22 OPTICAL INFORMATION STORAGE 483 16.23
THERMORECORDING ON LIQUID CRYSTALLINE POLYMERS 486 REFERENCES 487
BIBLIOGRAPHY 487 INDEX 489
|
| adam_txt |
POLYMERS: CHEMISTRY AND PHYSICS OF MODERN MATERIALS THIRD EDITION J.M.G.
COWIE HERIOT-WATT UNIVERSITY SCOTLAND,UK VALERIA ARRIGHI HERIOT-WATT
UNIVERSITY SCOTLAND,UK CONTENTS PREFACE XV THE AUTHORS XVII CHAPTER 1
INTRODUCTION 1 1.1 BIRTH OF A CONCEPT 1 1.2 SOME BASIC DEFINITIONS 2 1.3
SYNTHESIS OF POLYMERS 4 1.4 NOMENCLATURE 4 1.5 AVERAGE MOLAR MASSES AND
DISTRIBUTIONS 8 1.6 SIZE AND SHAPE 10 1.7 CONFIGURATION 12 1.8 THE GLASS
TRANSITION TEMPERATURE T G AND THE MELTING TEMPERATURE T M . 14 1.9
ELASTOMERS, FIBERS, AND PLASTICS 16 1.10 FIBER-FORMING POLYMERS 18 1.11
PLASTICS 18 1.12 THERMOSETTING POLYMERS 21 1.13 ELASTOMERS 21 PROBLEMS
25 REFERENCES 27 BIBLIOGRAPHY 27 CHAPTER 2 STEP-GROWTH POLYMERIZATION 29
2.1 GENERAL REACTIONS 29 2.2 REACTIVITY OF FUNCTIONAL GROUPS , 30 2.3
CAROTHERS EQUATION 31 2.4 CONTROL OF THE MOLAR MASS 32 2.5
STOICHIOMETRIC CONTROL OF M* 34 2.6 KINETICS 36 2.7 MOLAR MASS
DISTRIBUTION IN LINEAR SYSTEMS 38 2.8 AVERAGE MOLAR MASSES 39 2.9
CHARACTERISTICS OF STEP-GROWTH POLYMERIZATION 40 2.10 TYPICAL
STEP-GROWTH REACTIONS 40 2.11 RING FORMATION 41 2.12 NONLINEAR
STEP-GROWTH REACTIONS 42 2.13 STATISTICAL DERIVATION 43 2.14 COMPARISON
WITH EXPERIMENT 44 2.15 POLYURETHANES 46 2.16 THERMOSETTING POLYMERS 49
PROBLEMS 52 REFERENCES 56 BIBLIOGRAPHY 56 CHAPTER 3 FREE-RADICAL
ADDITION POLYMERIZATION 57 3.1 ADDITION POLYMERIZATION 57 3.2 CHOICE OF
INITIATORS 57 3.3 FREE-RADICAL POLYMERIZATION 58 3.4 INITIATORS 59 3.4.1
INITIATOR EFFICIENCY 60 3.5 CHAIN GROWTH 62 3.6 TERMINATION 62 3.7
STEADY-STATE KINETICS 63 3.8 HIGH-CONVERSION BULK POLYMERIZATIONS 65 3.9
CHAIN TRANSFER 67 3.9.1 CONSEQUENCES OF CHAIN TRANSFER 70 3.10
INHIBITORS AND RETARDERS 70 3.11 ACTIVATION ENERGIES AND THE EFFECT OF
TEMPERATURE 72 3.12 THERMODYNAMICS OF RADICAL POLYMERIZATION 73 3.13
HEATS OF POLYMERIZATION 76 3.14 POLYMERIZATION PROCESSES 76 3.15
FEATURES OF FREE-RADICAL POLYMERIZATION 79 3.16 CONTROLLED RADICAL
POLYMERIZATION 79 3.17 NITROXIDE-MEDIATED POLYMERIZATIONS 81 3.18 ATOM
TRANSFER RADICAL POLYMERIZATION (ATRP) 82 3.19 REVERSE ATRP 83 3.20
DEGENERATIVE CHAIN TRANSFER REACTION (DT) 84 3.21 REVERSIBLE ADDITION
FRAGMENTATION CHAIN TRANSFER (RAFT) 84 3.22 CRP OFVINYL CHLORIDE 87 3.23
THE KINETICS OF CRP PROCESSES 87 3.24 APPLICATION TO EXPERIMENTAL DATA
90 PROBLEMS 92 REFERENCES 96 BIBLIOGRAPHY 96 CHAPTER 4 IONIC
POLYMERIZATION 99 4.1 GENERAL CHARACTERISTICS 99 4.2 CATIONIC
POLYMERIZATION 100 4.3 PROPAGATION BY CATIONIC CHAIN CARRIERS 101 4.4
TERMINATION 102 4.5 GENERAL KINETIC SCHEME 103 4.6 ENERGETICS OF
CATIONIC POLYMERIZATION 103 4.7 TELECHELIC POLYMERS VIA CATIONIC
POLYMERIZATION 104 4.8 CATIONIC RING OPENING POLYMERIZATION 105 4.9
STABLE CARBOCATIONS 107 4.10 ANIONIC POLYMERIZATION 108 4.11 LIVING
POLYMERS 109 4.12 KINETICS AND MOLAR MASS DISTRIBUTION IN LIVING ANIONIC
SYSTEMS 110 4.13 METAL ALKYL INITIATORS 114 4.14 SOLVENT AND GEGEN ION
EFFECTS 114 4.15 ANIONIC RING-OPENING POLYMERIZATION 114 PROBLEMS 116
REFERENCES 118 BIBLIOGRAPHY 119 CHAPTER 5 LINEAR COPOLYMERS AND OTHER
ARCHITECTURES 121 5.1 GENERAL CHARACTERISTICS 121 5.2 COMPOSITION DRIFT
122 5.3 THE COPOLYMER EQUATION 122 5.4 MONOMER REACTIVITY RATIOS 123 5.5
REACTIVITY RATIOS AND COPOLYMER STRUCTURE 124 5.6 MONOMER REACTIVITIES
AND CHAIN INITIATION 127 5.7 INFLUENCE OF STRUCTURAL EFFECTS ON MONOMER
REACTIVITY RATIOS 127 5.7.1 RESONANCE EFFECTS 127 5.7.2 POLAR EFFECTS
129 5.8 THE Q-E SCHEME 129 5.9 ALTERNATING COPOLYMERS 131 5.10 BLOCK
COPOLYMER SYNTHESIS 133 5.10.1 TRANSFORMATION REACTIONS 135 5.10.1.1
CATIONIC TO CRP 137 5.10.1.2 ANIONIC TO CRP 138 5.10.1.3 ROMP TO ATRP
139 5.10.1.4 STEP-GROWTH ATRP 139 5.10.2 COUPLING REACTIONS 140 5.10.3
USE OF CRP METHODS 142 5.11 GRAFT COPOLYMER SYNTHESIS 145 5.12
STATISTICAL AND GRADIENT COPOLYMERS 147 5.13 COMPLEX MOLECULAR
ARCHITECTURES 148 5.14 DENDRIMERS 149 5.14.1 DIVERGENT GROWTH 150 5.14.2
CONVERGENT GROWTH 151 5.14.3 DENDRIMER MOLECULAR WEIGHT 152 5.14.4
PROPERTIES OF DENDRIMERS 153 5.14.5 APPLICATIONS OF DENDRIMERS 154
PROBLEMS 155 REFERENCES 156 BIBLIOGRAPHY 156 CHAPTER 6 POLYMER
STEREOCHEMISTRY 157 6.1 ARCHITECTURE 157 6.2 ORIENTATION 157 6.3
CONFIGURATION 158 6.3.1 MONOTACTIC POLYMERS 159 6.3.2 DITACTIC POLYMERS
160 6.3.3 POLYETHERS 160 6.4 GEOMETRIE ISOMERISM 162 6.5 CONFORMATION OF
STEREOREGULAR POLYMERS 163 6.6 FACTORS INFLUENCING STEREOREGULATION 165
6.7 HOMOGENEOUS STEREOSPECIFIC CATIONIC POLYMERIZATIONS 167 6.8
HOMOGENEOUS STEREOSELECTIVE ANIONIC POLYMERIZATIONS 168 6.9 HOMOGENEOUS
DIENE POLYMERIZATION 170 6.10 SUMMARY 172 PROBLEMS 172 REFERENCES 173
BIBLIOGRAPHY 173 CHAPTER 7 POLYMERIZATION REACTIONS INITIATED BY METAL
CATALYSTS AND TRANSFER REACTIONS 175 7.1 POLYMERIZATION USING
ZIEGLER-NATTA CATALYSTS 175 7.2 NATURE OF THE CATALYST 176 7.3 NATURE OF
ACTIVE CENTERS 177 7.4 BIMETALLIC MECHANISM 177 7.5 MONOMETALLIC
MECHANISM 178 7.6 STEREOREGULATION 180 7.7 RING-OPENING METATHESIS
POLYMERIZATION (ROMP) 181 7.8 MONOCYCLIC MONOMERS 182 7.9 BICYCLO- AND
TRICYCLOMONOMERS 183 7.10 COPOLYALKENAMERS 184 7.11 LIVING SYSTEMS 184
7.12 GROUP TRANSFER POLYMERIZATION (GTP) 186 7.13 ALDOL GROUP TRANSFER
POLYMERIZATION 187 7.14 METALLOCENE CATALYSTS 188 7.14.1
METALLOCENE/ALUMINOXANE CATALYSTS 189 7.14.2 STEREOREGULATION 189 7.14.3
CATIONIC METALLOCENES 192 7.14.4 MECHANISM OF STEREOREGULATION 192 7.15
CONCLUDING REMARKS 193 PROBLEMS 194 REFERENCES 194 BIBLIOGRAPHY 194
CHAPTER 8 POLYMERS IN SOLUTION 197 8.1 THERMODYNAMICS OF POLYMER
SOLUTIONS 197 8.2 IDEAL MIXTURES OF SMALL MOLECULES 197 8.3 NONIDEAL
SOLUTIONS 199 8.4 FLORY-HUGGINS THEORY: ENTROPY OF MIXING 199 8.5
ENTHALPY CHANGE ON MIXING 203 8.6 FREE ENERGY OF MIXING 204 8.7
LIMITATIONS OF THE FLORY-HUGGINS THEORY 205 8.8 PHASE EQUILIBRIA 206 8.9
FLORY-KRIGBAUM THEORY 208 8.10 LOCATION OF THE THETA TEMPERATURE 210
8.11 LOWER CRITICAL SOLUTION TEMPERATURES 213 8.12 SOLUBILITY AND THE
COHESIVE ENERGY DENSITY 216 8.13 POLYMER-POLYMER MIXTURES 219 8.14
KINETICS OF PHASE SEPARATION 223 PROBLEMS 224 REFERENCES 227
BIBLIOGRAPHY 227 CHAPTER 9 POLYMER CHARACTERIZATION * MOLAR MASSES 229
9.1 INTRODUCTION 229 9.2 MOLAR MASSES, MOLECULAR WEIGHTS, AND SI UNITS
229 9.3 NUMBER-AVERAGE MOLAR MASS M N 229 9.4 END-GROUP ASSAY 230 9.5
COLLIGATIVE PROPERTIES OF SOLUTIONS 230 9.6 OSMOTIC PRESSURE 231 9.7
LIGHT SCATTERING 234 9.7.1 SCATTERING FROM LARGE PARTICLES 236 9.8
DYNAMIC LIGHT SCATTERING 239 9.9 VISCOSITY 240 9.9.1 VISCOSITY-AVERAGE
MOLECULAR WEIGHT 242 9.10 GEL PERMEATION CHROMATOGRAPHY 243 9.11 MALDI
247 PROBLEMS 248 REFERENCES 251 BIBLIOGRAPHY 252 CHAPTER 10 POLYMER
CHARACTERIZATION * CHAIN DIMENSIONS, STRUCTURES, AND MORPHOLOGY 253 10.1
AVERAGE CHAIN DIMENSIONS 253 10.2 FREELY JOINTED CHAIN MODEL 254 10.3
SHORT-RANGE EFFECTS 255 10.4 CHAIN STIFFNESS 255 10.5 TREATMENT OF
DILUTE SOLUTION DATA 256 10.5.1 THE SECOND VIRIAL COEFFICIENT 256 10.5.2
EXPANSION FACTOR A 257 10.5.3 FLORY-FOX THEORY 258 10.5.4 INDIRECT
ESTIMATES OF UNPERTURBED CHAIN DIMENSIONS 259 10.5.5 INFLUENCE OF
TACTICITY ON CHAIN DIMENSIONS 259 10.6 NUCLEAR MAGNETIC RESONANCE (NMR)
260 10.7 INFRARED SPECTROSCOPY 262 10.8 THERMAL ANALYSIS 264 10.9
WIDE-ANGLE AND SMALL-ANGLE SCATTERING 265 10.9.1 WIDE-ANGLE X-RAY
SCATTERING 266 10.9.2 SMALL-ANGLE X-RAY SCATTERING (SAXS) 267 10.9.3
SMALL-ANGLE NEUTRON SCATTERING (SANS) 268 10.10 MICROSCOPY 271 10.10.1
OPTICAL MICROSCOPY 272 10.10.2 SCANNING ELECTRON MICROSCOPY 273 10.10.3
TRANSMISSION ELECTRON MICROSCOPY 274 10.10.4 ATOMIC FORCE MICROSCOPY AND
SCANNING TUNNELING MICROSCOPY 274 PROBLEMS 276 REFERENCES 277
BIBLIOGRAPHY 277 CHAPTER 11 THE CRY STALLINE STATE AND PARTIALLY ORDERED
STRUCTURES 279 11.1 INTRODUCTION 279 11.2 MECHANISM OF CRYSTALLIZATION
279 11.3 TEMPERATURE AND GROWTH RATE 281 11.4 MELTING 282 11.4.1 EFFECT
OF CRYSTALLITE SIZE ON MELTING 282 11.5 THERMODYNAMIC PARAMETERS 282
11.6 CRYSTALLINE ARRANGEMENT OF POLYMERS 285 11.6.1 FACTORS AFFECTING
CRYSTALLINITY AND T M 285 11.6.1.1 SYMMETRY 285 11.6.1.2 INTERMOLECULAR
BONDING 286 11.6.1.3 TACTICITY 287 11.6.1.4 BRANCHING AND MOLAR MASS 287
11.7 MORPHOLOGY AND KINETICS 287 11.8 MORPHOLOGY 287 11.8.1 CRYSTALLITES
288 11.8.2 SINGLE CRYSTALS 288 11.8.3 HEDRITES 289 11.8.4
CRYSTALLIZATION FROM THE MELT 289 11.8.5 SPHERULITES 291 11.9 KINETICS
OF CRYSTALLIZATION 292 11.9.1 ISOTHERMAL CRYSTALLIZATION 293 11.9.2 THE
AVRAMI EQUATION 293 11.9.3 DEVIATIONS FROM AVRAMI EQUATION 294 11.10
BLOCK COPOLYMERS 294 11.11 HISTORICAL DEVELOPMENT OF POLYMER LIQUID
CRYSTALS 296 11.12 LIQUID CRYSTALLINE PHASES 297 11.13 IDENTIFICATION OF
THE MESOPHASES 300 11.14 LYOTROPIC MAIN-CHAIN LIQUID CRYSTAL POLYMERS
302 11.15 THERMOTROPIC MAIN-CHAIN LIQUID CRYSTAL POLYMERS 304 11.16
SIDE-CHAIN LIQUID CRYSTAL POLYMERS 309 11.17 CHIRAL NEMATIC LIQUID
CRYSTAL POLYMERS 311 PROBLEMS 314 REFERENCES 318 BIBLIOGRAPHY 318
CHAPTER 12 THE GLASSY STATE AND GLASS TRANSITION 321 12.1 THE AMORPHOUS
STATE 321 12.2 THE GLASSY STATE 321 12.3 RELAXATION PROCESSES IN THE
GLASSY STATE 321 12.4 GLASS TRANSITION REGION 323 12.4.1 THE GLASS
TRANSITION TEMPERATURE, T G 323 12.4.2 EXPERIMENTAL DEMONSTRATION OF T
324 12.4.2.1 MEASUREMENT OF T G FROM V-T CURVES 325 12.4.2.2 THERMAL
METHODS 326 12.4.3 FACTORS AFFECTING T G 327 12.4.3.1 CHAIN FLEXIBILITY
328 12.4.3.2 STERIC EFFECTS 328 12.4.3.3 CONFIGURATIONAL EFFECTS 330
12.4.3.4 EFFECT OF CROSS-LINKS ON T G 330 12.5 THEORETICAL TREATMENTS
330 12.5.1 THE FREE-VOLUME THEORY 331 12.5.2 GIBBS-DI MARZIO
THERMODYNAMIC THEORY 335 12.5.3 ADAM-GIBBS THEORY 336 12.6 DEPENDENCE OF
T G ON MOLAR MASS 337 12.7 STRUCTURAL RELAXATION AND PHYSICAL AGING 338
PROBLEMS 339 REFERENCES 342 BIBLIOGRAPHY 343 CHAPTER 13 RHEOLOGY AND
MECHANICAL PROPERTIES 345 13.1 INTRODUCTION TO RHEOLOGY 345 13.2 THE
FIVE REGIONS OF VISCOELASTIC BEHAVIOR 346 13.3 THE VISCOUS REGION 347
13.3.1 SHEAR DEPENDENCE OF VISCOSITY 349 13.3.2 KINETIC UNITS IN POLYMER
CHAINS 351 13.3.3 EFFECT OF CHAIN LENGTH 352 13.3.4 TEMPERATURE
DEPENDENCE OF R| 353 13.3.5 CONCENTRATION DEPENDENCE OF VISCOSITY 353
13.3.6 TIME-DEPENDENT BEHAVIOR 354 13.4 MECHANICAL PROPERTIES 355 13.4.1
INTERRELATION OF MODULI 357 13.5 MECHANICAL MODELS DESCRIBING
VISCOELASTICITY 357 13.6 LINEAR VISCOELASTIC BEHAVIOR OF AMORPHOUS
POLYMERS 360 13.6.1 CREEP 360 13.6.2 STRESS-STRAIN MEASUREMENTS 363
13.6.3 EFFECT OF TEMPERATURE ON STRESS-STRAIN RESPONSE 363 13.6.4
BOLTZMANN SUPERPOSITION PRINCIPLE 364 13.6.5 STRESS RELAXATION 365 13.7
DYNAMIC MECHANICAL AND DIELECTRIC THERMAL ANALYSIS 366 13.7.1 DYNAMIC
MECHANICAL THERMAL ANALYSIS (DMTA) 366 13.7.2 DIELECTRIC THERMAL
ANALYSIS (DETA) 369 13.7.3 COMPARISON BETWEEN DMTA AND DETA 371 13.8
TIME-TEMPERATURE SUPERPOSITION PRINCIPLE 373 13.9 DYNAMIC VISCOSITY 377
13.10 A MOLECULAR THEORY FOR VISCOELASTICITY 378 13.11 THE REPTATION
MODEL 380 PROBLEMS 382 REFERENCES 387 BIBLIOGRAPHY 388 CHAPTER 14 THE
ELASTOMERIC STATE 389 14.1 GENERAL INTRODUCTION 389 14.1.1 NATURAL
RUBBER 390 14.2 EXPERIMENTAL VULCANIZATION 391 14.3 PROPERTIES OF
ELASTOMERS 391 14.4 THERMODYNAMIC ASPECTS OF RUBBERLIKE ELASTICITY 392
14.5 NONIDEAL ELASTOMERS 394 14.6 DISTRIBUTION FUNCTION FOR POLYMER
CONFORMATION 395 14.7 STATISTICAL APPROACH 398 14.7.1 EXPERIMENTAL
STRESS-STRAIN RESULTS 398 14.7.1.1 SIMPLE EXTENSION 398 14.7.1.2 SIMPLE
COMPRESSION 400 14.7.1.3 PURE SHEAR 400 14.7.1.4 LARGE ELASTIC
DEFORMATION 400 14.8 SWELLING OF ELASTOMERIC NETWORKS 400 14.9 NETWORK
DEFECTS 401 14.10 RESILIENCE OF ELASTOMERS 403 PROBLEMS 405 REFERENCES
408 BIBLIOGRAPHY 408 CHAPTER 15 STRUCTURE-PROPERTY RELATIONS 409 15.1
GENERAL CONSIDERATIONS 409 15.2 CONTROL OF T M AND T G 409 15.2.1 CHAIN
STIFFNESS 410 15.2.2 INTERMOLECULAR BONDING : 411 15.3 RELATION BETWEEN
T M AND T G 413 15.4 RANDOM COPOLYMERS 413 15.5 DEPENDENCE OF T M AND T
G ON COPOLYMER COMPOSITION 414 15.6 BLOCK COPOLYMERS 417 15.7
PLASTICIZERS 419 15.8 CRYSTALLINITY AND MECHANICAL RESPONSE 420 15.9
APPLICATION TO FIBERS, ELASTOMERS, AND PLASTICS 422 15.10 FIBERS 422
15.10.1 CHEMICAL REQUIREMENTS 423 15.10.1.1 LINEAR POLYESTERS 425
15.10.2 MECHANICAL REQUIREMENTS FOR FIBERS 426 15.10.2.1 SPINNING
TECHNIQUES 426 15.10.2.1.1 MELT SPINNING 426 15.10.2.1.2 WET AND DRY
SPINNING 426 15.10.2.2 DRAWING, ORIENTATION, AND CRYSTALLINITY 427
15.10.2.3 MODULUS AND CHAIN STIFFNESS 428 15.10.2.4 OTHER FACTORS 428
15.11 AROMATIC POLYAMIDES 429 15.12 POLYETHYLENE 431 15.13 ELASTOMERS
AND CROSS-LINKED NETWORKS 434 15.13.1 CROSS-LINKING 435 15.13.2 CREEP IN
CROSS-LINKED POLYMERS 435 15.13.3 ADDITIVES 435 15.14 PLASTICS 435
15.14.1 PLASTIC SELECTION FOR BOTTLE CRATE MANUFACTURE 437 15.14.2
MEDICAL APPLICATIONS 438 15.15 HIGH-TEMPERATURE SPECIALITY POLYMERS 439
15.16 CARBON FIBERS 446 15.17 CONCLUDING REMARKS 446 PROBLEMS 448
REFERENCES 453 BIBLIOGRAPHY 454 CHAPTER 16 POLYMERS FOR THE ELECTRONICS
INDUSTRY 455 16.1 INTRODUCTION 455 16.2 POLYMER RESISTS FOR IC
FABRICATION 455 16.3 THE LITHOGRAPHIE PROCESS 456 16.4 POLYMER RESISTS
457 16.4.1 SENSITIVITY 458 16.4.2 RESOLUTION 459 16.5 PHOTOLITHOGRAPHY
459 16.5.1 POSITIVE PHOTORESISTS 459 16.5.2 NEGATIVE PHOTORESISTS 460
16.6 ELECTRON BEAM SENSITIVE RESISTS 463 16.6.1 POSITIVE RESISTS 463
16.6.2 NEGATIVE RESISTS 464 16.7 X-RAY AND ION SENSITIVE RESISTS 464
16.8 ELECTROACTIVE POLYMERS 465 16.9 CONDUCTION MECHANISMS 466 16.10
PREPARATION OF CONDUCTIVE POLYMERS 467 16.11 POLYACETYLENE 469 16.12
POLY(JC-PHENYLENE) 472 16.13 POLYHETEROCYCLIC SYSTEMS 474 16.13.1
POLYPYRROLE 475 16.13.2 SULFUR COMPOUNDS 475 16.14 POLYANILINE 476 16.15
POLY(PHENYLENE SULFIDE) 476 16.16 POLY(L,6-HEPTADIYNE) 476 16.17
APPLICATIONS 476 16.18 PHOTONIC APPLICATIONS 477 16.19 LIGHT-EMITTING
POLYMERS 477 16.19.1 APPLICATIONS 478 16.20 NONLINEAR OPTICS 478 16.21
LANGMUIR-BLODGETT FILMS 481 16.22 OPTICAL INFORMATION STORAGE 483 16.23
THERMORECORDING ON LIQUID CRYSTALLINE POLYMERS 486 REFERENCES 487
BIBLIOGRAPHY 487 INDEX 489 |
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| discipline_str_mv | Chemie / Pharmazie Physik Werkstoffwissenschaften Chemie Werkstoffwissenschaften / Fertigungstechnik |
| edition | 3. ed. |
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| genre_facet | Lehrbuch |
| id | DE-604.BV022475375 |
| illustrated | Illustrated |
| index_date | 2024-07-02T17:46:13Z |
| indexdate | 2024-07-09T20:58:24Z |
| institution | BVB |
| isbn | 9780849398131 0849398134 |
| language | English |
| lccn | 2007005187 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015682796 |
| oclc_num | 82473191 |
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| owner | DE-703 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-1046 DE-634 DE-526 DE-83 DE-11 DE-29T DE-B768 |
| owner_facet | DE-703 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-1046 DE-634 DE-526 DE-83 DE-11 DE-29T DE-B768 |
| physical | 499 S. Ill., graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
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| publisher | CRC Press |
| record_format | marc |
| spelling | Cowie, John M. G. Verfasser (DE-588)115449213 aut Polymers chemistry and physics of modern materials J. M. G. Cowie ; Valeria Arrighi 3. ed. Boca Raton, FL CRC Press 2008 499 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier "Extensively revised and updated to keep abreast of recent advances, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide a broad-based, high-information text at an introductory, reader-friendly level that illustrates the multidisciplinary nature of polymer science. Adding or amending roughly 50 percent of the material, this new edition strengthens the original's aim to contribute a comprehensive treatment by offering a wide and balanced selection of topics across all aspects of the chemistry and physics of polymer science, from synthesis and physical properties to applications."--BOOK JACKET. Polymères Polymérisation Polymers Textbooks Polymerization Textbooks Stereochemie (DE-588)4129569-9 gnd rswk-swf Makromolekulare Chemie (DE-588)4168684-6 gnd rswk-swf Physik (DE-588)4045956-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Struktur (DE-588)4058125-1 gnd rswk-swf Morphologie (DE-588)4040289-7 gnd rswk-swf Polymerisation (DE-588)4046704-1 gnd rswk-swf Polyaddition (DE-588)4139344-2 gnd rswk-swf Copolymerisation (DE-588)4070106-2 gnd rswk-swf Mechanische Eigenschaft (DE-588)4217961-0 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf 1\p (DE-588)4123623-3 Lehrbuch gnd-content Polymere (DE-588)4046699-1 s Physik (DE-588)4045956-1 s DE-604 Makromolekulare Chemie (DE-588)4168684-6 s Chemie (DE-588)4009816-3 s 2\p DE-604 Polymerisation (DE-588)4046704-1 s 3\p DE-604 Copolymerisation (DE-588)4070106-2 s 4\p DE-604 Polyaddition (DE-588)4139344-2 s 5\p DE-604 Struktur (DE-588)4058125-1 s 6\p DE-604 Stereochemie (DE-588)4129569-9 s 7\p DE-604 Mechanische Eigenschaft (DE-588)4217961-0 s 8\p DE-604 Morphologie (DE-588)4040289-7 s 9\p DE-604 Arrighi, Valeria Verfasser aut http://www3.ub.tu-berlin.de/ihv/001772887.pdf Inhaltsverzeichnis GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015682796&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 6\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 7\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 8\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 9\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Cowie, John M. G. Arrighi, Valeria Polymers chemistry and physics of modern materials Polymères Polymérisation Polymers Textbooks Polymerization Textbooks Stereochemie (DE-588)4129569-9 gnd Makromolekulare Chemie (DE-588)4168684-6 gnd Physik (DE-588)4045956-1 gnd Polymere (DE-588)4046699-1 gnd Struktur (DE-588)4058125-1 gnd Morphologie (DE-588)4040289-7 gnd Polymerisation (DE-588)4046704-1 gnd Polyaddition (DE-588)4139344-2 gnd Copolymerisation (DE-588)4070106-2 gnd Mechanische Eigenschaft (DE-588)4217961-0 gnd Chemie (DE-588)4009816-3 gnd |
| subject_GND | (DE-588)4129569-9 (DE-588)4168684-6 (DE-588)4045956-1 (DE-588)4046699-1 (DE-588)4058125-1 (DE-588)4040289-7 (DE-588)4046704-1 (DE-588)4139344-2 (DE-588)4070106-2 (DE-588)4217961-0 (DE-588)4009816-3 (DE-588)4123623-3 |
| title | Polymers chemistry and physics of modern materials |
| title_auth | Polymers chemistry and physics of modern materials |
| title_exact_search | Polymers chemistry and physics of modern materials |
| title_exact_search_txtP | Polymers chemistry and physics of modern materials |
| title_full | Polymers chemistry and physics of modern materials J. M. G. Cowie ; Valeria Arrighi |
| title_fullStr | Polymers chemistry and physics of modern materials J. M. G. Cowie ; Valeria Arrighi |
| title_full_unstemmed | Polymers chemistry and physics of modern materials J. M. G. Cowie ; Valeria Arrighi |
| title_short | Polymers |
| title_sort | polymers chemistry and physics of modern materials |
| title_sub | chemistry and physics of modern materials |
| topic | Polymères Polymérisation Polymers Textbooks Polymerization Textbooks Stereochemie (DE-588)4129569-9 gnd Makromolekulare Chemie (DE-588)4168684-6 gnd Physik (DE-588)4045956-1 gnd Polymere (DE-588)4046699-1 gnd Struktur (DE-588)4058125-1 gnd Morphologie (DE-588)4040289-7 gnd Polymerisation (DE-588)4046704-1 gnd Polyaddition (DE-588)4139344-2 gnd Copolymerisation (DE-588)4070106-2 gnd Mechanische Eigenschaft (DE-588)4217961-0 gnd Chemie (DE-588)4009816-3 gnd |
| topic_facet | Polymères Polymérisation Polymers Textbooks Polymerization Textbooks Stereochemie Makromolekulare Chemie Physik Polymere Struktur Morphologie Polymerisation Polyaddition Copolymerisation Mechanische Eigenschaft Chemie Lehrbuch |
| url | http://www3.ub.tu-berlin.de/ihv/001772887.pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015682796&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT cowiejohnmg polymerschemistryandphysicsofmodernmaterials AT arrighivaleria polymerschemistryandphysicsofmodernmaterials |
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